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1. 发光学及应用国家重点实验室 中国科学院长春光学精密机械与物理研究所,吉林 长春,130033
2. 中国科学院大学, 北京 100049
收稿日期:2013-10-08,
修回日期:2013-11-09,
纸质出版日期:2014-03-03
移动端阅览
佐婧, 郭晓阳, 刘星元. 基于旋涂法和电子束蒸发法制备的V<sub>2</sub>O<sub>5</sub>/Ag/V<sub>2</sub>O<sub>5</sub>叠层透明导电薄膜[J]. 发光学报, 2014,35(3): 360-365
ZUO Jing, GUO Xiao-yang, LIU Xing-yuan. V<sub>2</sub>O<sub>5</sub>/Ag/V<sub>2</sub>O<sub>5</sub> Multilayer Transparent Conductive Films Based on Sol-gel and Electron Beam Evaporation Techniques[J]. Chinese Journal of Luminescence, 2014,35(3): 360-365
佐婧, 郭晓阳, 刘星元. 基于旋涂法和电子束蒸发法制备的V<sub>2</sub>O<sub>5</sub>/Ag/V<sub>2</sub>O<sub>5</sub>叠层透明导电薄膜[J]. 发光学报, 2014,35(3): 360-365 DOI: 10.3788/fgxb20143503.0360.
ZUO Jing, GUO Xiao-yang, LIU Xing-yuan. V<sub>2</sub>O<sub>5</sub>/Ag/V<sub>2</sub>O<sub>5</sub> Multilayer Transparent Conductive Films Based on Sol-gel and Electron Beam Evaporation Techniques[J]. Chinese Journal of Luminescence, 2014,35(3): 360-365 DOI: 10.3788/fgxb20143503.0360.
利用溶胶-凝胶技术与电子束蒸镀相结合的方法在常温下制备了叠层V
2
O
5
/Ag/V
2
O
5
(VAV)透明导电薄膜,研究了各层薄膜厚度对叠层结构光电特性的影响。用原子力显微镜、紫外-可见光分光光度计、四探针电阻仪及开尔文探针对样品的表面形貌、光电性能及功函数等性质进行了表征。实验结果表明,该薄膜具有良好的光学和电学性质,可见光(380~780 nm)平均透过率达75%,迁移率为16.89 cm
2
/(Vs),载流子浓度为-1.04310
22
cm
-3
,方块电阻值为15.1 /□,功函数为5.17 eV。该制备方法降低了V
2
O
5
薄膜的工艺制备难度,为该材料在太阳能电池中的应用创造了良好的前期基础。
V
2
O
5
/Ag/V
2
O
5
(VAV) multi-layer transparent conductive film was prepared by the combination of sol-gel technique and electron beam evaporation at room temperature. The effects of each layer's thickness on photoelectrical properties and surface appearance of multi-layers were studied by atomic force microscope
UV-Vis spectrophotometer
four-point probe method and Kelvin probe. The experiments results reveal that the multi-layer transparent conductive film has desirable photo-electrical properties with average transmission of 75%(380~780 nm)
mobility of 16.89 cm
2
/(Vs)
carrier concentration of -1.04310
22
cm
-3
the sheet resistance of 15.1 /□
and work function of 5.17 eV. This method reduces the difficulty of fabricating V
2
O
5
/Ag/V
2
O
5
multi-layer films
providing a kind of promising transparent electrode for solar cells.
Yu S H, Jia C H, Zheng H W, et al. High quality transparent conductive SnO2/Ag/SnO2 tri-layer films deposited at room temperature by magnetron sputtering[J]. Mater. Lett., 2012, 85:68-70. [2] Zhang J N, Li Y T, Fan Y, et al. Study of new transparent conductive film with erbium fluoride doped indium oxide[J]. Chin. J. Lumin.(发光学报), 2012, 33(12):1295-1298 (in Chinese). [3] Hutter O S, Stec H M, Hatton R A, et al. An indium-free low work function window electrode for organic photovoltaics which improves with in-situ oxidation[J]. Adv. Mater., 2013, 25(2):284-288. [4] Forrest S R. The path to ubiquitous and low-cost organic electronic appliances on plastic[J]. Nature, 2004, 428(6986):911-918. [5] Holland J, Siddal G. Heat-reflecting windows using gold and bismuth oxide films[J]. J. Appl. Phys., 1958, 9(9):359-361. [6] Sergeant N P, Hadipour A, Niesen B, et al. Design of transparent anodes for resonant cavity enhanced light harvesting in organic solar cells[J]. Adv. Mater., 2012, 24(6):728-732. [7] Liu P, Zhang J G, Turner J A, et al. Fabrication of LiV2O5 thin-film electrodes for rechargeable lithium batteries[J]. Solid State Ionics, 1998, 111(1-2):145-151. [8] Kloppel A, Kriegseis W, Meyer B K, et al. Dependence of the electrical and optical behaviour of ITO-silver-ITO multilayers on the silver properties[J]. Thin Solid Films, 2000, 365(1):139-146. [9] Guo X Y, Lin J, Chen H, et al. Ultrathin and efficient flexible polymer photovoltaic cells based on stable indium-free multilayer transparent electrodes[J]. J. Mater. Chem., 2012, 22(33):17176-17182. [10] Wang N, Liu X X, Liu X Y. Ultraviolet luminescent, high-effective-work-function LaTiO3-doped indium oxide and its effects in organic optoelectronics[J]. Adv. Mater., 2010, 22(19):2211-2215. [11] Tseng C T, Cheng Y H, Lee M C M. Study of anode work function modified by self-assembled monolayers on pentacene/fullerene organic solar cells[J]. Appl. Phys. Lett., 2007, 91(23):233510-1-3. [12] Zilberberg K, Trost S, Meyer J, et al. Inverted organic solar cells with sol-gel processed high work-function vanadium oxide hole-extraction layers[J]. Adv. Funct. Mater., 2011, 21(24):4776-4783.
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