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1. 长春理工大学 材料科学与工程学院,吉林 长春,130022
2. 吉林师范大学信息技术学院 功能材料物理与化学教育部重点实验室,吉林 四平,136000
收稿日期:2013-07-23,
修回日期:2013-08-29,
纸质出版日期:2013-12-10
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张刚, 田晓萃, 高永慧, 常喜, 汪津, 姜文龙, 张希艳. 荧光染料掺杂的高效率、高亮度白色有机电致发光器件[J]. 发光学报, 2013,34(12): 1603-1606
ZHANG Gang, TIAN Xiao-cui, GAO Yong-hui, CHANG Xi, WANG Jin, JIANG Wen-long, ZHANG Xi-yan. High Efficiency and Luminance White OLED Based on Fluorescence Dopant[J]. Chinese Journal of Luminescence, 2013,34(12): 1603-1606
张刚, 田晓萃, 高永慧, 常喜, 汪津, 姜文龙, 张希艳. 荧光染料掺杂的高效率、高亮度白色有机电致发光器件[J]. 发光学报, 2013,34(12): 1603-1606 DOI: 10.3788/fgxb20133412.1603.
ZHANG Gang, TIAN Xiao-cui, GAO Yong-hui, CHANG Xi, WANG Jin, JIANG Wen-long, ZHANG Xi-yan. High Efficiency and Luminance White OLED Based on Fluorescence Dopant[J]. Chinese Journal of Luminescence, 2013,34(12): 1603-1606 DOI: 10.3788/fgxb20133412.1603.
制备了结构为 ITO/NPB(30 nm)/Rubrene(0.2 nm)/CBP:Bczvbi(8 nm,
x
%)/Bphen(30 nm)/Cs
2
CO
3
:Ag
2
O(2 nm,20%)/Al(100 nm)的器件。研究了Bczvbi掺杂浓度(
x
=5,10,15)对白光器件性能的影响。综合利用发光层中主客体之间的能量转移和空穴阻挡层的空穴阻挡特性,得到了高效率、高亮度的白色有机电致发光器件。当Bczvbi的掺杂质量分数为10%时,器件的效率和亮度都为最大。驱动电压为7 V时,最大电流效率为4.61 cd/A;驱动电压为9 V时,最大亮度为21 240 cd/m
2
。当驱动电压从4 V增加到9 V时,色坐标从(0.36,0.38)变化为(0.27,0.29),均处于白光区域。
The OLED devices were fabricated with the structure of ITO/NPB (30 nm)/Rubrene (0.2 nm)/CBP:Bczvbi (8 nm
x
%)/Bphen (30 nm)/Cs
2
CO
3
:Ag
2
O (2 nm
20%)/Al (100 nm). The effect of different CBP:Bczvbi doping concentration (
x
=5
10
15) on the properties of white light device was studied. High luminance and efficiency white organic light-emitting diodes (OLEDs) were obtained comprehensively utilizing the energy transfer between the host and the guset in the luminous layer and the hole-blocking characteristics. The device had the maximum efficiency and luminance when the mass fraction of Bczvbi was 10%. This device had a maximum current efficiency of 4.61 cd/A at 7 V and maximum luminance of 21 240 cd/m
2
at 9 V. The CIE coordinates of the device were well within the white region when the voltage changed from 4 V to 9 V.
Sepeai S, Salleh M M, Yahaya M, et al. Improvement of white organic light emitting diode performances by an annealing process[J]. Thin Solid Films, 2009, 517(16):4679-4683.[2] Zhang J, Zhang F H, Yan H G. High efficiency white fluorescent organic light-emitting diodes with HAT-CN hole injection layer[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2011, 26(4):490-495 (in Chinese).[3] Hou L T, Wang P, Wang B, et al. High efficiency tandem organic light-emitting diodes with effective charge generation layer[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2011, 26(2):142-146 (in Chinese).[4] Sasabe H, Takamatsu J I, Motoyama T, et al. High-performance white OLEDs with high color-rendering index for next-generation solid-state lighting[J]. Adv. Mater., 2010, 22:5003-5007.[5] Blochwitz-Nimoth J, Langguth O, Murano S, et al. PIN-OLEDs for active-matrix-display use[J]. J. Soc. Inf. Disp., 2010, 18(8):596-605.[6] Komoda T, Ide N, Varutt K, et al. High-performance white OLEDs with high color-rendering index for next-generation solid-state lighting[J]. J. Soc. Inf. Disp., 2011, 19(11):838-846.[7] Yang H S, Wu L S, Pan Y Z. White organic light-emitting device based on phosphorescent emissive layer combined with fluorescent emitter[J]. J. OptoelectronicsLaser (光电子激光), 2013, 24(4):673-678 (in Chinese).[8] Ma Y, Han W, Zhang F H, et al. White organic light-emitting diodes based on mixed doping emitting layer[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2011, 26(1):40-43 (in Chinese).[9] Zhang Y H, Wu Y Z, Ma J J, et al. Ideal white organic electroluminescent device realized by inserting an ultra thin layer[J]. Chin. J. Lumin.(发光学报), 2013, 34(6):748-752 (in Chinese).[10] Li L, Yu J S, Wang J, et al. Higll-efficiency white phosphorescent organic light-emitting diodes[J]. Acta Phys.-Chim. Sinica (物理化学学报), 2007, 23(10):1493-1497 (in Chinese).[11] Zhou L, Deng R P, Hao Z M, et al. Efficient white electroluminescent device with stable emission spectrum[J]. Acta Chim. Sinica (化学学报), 2012, 70(18):1904-1908 (in Chinese).[12] Ding G Y, Jiang W L, Wang J, et al. White organic light-emitting devices based on a novel CzHQZn[J]. J. OptoelectronicsLaser (光电子激光), 2009, 20(6):717-780 (in Chinese).[13] Jiang W L, Ding G Y, Wang J, et al. White light devices fabricated by using DPVBi hole block and luminous characters[J]. Semicond. Optoelectron.(半导体光电), 2006, 27(6):701-703 (in Chinese).
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