侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性

罗春华; 董秋静; 王丹; 张宏; 陶栋梁; 崔玉民

doi:10.3788/fgxb20143507.0777

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侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性

材料合成及性能 | 更新时间：2020-08-12

- 侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性
- Photocrosslinkable Properties of Poly(meth)acrylates with Pendent Chalcone Moieties
- 发光学报 2014年35卷第7期页码：777-784
- 作者机构：
  
  1. 阜阳师范学院化学化工学院,安徽阜阳,236037
  2. 聚合物分子工程国家重点实验室复旦大学上海,200433
- 作者简介：
- 基金信息：
  
  国家自然科学基金（50903018）();聚合物分子工程国家重点实验室（复旦大学）开放研究课题基金（K2013-11）();安徽省高等学校自然科学基金（KJ2014A1
- DOI：10.3788/fgxb20143507.0777
  中图分类号： O631
- 收稿日期：2014-03-10，
  
  修回日期：2014-05-06，
  
  纸质出版日期：2014-07-03
- 稿件说明：
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罗春华, 董秋静, 王丹等. 侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性[J]. 发光学报, 2014,35(7): 777-784

LUO Chun-hua, DONG Qiu-jing, WANG Dan etc. Photocrosslinkable Properties of Poly(meth)acrylates with Pendent Chalcone Moieties[J]. Chinese Journal of Luminescence, 2014,35(7): 777-784
罗春华, 董秋静, 王丹等. 侧链含查尔酮基团的聚(甲基)丙烯酸酯的光交联特性[J]. 发光学报, 2014,35(7): 777-784 DOI： 10.3788/fgxb20143507.0777.

LUO Chun-hua, DONG Qiu-jing, WANG Dan etc. Photocrosslinkable Properties of Poly(meth)acrylates with Pendent Chalcone Moieties[J]. Chinese Journal of Luminescence, 2014,35(7): 777-784 DOI： 10.3788/fgxb20143507.0777.

摘要

采用红外光谱、热重分析、紫外光谱和荧光光谱对侧链含查尔酮基团的聚（4-甲基丙烯酰氧基-4'-二甲氨基查尔酮）（PMADMAC）和聚（4-丙烯酰氧基查尔酮）（PAC）的光交联特性进行了研究。随着光照时间的增加，PMADMAC和PAC聚合物光致环加成反应迅速进行，波长短的紫外线更易使得聚合物发生[2+2]环加成反应。与溶液状态相比，固体薄膜状态下的光交联反应速率较慢。PMADMAC聚合物更容易发生光致环加成反应，其光交联速率要比PAC聚合物快，环加成反应也更彻底。采用荧光光谱研究了聚合物的发光特性，发现PAC聚合物无荧光，而PMADMAC聚合物具有溶剂极性敏感的荧光特性。在PMADMAC聚合物的稀溶液中，随着365 nm紫外光照时间的增加，荧光强度迅速降低，其荧光特征波长在紫外光照射后发生蓝移。 PMADMAC和PAC聚合物的热稳定性较好，光交联后形成热不稳定的环丁烷结构，其热稳定性有所降低。

Abstract

The photocrosslinking properties of poly(4-methacryloyloxy-4'-dimethyl aminochalcone) (PMADMAC) and poly(4-acryloyloxychalcone) (PAC) homopolymers were investigated by Fourier transform infrared spectoscopy (FT-IR)

thermogravimetric analysis

UV-visible spectroscopy (UV-Vis)

and fluorescence spectroscopy. Photocrosslinking results of PMADMAC and PAC indicate the photo-induced [2+2] cycloaddition reaction takes place rapidly with the increase of light irradiation time and is carried out easily at presence of shortwave UV light. The photocrosslinking rate of polymers in the state of thin film is slower than that of solution due to the limited molecular motion in solid. Compared to PAC

the cycloaddition reaction of PMADMAC with intramolecular charge transfer properties takes place more easily and completely

and the photocrosslinking rate more rapidly. The photoluminescent properties were investigated by fluorescence spectroscopic techniques and the results show PMADMAC with solvent polarity sensitive fluorescence and PAC without fluorescence. With the increase of 365 nm UV light irradiation time

the fluorescent intensity of PMADMAC dilute solution decreases drastically and the fluorescent wavelength blueshifts in the late of UV irradiation. Thermogravimetric analysis results show a good thermalstability of PMADMAC and PAC

and a decrease in thermalstability after the formation of cyclobutane ring by photocrosslinking.

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