一种新型罗丹明类荧光分子探针及其对Fe(Ⅲ)的选择性识别

成春文; 王风贺; 段伦超; 雷武; 夏明珠; 王风云

doi:10.3788/fgxb20143501.0125

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一种新型罗丹明类荧光分子探针及其对Fe(Ⅲ)的选择性识别

发光学应用及交叉前沿 | 更新时间：2020-08-12

- 一种新型罗丹明类荧光分子探针及其对Fe(Ⅲ)的选择性识别
- Synthesis of A New Fluorescent Probe Based on Rhodamine and Its Performance in Selective Recognition of Fe(Ⅲ)
- 发光学报 2014年35卷第1期页码：125-130
- 作者机构：
  
  1. 南京师范大学环境科学与工程系,江苏南京,210023
  2. 南京理工大学工业化学研究所, 江苏南京 210094
- 作者简介：
- 基金信息：
  
  国家自然科学基金（41101287）();江苏省科技支撑计划（BE2012758）();江苏高校优势学科建设工程资助项目()
- DOI：10.3788/fgxb20143501.0125
  中图分类号： O657;O482.31
- 收稿日期：2013-08-23，
  
  修回日期：2013-09-19，
  
  纸质出版日期：2014-01-03
- 稿件说明：
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成春文, 王风贺, 段伦超, 雷武, 夏明珠, 王风云. 一种新型罗丹明类荧光分子探针及其对Fe(Ⅲ)的选择性识别[J]. 发光学报, 2014,35(1): 125-130

CHENG Chun-wen, WANG Feng-he, DUAN Lun-chao, LEI Wu, XIA Ming-zhu, WANG Feng-yun. Synthesis of A New Fluorescent Probe Based on Rhodamine and Its Performance in Selective Recognition of Fe(Ⅲ)[J]. Chinese Journal of Luminescence, 2014,35(1): 125-130
成春文, 王风贺, 段伦超, 雷武, 夏明珠, 王风云. 一种新型罗丹明类荧光分子探针及其对Fe(Ⅲ)的选择性识别[J]. 发光学报, 2014,35(1): 125-130 DOI： 10.3788/fgxb20143501.0125.

CHENG Chun-wen, WANG Feng-he, DUAN Lun-chao, LEI Wu, XIA Ming-zhu, WANG Feng-yun. Synthesis of A New Fluorescent Probe Based on Rhodamine and Its Performance in Selective Recognition of Fe(Ⅲ)[J]. Chinese Journal of Luminescence, 2014,35(1): 125-130 DOI： 10.3788/fgxb20143501.0125.

摘要

以罗丹明B、乙二胺和乙二醛为反应原料，合成了一种新型的荧光增强型识别Fe

的分子探针（fluorescent probe，FP）。用核磁和质谱对其分子结构进行了表征，并通过荧光光谱研究了FP对Al

、Pb

、Cu

、Cd

、Mn

、Hg

、Mg

、Ca

、K

、Na

等不同金属离子的识别性能。研究结果表明：在纯甲醇溶剂中，探针FP对Fe

的识别具有较好的选择性，且基本不受其他金属离子的干扰；通过Jobs曲线可知，探针FP与Fe

的络合比为1：3；Fe

浓度在410

-4

~510

-3

mol/L范围内时，探针FP的荧光强度与Fe

浓度具有良好的线性关系，线性相关系数为0.995 3。

Abstract

A novel fluorescent probe (FP) for detecting Fe

was synthesized from rhodamine B

ethylenediamine and glyoxal. Its molecule structure of FP was characterized by

H NMR and MS

and its fluorescent properties of FP in detecting Fe

and other different metal ions were investigated by fluorescent spectroscopy. The experimental results show that FP has a higher selective recognition for Fe

in CH

and other metal ions

such as Al

and Na

have no effects on its recognition for Fe

. The complexation ratio of FP/Fe

is l:3 from the method of Jobs plot by UV-Vis spectroscopy. When the concentration of Fe

is 410

-4

~510

-3

mol/L

there is a good linear relationship between the fluorescence intensity of FP and the concentration of Fe

and the linear correlation coefficient is 0.995 3. The analysis reveals that FP can be used as a fluorescent sensor for the selective detection of Fe

关键词

Keywords

references

Czarnik A W, Dujols V, Ford F. A long-wavelength fluorescent chemodosimeter selective for Cu(Ⅱ) ion in water[J]. J. Am. Chem. Soc., 1997, 119(31):7386-7387.[2] Li C Y, Zhang X B, Qiao L Z, et al. Naphthalimide-porphyrin hybrid based ratiometric bioimaging probe for Hg2+:Well-resolved emission spectra and unique specificity[J]. Anal. Chem., 2009, 81(24):9993-10001.[3] Atsushi N, Ryousuke Y, Takeshi O, et al. BODIPY-based chain transfer agent:Reversibly thermoswitchable luminescent gold nanoparticle stabilized by BODIPY-terminated water-soluble polymer[J]. Langmuir, 2010, 26(19):15644-15649.[4] Jung H S, Ko K C, Kim G H, et al. Coumarin-based thiol chemosensor: Synthesis, turn-on mechanism, and its biological application[J]. Org. Lett., 2011, 13(6):1498-1501.[5] Chen X Q, Yoon J Y, Kim J S, et al. Fluorescent chemosensors based on spiroring-opening of xanthenes and related derivatives[J]. Chem. Rev., 2012, 112(3):1910-1956.[6] Kumar M, Kumar N, Bhalla V, et al. Naphthalimide appended rhodamine derivative: Through bond energy transfer for sensing of Hg2+ ions[J]. Org. Lett., 2011, 13(6):1422-1425.[7] Yang Z, She M Y, Li J L, et al. Three rhodamine-based "off-on" chemosensors with high selectivity and sensitivity for Fe3+ imaging in living cells[J]. J. Org. Chem., 2012, 77(2):1143-1147.[8] Liu J L, Li C Y, Li F Y. Fluorescence turn-on chemodosimeter-functionalized mesoporous silica nanoparticles and their application in cell imaging[J]. J. Mater. Chem., 2011, 21(20):7175-7181.[9] Liu W M, Zhang X L, Li H P, et al. Dithiolane linked thiorhodamine dimer for Hg2+ recognition in living cells[J]. Org. Biomol. Chem., 2009, 7(4):660-664.[10] Tae J S, Yang Y K, Lee S. A gold(Ⅲ) ion-selective fluorescent probe and its application to bioimagings[J]. Org. Lett., 2009, 11(24):5610-5613.[11] Chen X Q, Yoon J Y, Park S, et al. Hg2+ selective fluorescent and colorimetric sensor: Its crystal structure and application to bioimaging[J]. Org. Lett., 2008, 10(12):5235-5238.[12] Zhang M, Zhang J P, Zhu M W, et al. A selective turn-on fluorescent sensor for Fe Ⅲ and application to bioimaging[J]. Tetrahedron Lett., 2007, 48(21):3709-3712.[13] Tae J S, Ko S K, Yang Y K, et al. In vivo monitoring of mercury ions using a rhodamine-based molecular probe[J]. J. Am. Chem. Soc., 2006, 128(43):14150-14155.[14] Amrita C, Santra M, Ahn K H, et al. Selective fluorogenic and chromogenic probe for detection of silver ions and silver nanoparticles in aqueous media[J]. J. Am. Chem. Soc., 2009, 131(6):2040-2041.[15] Hu M M, Fan J L, Peng X J, et al. Fluorescent probe visual detection of copper ion in aqueous solution[J]. Chin. J. Anal. Chem.(分析化学), 2011, 39(8):1195-1200 (in Chinese).[16] Nicolas J, Veronica S M, Giuseppe M, et al. Fluorescently labeled protein-polymer bioconjugates using protein-derived macroinitiators from living radical polymerization[J]. ACS Symp. Series (Polymers for Biomedical Applications), 2008, 977:78-94.[17] Banerjee A, Shuai Y, Dixit R, et al. Concentration dependence of fluorescence signal in a microfluidic fluorescence detector[J]. J. Lumin., 2010, 130(6):1095-1100.[18] Li N, Liu M L, Shi J L, et al. Recent progress in rhodamine-based "off-on" fluorescent probes[J]. Chin. J. Org. Chem.(有机化学), 2011, 31(1):39-53(in Chinese).[19] Zhang X, Shiraishi Y, Hirai T. Cu(Ⅱ)-selective green fluorescence of a rhodamine diacetic acid conjugate[J]. Org. Lett., 2007, 9(24):5039-5042.

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