超声波辅助分散法制备镨掺杂钛酸钙荧光效果珠光颜料

周为明; 张华集; 吴楠; 柯梅珍; 袁占辉; 陈庆华; 罗永晋; 钱庆荣

doi:10.3788/fgxb20143505.0578

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超声波辅助分散法制备镨掺杂钛酸钙荧光效果珠光颜料

材料合成及性能 | 更新时间：2020-08-12

- 超声波辅助分散法制备镨掺杂钛酸钙荧光效果珠光颜料
- Preparation of CaTiO₃：Pr³⁺ Pearlescent Pigments with Fluorescent by Ultrasonic-assisted dispersion
- 发光学报 2014年35卷第5期页码：578-584
- 作者机构：
  
  1. 福建师范大学材料科学与工程学院,福建福州,350007
  2. 福建师范大学环境科学与工程学院,福建福州,350007
- 作者简介：
- 基金信息：
  
  福建省产学研重大项目（2011H6005）();教育部留学回国人员科研启动基金（2012-11）资助项目()
- DOI：10.3788/fgxb20143505.0578
  中图分类号： TQ626;O482.31
- 收稿日期：2013-12-23，
  
  修回日期：2014-01-17，
  
  网络出版日期：2014-03-07，
  
  纸质出版日期：2014-05-03
- 稿件说明：
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周为明, 张华集, 吴楠等. 超声波辅助分散法制备镨掺杂钛酸钙荧光效果珠光颜料[J]. 发光学报, 2014,35(5): 578-584

ZHOU Wei-ming, ZHANG Hua-ji, WU Nan etc. Preparation of CaTiO3：Pr3+ Pearlescent Pigments with Fluorescent by Ultrasonic-assisted dispersion[J]. Chinese Journal of Luminescence, 2014,35(5): 578-584
周为明, 张华集, 吴楠等. 超声波辅助分散法制备镨掺杂钛酸钙荧光效果珠光颜料[J]. 发光学报, 2014,35(5): 578-584 DOI： 10.3788/fgxb20143505.0578.

ZHOU Wei-ming, ZHANG Hua-ji, WU Nan etc. Preparation of CaTiO3：Pr3+ Pearlescent Pigments with Fluorescent by Ultrasonic-assisted dispersion[J]. Chinese Journal of Luminescence, 2014,35(5): 578-584 DOI： 10.3788/fgxb20143505.0578.

摘要

采用超声波辅助分散法在云母钛珠光颜料表面原位生成镨掺杂的钛酸钙，制备一种具有荧光效果的珠光颜料。分别采用荧光分光光度计、激光粒度分析仪、X射线衍射仪、冷场扫描电子显微镜和全自动色差计对所制备的样品进行表征。结果表明：在包覆率为5.3%、煅烧温度为900 ℃、煅烧时间为150 min的条件下获得的样品表面光滑平整、粒径分布均匀（平均粒径为24.34 m）。该样品在太阳光下呈白色，其颜色特征参数（

，

）为（89.03，-1.29，1.00）。在304 nm紫外光激发下，样品的发射光谱主峰位于613 nm，呈红光发射，对应于Pr

的

跃迁，平均荧光寿命为154.50 s。

Abstract

CaTiO

:Pr

based pearlescent pigments with fluorescent were prepared by ultrasonic-assisted dispersion technique. The samples were characterized by fluorospectro-photometer

laser particle size analyzer

X-ray diffraction

scanning electron microscopy and automatic colorimeter

respectively. The results show that the sample obtained from TiO

-mica pearlescent pigments with CaO coating ratio 5.3% and calcinating at 900 ℃ for 150 min gives a narrow particle size distribution (the average diameter is 24.34 m) with a homogeneous

dense and smooth surface. It gives white color under the solar light. The characteristic color(

) of the sample is (89.03

-1.29

1.00). The maximum emission wavelength is a red light of 613 nm under the excitation of ultraviolet at 304 nm

corresponding to the transition for

. The average fluorescent lifetime is 154.50 s.

关键词

Keywords

references

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