煅烧温度对Ba1.2Ca0.64SiO4：0.10Eu，0.06Mn粉体发光性能的影响

李湘祁; 张懿

doi:10.3788/fgxb20143506.0643

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煅烧温度对Ba_1.2Ca_0.64SiO₄：0.10Eu，0.06Mn粉体发光性能的影响

材料合成及性能 | 更新时间：2020-08-12

- 煅烧温度对Ba_1.2Ca_0.64SiO₄：0.10Eu，0.06Mn粉体发光性能的影响
- Influence of Calcination Temperature on The Luminescent Properties of Ba_1.2Ca_0.64SiO₄：0.10Eu,0.06Mn Phosphor
- 发光学报 2014年35卷第6期页码：643-648
- 作者机构：
  
  福州大学材料科学与工程学院,福建福州,350180
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143506.0643
  中图分类号： O482.31
- 收稿日期：2014-01-15，
  
  修回日期：2014-02-15，
  
  纸质出版日期：2014-06-03
- 稿件说明：
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李湘祁, 张懿,. 煅烧温度对Ba1.2Ca0.64SiO4：0.10Eu，0.06Mn粉体发光性能的影响[J]. 发光学报, 2014,35(6): 643-648

LI Xiang-qi, ZHANG Yi,. Influence of Calcination Temperature on The Luminescent Properties of Ba1.2Ca0.64SiO4：0.10Eu,0.06Mn Phosphor[J]. Chinese Journal of Luminescence, 2014,35(6): 643-648
李湘祁, 张懿,. 煅烧温度对Ba1.2Ca0.64SiO4：0.10Eu，0.06Mn粉体发光性能的影响[J]. 发光学报, 2014,35(6): 643-648 DOI： 10.3788/fgxb20143506.0643.

LI Xiang-qi, ZHANG Yi,. Influence of Calcination Temperature on The Luminescent Properties of Ba1.2Ca0.64SiO4：0.10Eu,0.06Mn Phosphor[J]. Chinese Journal of Luminescence, 2014,35(6): 643-648 DOI： 10.3788/fgxb20143506.0643.

摘要

以MCM-41为硅源，在800~1 100℃下合成了Ba

1.2

0.64

SiO

：0.10Eu，0.06Mn荧光粉，研究了煅烧温度对荧光粉发光性能的影响。实验结果表明，Eu

的蓝绿光发射带的强度与宽度随煅烧温度的升高先增大后减小，在1 000℃时强度达到最大。最大发射峰位随温度的升高而发生红移，由800℃和900℃时的450 nm移至1 000℃和1 100℃时的480 nm。Mn

的红光发射起源于Eu

发射光的激发，其强度随温度的升高而增大。与Mn

发生能量传递作用的Eu

主要位于10配位的M（1）格位。

Abstract

1.2

0.64

SiO

:0.10Eu

0.06Mn phosphor was synthesized at 800~1 100℃ by using MCM-41 as Si source. The influence of calcination temperature on the luminescent properties was investigated. The results indicate that the intensity and bandwidth of Eu

blue-green emission increase with temperature at first and then decrease. The sample calcined at 1 000℃ has the highest Eu

emission intensity. The peak maximum shows red-shift from 450 nm to 480 nm when the calcination temperatures changed from 800℃ and 900℃ to 1 000℃ and 1 100℃. The red emission of Mn

arises from the excitation by the Eu

emission and increases with temperature. The Eu

ions which can transfer energy to Mn

are mainly on the ten-coordinated M(1) sites.

关键词

Keywords

references

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