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光学碱度对Tb3+掺杂Bi2O3-B2O3玻璃发光性能的影响
Effect of Optical Basicity on Luminescence Properties of Tb3+ Doped Bi2O3-B2O3 Glasses
- 发光学报 2014年35卷第4期 页码：413-419
- 作者机构：
1. 陕西科技大学 材料科学与工程学院,陕西 西安,710021
2. 陕西科技大学 机电工程学院,陕西 西安,710021
- 作者简介：
- 基金信息：国际科技合作计划项目（2009DFR50520）资助()
DOI：10.3788/fgxb20143504.0413
中图分类号： O482.31收稿日期：2013-11-22，
修回日期：2013-12-11，
网络出版日期：2014-01-24，
纸质出版日期：2014-04-03
- 稿件说明：
移动端阅览
刘盼, 殷海荣, 郭宏伟等. 光学碱度对Tb<sup>3+</sup>掺杂Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>玻璃发光性能的影响[J]. 发光学报, 2014,35(4): 413-419
LIU Pan, YIN Hai-rong, GUO Hong-wei etc. Effect of Optical Basicity on Luminescence Properties of Tb<sup>3+</sup> Doped Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub> Glasses[J]. Chinese Journal of Luminescence, 2014,35(4): 413-419
刘盼, 殷海荣, 郭宏伟等. 光学碱度对Tb<sup>3+</sup>掺杂Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>玻璃发光性能的影响[J]. 发光学报, 2014,35(4): 413-419 DOI： 10.3788/fgxb20143504.0413.
LIU Pan, YIN Hai-rong, GUO Hong-wei etc. Effect of Optical Basicity on Luminescence Properties of Tb<sup>3+</sup> Doped Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub> Glasses[J]. Chinese Journal of Luminescence, 2014,35(4): 413-419 DOI： 10.3788/fgxb20143504.0413.
摘要
采用熔融法制备了Tb
3+
掺杂的Bi
2
O
3
-B
2
O
3
系统玻璃，使用激发、发射及拉曼光谱分析了光学碱度与玻璃结构及发光性能的关系，同时绘制了Tb
3+
、Bi
3+
和Bi
2+
的能级图。研究结果表明：Tb
3+
掺杂的Bi
2
O
3
-B
2
O
3
玻璃由[BO
3
]、[BiO
3
]、[BO
4
]及[BiO
6
]共同组成，且随着光学碱度由0.63增加到0.93，玻璃的结构逐渐疏松。高的光学碱度使部分Bi
3+
变为Bi
2+
，发出571 nm（
2
P
3/2（2）
2
P
1/2
）的光，Bi
3+
Tb
3+
的能量降低。在光学碱度及Tb
3+
、Bi
3+
和Bi
2+
离子的共同作用下，随着光学碱度的提高，玻璃的发光颜色由黄绿色变为白色。
Abstract
Tb
3+
doped Bi
2
O
3
-B
2
O
3
glasses were prepared by melting technique
and the relationship of optical basicity
luminescence properties and structure were investigated by excitation
emission and Raman spectra. Energy level structures of Tb
3+
Bi
3+
and Bi
2+
ions were plotted for the excitation and energy transfer routes. The results show that Tb
3+
doped Bi
2
O
3
-B
2
O
3
glasses consist of [BO
3
]
[BiO
3
]
[BO
4
]
and [BiO
6
] together as basic structural groups
and its structure turn looses as the optical basicity increasing from 0.63 to 0.93. Based on energy matching condition
571 nm emission ascribed to
2
P
3/2(2)
2
P
1/2
transition of Bi
2+
reduces from Bi
3+
ions at high optical basicity of glasses
which decreases the transition of Bi
3+
Tb
3+
. The luminescent properties of Tb
3+
doped Bi
2
O
3
-B
2
O
3
glasses are quite sensitive to optical basicity
the luminescence color turns to white from yellow-green with the optical basicity increasing.
关键词
Keywords
references
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