荧光粉MPO4：Eu3+,Bi3+/Tb3+ (M=La,Gd,Y) 的结构及发光性能研究

金叶; 王庆平

doi:10.3788/fgxb20143501.0061

您当前的位置：

首页 >

文章列表页 >

荧光粉MPO₄：Eu³⁺,Bi³⁺/Tb³⁺ (M=La,Gd,Y) 的结构及发光性能研究

材料合成及性能 | 更新时间：2020-08-12

- 荧光粉MPO₄：Eu³⁺,Bi³⁺/Tb³⁺ (M=La,Gd,Y) 的结构及发光性能研究
- Crystal Structure and Photoluminescence Properties of MPO₄：Eu³⁺,Bi³⁺/Tb³⁺ (M=La,Gd,Y) Phosphors
- 发光学报 2014年35卷第1期页码：61-65
- 作者机构：
  
  1. 重庆理工大学光电信息学院重庆,400054
  2. 重庆大学材料学院重庆,400044
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11104366，11104365）();重庆市自然科学基金（CSTC2011jjA50015，CSTC2011BB4112）资助项目()
- DOI：10.3788/fgxb20143501.0061
  中图分类号： O482.31;O614.33
- 收稿日期：2013-08-16，
  
  修回日期：2013-09-15，
  
  纸质出版日期：2014-01-03
- 稿件说明：
移动端阅览
金叶, 王庆平. 荧光粉MPO4：Eu3+,Bi3+/Tb3+ (M=La,Gd,Y) 的结构及发光性能研究[J]. 发光学报, 2014,35(1): 61-65

JIN Ye, WANG Qing-ping. Crystal Structure and Photoluminescence Properties of MPO4：Eu3+,Bi3+/Tb3+ (M=La,Gd,Y) Phosphors[J]. Chinese Journal of Luminescence, 2014,35(1): 61-65
金叶, 王庆平. 荧光粉MPO4：Eu3+,Bi3+/Tb3+ (M=La,Gd,Y) 的结构及发光性能研究[J]. 发光学报, 2014,35(1): 61-65 DOI： 10.3788/fgxb20143501.0061.

JIN Ye, WANG Qing-ping. Crystal Structure and Photoluminescence Properties of MPO4：Eu3+,Bi3+/Tb3+ (M=La,Gd,Y) Phosphors[J]. Chinese Journal of Luminescence, 2014,35(1): 61-65 DOI： 10.3788/fgxb20143501.0061.

摘要

采用高温固相法合成了一系列

：Eu

，Bi

（

=La，Gd，Y）及

：Tb

（

=La，Gd，Y）荧光粉材料，用X射线衍射（XRD）仪对样品结构进行了表征。所合成的LaPO

和GdPO

属单斜晶系，而YPO

属体心立方晶系。用Diamond软件对结构进行分析并绘出了晶胞结构。对样品发光性质的研究结果表明，虽然

（

=La，Gd，Y）均属于正磷酸盐，但由于晶格结构不同，其发光性质也不同。立方晶系的YPO

更有利于掺入其中的稀土离子的发光，Bi

离子的引入能够明显改善样品的发光性能。

Abstract

:Eu

/Tb

(

=La

Y) phosphors were synthesized by conventional solid state reaction. The structures of the samples were characterized by X-ray diffraction (XRD). The results indicate that YPO

crystallizes is cubic structure while LaPO

and GdPO

are monoclinic structure. The difference between the emission spectra of YPO

:0.04Eu

and LaPO

:0.04Eu

indicates that the Eu

ions occupy nonequivalent sites in differrent material. The cubic structure is better for the luminescence of the doped RE ions than monoclinic structure. YPO

:0.04Eu

exhibits strong absorption at 394 nm and intense red emission. The same result can be obtained while the Eu

ions are changed into Tb

ions. The introduction of Bi

ions can significantly improve the photoluminescence properties of the phosphors.

关键词

Keywords

references

Rambabu U, Buddhudu S. Optical properties of LnPO4:Eu3+ (Ln=Y, La and Gd) powder phosphors[J]. Opt. Mater., 2001, 17(3):401-408.[2] Li Y, Shi Y, Wang Y. Crystal structure and photoluminescence properties of CaSr2Al2O6:Eu2+ phosphors[J]. ECS J. Solid State Sci. Technol., 2013, 2(9):R208-R212.[3] Luwang M N, Ningthoujam R S, Srivastava S K, et al. Disappearance and recovery of luminescence in Bi3+, Eu3+ codoped YPO4 nanoparticles due to the presence of water molecules up to 800 ℃[J]. J. Am. Chem. Soc., 2011, 133(9):2998-3004.[4] Zhang C, Liang H, Zhang S, et al. Efficient sensitization of Eu3+ emission by Tb3+ in Ba3La(PO4)3 under VUV-UV excitation: Energy transfer and tunable emission[J]. J. Phys. Chem. C, 2012, 116(30):15932-15937.[5] Fang Y, Xu A, Song R, et al. Systematic synthesis and characterization of single crystal lanthanide orthophosphate nanowires[J]. J. Am. Chem. Soc., 2003, 125(51):16205-16034.[6] Qi Z, Shi C, Zhang W, et al. Local structure and luminescence of nanocrystalline Y2O3:Eu[J]. Appl. Phys. Lett., 2002, 81(15):2857-2859.[7] Huang C, Chan T, Liu W, et al. Crystal structure of blue-white-yellow color-tunable Ca4Si2O7F2:Eu2+, Mn2+ phosphor and investigation of color tenability through energy transfer for single-phase white-light near-ultraviolet LEDs[J]. J. Mater. Chem., 2012, 22:20210-20216.[8] Hong G Y. Fundamental and Application of Rare Earth Luminescent Materials[M]. Beijing: Science Press, 2011:67.[9] Zhou J, Su M. Studies on the luminescence of Eu3+-doped lanthanum phosphate[J]. Chem. J. Chin. Univ.(高等化学学报), 1993, 14(3):314-316 (in Chinese).[10] Beall G W, Boatner L A, Mullica D F, et al. The structure of cerium orthophosphate, a synthetic analogue of monazite[J]. J. Inorg. Nucl. Chem., 1981, 43(1):101-105.[11] Li C X, Hou Z Y, Zhang C M, et al. Controlled synthesis of Ln3+(Ln=Tb, Eu, Dy) and V5+ ion-doped YPO4 nano-/microstructures with tunable luminescent colors[J]. Chem. Mater., 2009, 21(19):4598-4607.[12] Park W J, Jung M K, Im S J, et al. Phptoluminescence characteristics of energy transfer between Bi3+ and Eu3+ in LnVO4:Eu, Bi(Ln=Y, La, Gd)[J]. Colloids Surf. A, 2008, 373:313-314.[13] Park W J, Yoon S G, Yoon D H. Photoluminescence properties of Y2O3 co-doped with Eu and Bi compounds as red-emitting phosphor for white LED[J]. J. Electroceram., 2006, 17(1):41-44.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

共沉淀法制备不球磨稀土磷酸盐绿色荧光粉研究

Ce³⁺掺杂Ba₃Y₂(BO₃)₄荧光粉发光性能及应用

Mn⁴⁺激活氟化物荧光粉水解劣化评价方法

Al/Ga离子替换提升Ni²⁺掺杂尖晶石结构MgAl_xGa_2-_xO₄近红外二区发光特性

F/O阴离子取代调控ZnGa₂O₄∶Cr³⁺近红外发光