新型蒽衍生物蓝光材料的合成及光电性能研究

祝艳龙; 徐茂梁; 姜菡雨; 刘亚东; 张异光; 孟庆华

doi:10.3788/fgxb20143503.0354

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新型蒽衍生物蓝光材料的合成及光电性能研究

器件制备及器件物理 | 更新时间：2020-08-12

- 新型蒽衍生物蓝光材料的合成及光电性能研究
- Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative
- 发光学报 2014年35卷第3期页码：354-359
- 作者机构：
  
  1. 西安近代化学研究所, 陕西西安 710065
  2. 长春工程职业技术学院,吉林长春,130017
- 作者简介：
- 基金信息：
  
  西安市经开区科技创新项目（JKZD110532）资助()
- DOI：10.3788/fgxb20143503.0354
  中图分类号： TN383+.1
- 收稿日期：2013-11-07，
  
  修回日期：2013-12-25，
  
  纸质出版日期：2014-03-03
- 稿件说明：
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祝艳龙, 徐茂梁, 姜菡雨等. 新型蒽衍生物蓝光材料的合成及光电性能研究[J]. 发光学报, 2014,35(3): 354-359

ZHU Yan-long, XU Mao-liang, JIANG Han-yu etc. Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative[J]. Chinese Journal of Luminescence, 2014,35(3): 354-359
祝艳龙, 徐茂梁, 姜菡雨等. 新型蒽衍生物蓝光材料的合成及光电性能研究[J]. 发光学报, 2014,35(3): 354-359 DOI： 10.3788/fgxb20143503.0354.

ZHU Yan-long, XU Mao-liang, JIANG Han-yu etc. Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative[J]. Chinese Journal of Luminescence, 2014,35(3): 354-359 DOI： 10.3788/fgxb20143503.0354.

摘要

通过引入具有电子传输性能的噁二唑衍生物支链，采用Suzuki偶联反应，设计并合成了一种新型的蒽衍生物蓝光材料，同时研究了它的光学性能、热学性能、电化学性能以及成膜性。研究结果表明，该化合物在四氢呋喃溶液中发射蓝色荧光，最大发射波长为433 nm，其荧光量子效率为0.94，是9，10-二（-萘基）蒽（ADN）的1.17倍。该化合物薄膜经过100 ℃高温烘烤3 h，依然保持连续、均一、平整的无定型结构，是制备长寿命、高效率OLED的很有潜力的材料。

Abstract

Using Suzuki coupling reaction

a novel blue-emitting anthracene-based derivatives was designed and synthesized by introducing the electron transport branch of oxadiazole derivatives. The optical properties

thermal properties

electrochemical properties

and surface morphology of the compound were characterized. The maximum emission wavelength of this compound is 433 nm in tetrahydrofuran

and the fluorescence quantum yields is 0.94 which is 1.17 times than that of 9

10-di(2-naphthyl)anthracene. The film of this compound is continuous

compact

and smooth after annealing at 100 ℃ for 3 h

which is suitable to prepare long life and high efficiency OLED devices.

关键词

Keywords

references

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