AlGaN合金中局域态和极化电场的竞争机制

毛德丰; 金鹏; 李维; 刘贵鹏; 王维颖; 王占国

doi:10.3788/fgxb20143507.0761

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AlGaN合金中局域态和极化电场的竞争机制

材料合成及性能 | 更新时间：2020-08-12

- AlGaN合金中局域态和极化电场的竞争机制
- Competition Mechanism of Local State-internal Polarization Electric Field in Algan Alloy
- 发光学报 2014年35卷第7期页码：761-766
- 作者机构：
  
  中国科学院半导体研究所半导体材料科学重点实验室低维半导体材料与器件北京市重点实验室北京,100083
- 作者简介：
- 基金信息：
  
  国家重点基础研究发展计划（973计划）（2012CB619306）资助项目()
- DOI：10.3788/fgxb20143507.0761
  中图分类号： TN304
- 收稿日期：2014-03-13，
  
  修回日期：2014-04-01，
  
  纸质出版日期：2014-07-03
- 稿件说明：
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毛德丰, 金鹏, 李维等. AlGaN合金中局域态和极化电场的竞争机制[J]. 发光学报, 2014,35(7): 761-766

MAO De-feng, JIN Peng, LI Wei etc. Competition Mechanism of Local State-internal Polarization Electric Field in Algan Alloy[J]. Chinese Journal of Luminescence, 2014,35(7): 761-766
毛德丰, 金鹏, 李维等. AlGaN合金中局域态和极化电场的竞争机制[J]. 发光学报, 2014,35(7): 761-766 DOI： 10.3788/fgxb20143507.0761.

MAO De-feng, JIN Peng, LI Wei etc. Competition Mechanism of Local State-internal Polarization Electric Field in Algan Alloy[J]. Chinese Journal of Luminescence, 2014,35(7): 761-766 DOI： 10.3788/fgxb20143507.0761.

摘要

通过MOVPE方法生长了不同Al组分的3块Al

N样品，利用稳态光谱和时间分辨光谱对其样品的光学特性进行了分析。鉴于影响氮化物发光性质的极化电场或局域态的单一机制不能充分解释我们的实验现象，提出了局域态-内部极化电场竞争的机制。通过对实验数据的分析，得出如下重要结论：样品PL峰位蓝移的温度起点基本对应于局域态和极化电场起作用的交替点，PL峰位发生蓝移的温度起点与光强-温度曲线的斜率出现明显变化的温度点一致；随着温度的升高，若AlGaN合金样品中PL峰位存在二次蓝移，则说明样品中电场分布不均匀。

Abstract

Three Al

N samples were grown by metal organic chemical vapor phase deposition (MOCVD)

and their optical properties were analyzed by the steady-state and time-resolved photoluminescence (PL) techniques. In view of the fact that the experimental phenomena cant be fully explained by a single mechanism of polarization electric field or that of local state

which remarkably influence luminescent properties of nitrids

the competition mechanism between local state and internal polarization electric field was proposed. By analyzing the experimental data

two crucial conclusions are drawn. First

the temperature starting point of PL peak blue-shift basically corresponds to the shift point between the effect of local state and the effect of polarization electric field. The temperature starting point of PL peak blue-shift is well consistent with the temperature point where the slope of illuminant intensity-temperature curve changes significantly. Then

there is non-uniform polarization electric field distribution in the sample if the PL peak has two blue-shifts with the temperature increasing in AlGaN alloy.

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Keywords

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