白光LED用红色荧光粉Sr2EuxGd1-xAlO5的制备及其发光性质

孙晓园; 贺小光; 于立军; 高允锋; 郭锦泉; 骆永石; 张家骅; 吴春雷

doi:10.3788/fgxb20133411.1474

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白光LED用红色荧光粉Sr₂Eu_xGd_1-xAlO₅的制备及其发光性质

材料合成及性能 | 更新时间：2020-08-12

- 白光LED用红色荧光粉Sr₂Eu_xGd_1-xAlO₅的制备及其发光性质
- Preparation and Photoluminescence Properties of Red Emitting Sr₂Eu_xGd_1-xAlO₅ Phosphor for White LED
- 发光学报 2013年34卷第11期页码：1474-1478
- 作者机构：
  
  1. 发光学及应用国家重点实验室中国科学院长春光学精密机械与物理研究所,吉林长春,130033
  2. 长春师范大学物理学院,吉林长春,130032
  3. 牡丹江师范学院理学院, 黑龙江牡丹江 157011
- 作者简介：
- 基金信息：
  
  吉林省科技发展计划(201101106)();长春师范学院自然科学基金(长师院自科合字[2009]第007号();长师院自科合字政策[2010]第002号)资助项目()
- DOI：10.3788/fgxb20133411.1474
  中图分类号： O482.31
- 收稿日期：2013-06-07，
  
  修回日期：2013-09-06，
  
  纸质出版日期：2013-11-10
- 稿件说明：
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孙晓园, 贺小光, 于立军, 高允锋, 郭锦泉, 骆永石, 张家骅, 吴春雷. 白光LED用红色荧光粉Sr2EuxGd1-xAlO5的制备及其发光性质[J]. 发光学报, 2013,34(11): 1474-1478

SUN Xiao-yuan, HE Xiao-guang, YU Li-jun, GAO Yun-feng, GUO Jin-quan, LUO Yong-shi, ZHANG Jia-hua, WU Chun-lei. Preparation and Photoluminescence Properties of Red Emitting Sr2EuxGd1-xAlO5 Phosphor for White LED[J]. Chinese Journal of Luminescence, 2013,34(11): 1474-1478
孙晓园, 贺小光, 于立军, 高允锋, 郭锦泉, 骆永石, 张家骅, 吴春雷. 白光LED用红色荧光粉Sr2EuxGd1-xAlO5的制备及其发光性质[J]. 发光学报, 2013,34(11): 1474-1478 DOI： 10.3788/fgxb20133411.1474.

SUN Xiao-yuan, HE Xiao-guang, YU Li-jun, GAO Yun-feng, GUO Jin-quan, LUO Yong-shi, ZHANG Jia-hua, WU Chun-lei. Preparation and Photoluminescence Properties of Red Emitting Sr2EuxGd1-xAlO5 Phosphor for White LED[J]. Chinese Journal of Luminescence, 2013,34(11): 1474-1478 DOI： 10.3788/fgxb20133411.1474.

摘要

用高温固相反应法合成了Sr

AlO

红色荧光粉

研究了荧光粉的晶体结构和发光性质。在紫外光和近紫外光激发下

样品的发射光谱由Eu

的

(

4) 特征发射组成

其中Eu

离子的

(

=590 nm)和

(

=622 nm)跃迁发射的强度最大。当Eu

离子的摩尔分数为 0.75时

样品的发光最强。研究结果表明

AlO

荧光粉是一种在近紫外芯片白光LED上有应用前景的红光荧光粉。

Abstract

The red emitting phosphor Sr

AlO

was synthesized through the solid-state reaction technique. The structure

photoluminescence properties of Sr

AlO

were described. Under the excitation of UV and near UV light

the photoluminescence emission spectra can be assigned to the well-known transitions of Eu

from the initial state

to the final states

(

4). The two strong emissions peak at 590 nm and 622 nm

which arose from the

and

transitions of Eu

respectively. When the mole fraction of Eu

is 0.75

the emission intensity of the phosphor is the strongest. This phosphor is considered to be a potential red-emitting phosphor for NUV chip white LED.

关键词

Keywords

references

Kuo C H, Sheu J K, Chang S J, et al. n-UV+blue/green/red white light emitting diode lamps [J]. Jpn. J. Appl. Phys., Part 1, 2003, 42:2284-2287.[2] Xie R J, Hirosak N, Mitomo M, et al. Wavelength-tunable and thermally stable Li--sialon:Eu2+ oxynitride phosphors for white light-emitting diodes [J]. Appl. Phys. Lett., 2006, 89(24):241103-1-3.[3] Wang L, Zhang X, Hao Z D, et al. Energy transfer in Y3Al5O12:Ce3+, Cr3+ and Y3Al5O12:Ce3+, Pr3+, Cr3+ phosphors [J]. Chin. J. Lumin.(发光学报), 2011, 32(5):418-422 (in Chinese).[4] Kim J S, Jeon P E, Choi J C, et al. Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor [J]. Appl. Phys. Lett., 2004, 84(15):2931-2933.[5] Zhang Y Y, Xia Z G, Wu W W. Luminescence properties and energy transfer of Sr3Gd0.5-xTb0.5(BO3)3:xEu3+ [J]. Chin. J. Lumin.(发光学报), 2012, 33(9):949-953 (in Chinese).[6] Sun X Y, Hao Z D, Li C J, et al. Enhanced orange-red emission by using Mo codoped in Ba2CaWO6:Eu3+, Li+ phosphor under near UV excitation [J]. J. Lumin., 2013, 134(1):191-194.[7] Wang R, Xu J, Chen C. Fabrication and luminescence properties of Sr3B2O6:Eu3+, Na+ phosphor for white LED applications [J]. Chin. J. Lumin.(发光学报), 2011, 32(10):983-987 (in Chinese).[8] Drofenik M, Golic L. R++efinement of the Sr2EuFeO5 and SrEuAlO5 structures [J]. Acta Cryst., 1979, B35:1059-1062.[9] Zhang S Y. Spectroscopy of Rare Earth Ions [M]. Beijing: Science Press, 2008:251.[10] Hong G Y. Luminescent Materials of Rare Earth [M]. Beijing: Science Press, 2011:98-99.[11] Sun J Y, Du H Y, Hu W X. Solid Luminescent Materials [M]. Beijing: Chemical Industry Press, 2003:91-92.

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