插入电荷控制层对蓝色OLED发光性能的提高

王丽; 吴晓明; 华玉林; 肖志慧; 张欣; 辛利文; 印寿根

doi:10.3788/fgxb20143501.0085

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插入电荷控制层对蓝色OLED发光性能的提高

器件制备及器件物理 | 更新时间：2020-08-12

- 插入电荷控制层对蓝色OLED发光性能的提高
- Improvement of Performance of A Blue Organic Light-emitting Diode by Inserting Charge Control Layers
- 发光学报 2014年35卷第1期页码：84-89
- 作者机构：
  
  天津理工大学材料科学与工程学院, 显示材料与光电器件教育部重点实验室, 天津市光电显示材料与器件重点实验室天津,300384
- 作者简介：
- 基金信息：
  
  国家自然科学基金（60906022）();天津市自然科学基金（10JCYBJC01100）();天津市高等学校科技发展基金计划重点项目（2011ZD02）资助()
- DOI：10.3788/fgxb20143501.0085
  中图分类号： TN383+.1
- 收稿日期：2013-07-24，
  
  修回日期：2013-09-17，
  
  纸质出版日期：2014-01-03
- 稿件说明：
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王丽, 吴晓明, 华玉林, 肖志慧, 张欣, 辛利文, 印寿根. 插入电荷控制层对蓝色OLED发光性能的提高[J]. 发光学报, 2014,35(1): 84-89

WANG Li, WU Xiao-ming, HUA Yu-lin, XIAO Zhi-hui, ZHANG Xin, XIN Li-wen, YIN Shou-gen. Improvement of Performance of A Blue Organic Light-emitting Diode by Inserting Charge Control Layers[J]. Chinese Journal of Luminescence, 2014,35(1): 84-89
王丽, 吴晓明, 华玉林, 肖志慧, 张欣, 辛利文, 印寿根. 插入电荷控制层对蓝色OLED发光性能的提高[J]. 发光学报, 2014,35(1): 84-89 DOI： 10.3788/fgxb20143501.0085.

WANG Li, WU Xiao-ming, HUA Yu-lin, XIAO Zhi-hui, ZHANG Xin, XIN Li-wen, YIN Shou-gen. Improvement of Performance of A Blue Organic Light-emitting Diode by Inserting Charge Control Layers[J]. Chinese Journal of Luminescence, 2014,35(1): 84-89 DOI： 10.3788/fgxb20143501.0085.

摘要

用蓝色有机荧光材料N

，N

-tetrap-tolylchrysene-6，12-diamine （DNCA）作为发光层，在发光层中间以及发光层与电子传输层之间插入2-methyl-9，10-

（2-napthyl）anthracene （MADN）和9，10-

（2-naphthyl）anthracene （ADN）作为电荷控制层，制备了结构为ITO/NPB（40 nm）/DNCA（15 nm）/MADN（3 nm）/DNCA（15 nm）/ADN（3 nm）/Bphen（30 nm）/LiF（0.8 nm）/Al（120 nm）的蓝色有机电致发光器件（OLED）。该器件的最大电流效率和最大亮度分别为5.6 cd/A和23 310 cd/m

。与传统的单发光层器件相比，最大电流效率和最大亮度分别提高了70%和87%。器件发光性能的提高可归结于两个电荷控制层在整个器件中的协同作用。第一电荷控制层MADN的作用主要是将发光层区域分成两个部分，从而扩大了激子在发光层中的复合区域；第二电荷控制层ADN可以有效地将空穴限制在发光层中，避免了激子在电子传输层中形成的无辐射跃迁从而提高了器件的发光性能。

Abstract

The performance of blue fluorescent organic light-emitting device (OLED) with N

-tetrap-tolylchrysene-6

12-diamine (DNCA) as emitting layer (EML) was improved by inserting 2-methyl-9

10-

(2-napthyl)anthracene (MADN) 9

10-

(2-naphthyl)anthracene (ADN) as charge control layers (CCLs) into the device. For the optimum device with CCL structure of ITO/NPB (40 nm)/DNCA(15 nm)/MADN(3 nm)/DNCA(15 nm)/ADN(3 nm)/Bphen(30 nm)/LiF(0.8 nm)/Al(120 nm)

the maximal current efficiency of 5.6 cd/A and the maximal luminance of 23 310 cd/m

were achieved

which were enhanced by 70% and 87% comparing with the control device (CD) without CCLs

respectively. The performance improvement of the device can be attributed to the synergistic action (function) of the two CCLs. By utilizing the CCL structure

the original emitting zone can be separated into two parts by inserting MADN in the first EML

and the exciton formation region can also be broadened accordingly. Therefore

the excitons radiative process can be utilized to a great extent. Meanwhile

the holes can be effectively confined in the second EML by inserting ADN between the EML and ETL

which can prevent the excitons non-radiative process in the ETL so as to improve the device performance.

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references

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