纳米SrHPO4：RE（RE=Eu3+或Tb3+）磷光体的水热合成与光谱特性

刘丽艳; 于佳音; 于湛; 田鹏; 张向东; 庞然; 李成宇

doi:10.3788/fgxb20143505.0548

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纳米SrHPO₄：RE（RE=Eu³⁺或Tb³⁺）磷光体的水热合成与光谱特性

材料合成及性能 | 更新时间：2020-08-12

- 纳米SrHPO₄：RE（RE=Eu³⁺或Tb³⁺）磷光体的水热合成与光谱特性
- Hydrothermal Synthesis and Optical Properties of SrHPO₄：RE(RE=Eu³⁺ or Tb³⁺) Nanophosphor
- 发光学报 2014年35卷第5期页码：548-552
- 作者机构：
  
  1. 中国科学院长春应用化学研究所稀土化学与物理重点实验室,吉林长春,130022
  2. 沈阳师范大学化学与生命科学学院,辽宁沈阳,110034
  3. 辽宁大学化学院,辽宁沈阳,110036
- 作者简介：
- 基金信息：
  
  辽宁省教育厅科学研究一般项目（L2012393）();沈阳师范大学优秀人才支持计划项目();沈阳师范大学实验中心主任基金（SY200803）资助项目()
- DOI：10.3788/fgxb20143505.0548
  中图分类号： O482.31
- 收稿日期：2013-12-27，
  
  修回日期：2014-02-19，
  
  网络出版日期：2014-03-07，
  
  纸质出版日期：2014-05-03
- 稿件说明：
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刘丽艳, 于佳音, 于湛等. 纳米SrHPO4：RE（RE=Eu3+或Tb3+）磷光体的水热合成与光谱特性[J]. 发光学报, 2014,35(5): 548-552

LIU Li-yan, YU Jia-yin, YU Zhan etc. Hydrothermal Synthesis and Optical Properties of SrHPO4：RE(RE=Eu3+ or Tb3+) Nanophosphor[J]. Chinese Journal of Luminescence, 2014,35(5): 548-552
刘丽艳, 于佳音, 于湛等. 纳米SrHPO4：RE（RE=Eu3+或Tb3+）磷光体的水热合成与光谱特性[J]. 发光学报, 2014,35(5): 548-552 DOI： 10.3788/fgxb20143505.0548.

LIU Li-yan, YU Jia-yin, YU Zhan etc. Hydrothermal Synthesis and Optical Properties of SrHPO4：RE(RE=Eu3+ or Tb3+) Nanophosphor[J]. Chinese Journal of Luminescence, 2014,35(5): 548-552 DOI： 10.3788/fgxb20143505.0548.

摘要

利用水热法合成了-SrHPO

：

（

=Eu

，Tb

）纳米磷光体，并研究了材料的形貌与光谱特性。-SrHPO

纳米粒子为长度90~200 nm的棒状结构，直径为24~36 nm。Eu

和Tb

的掺杂均会降低-SrHPO

的结晶度，并减小其长径比。-Sr

0.97

HPO

：0.03Eu

在395 nm近紫外光的激发下，存在分别由

和

跃迁引起的590 nm和614 nm发射峰，最终发射橙红光。-Sr

0.97

HPO

：0.03Tb

在217 nm近紫外光的激发下，存在由

跃迁引起的543 nm绿光发射。

Abstract

(

=Eu

or Tb

) single-doped -SrHPO

phosphors with nano-scale grain were synthesized by the hydrothermal method in this work. The morphological and optical properties of these phosphors were also investigated. The sizes of the -SrHPO

nanorods are found in the range of 90 to 200 nm in length and 24 to 36 nm in width. The introduction of doping agent ions of Eu

or Tb

decreases both the quality of the crystallinity and the aspect ratio of the matrix. Under the excitation of near ultraviolet light (395 nm)

-Sr

0.97

HPO

:0.03Eu

exhibits two main emission peaks at 590 nm and 614 nm

corresponding to the

(

2) transition of Eu

respectively. Under the excitation of near ultraviolet light (217 nm)

-Sr

0.97

HPO

:0.03Tb

shows only one predominant emission peak at 543 nm originated from the

transition of Tb

. The CIE chromaticity coordinates for -Sr

0.97

HPO

:0.03Eu

phosphor are presented in the orange yellow region and that of -Sr

0.97

HPO

:0.03Tb

phosphor observed in the yellowish green region.

关键词

Keywords

references

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