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Eu3+掺杂的含氧磷酸盐发光性质
Luminescent Properties of Eu3+-doped Oxyphosphates
- 发光学报 2013年34卷第11期 页码：1435-1439
- 作者机构：
发光学与应用国家重点实验室 中国科学院长春光学精密机械与物理研究所,吉林 长春,130033
- 作者简介：
- 基金信息：国家自然科学基金(10874180,11174278,10774141,11174276,51172226)资助项目()
DOI：10.3788/fgxb20133411.1435
中图分类号： O482.31收稿日期：2013-07-04，
修回日期：2013-09-06，
纸质出版日期：2013-11-10
- 稿件说明：
移动端阅览
吕少哲, 张家骅, 张继森, 鄂书林, 赵海峰, 骆永石. Eu<sup>3+</sup>掺杂的含氧磷酸盐发光性质[J]. 发光学报, 2013,34(11): 1435-1439
LÜ Shao-zhe, ZHANG Jia-hua, ZHANG Ji-shen, E Shu-lin, ZHAO Hai-feng, LUO Yong-shi. Luminescent Properties of Eu<sup>3+</sup>-doped Oxyphosphates[J]. Chinese Journal of Luminescence, 2013,34(11): 1435-1439
吕少哲, 张家骅, 张继森, 鄂书林, 赵海峰, 骆永石. Eu<sup>3+</sup>掺杂的含氧磷酸盐发光性质[J]. 发光学报, 2013,34(11): 1435-1439 DOI： 10.3788/fgxb20133411.1435.
LÜ Shao-zhe, ZHANG Jia-hua, ZHANG Ji-shen, E Shu-lin, ZHAO Hai-feng, LUO Yong-shi. Luminescent Properties of Eu<sup>3+</sup>-doped Oxyphosphates[J]. Chinese Journal of Luminescence, 2013,34(11): 1435-1439 DOI： 10.3788/fgxb20133411.1435.
摘要
采用固态反应法制备了Gd
3
PO
7
:Eu
3+
和 La
3
PO
7
:Eu
3+
发光材料
通过X射线衍射和SEM确定了样品的结构和形貌。 在真空紫外光的激发下
Gd
3
PO
7
:Eu
3+
样品展示了较弱的基质吸收;但在紫外光的激发下
Gd
3
PO
7
:Eu
3+
显示了比La
3
PO
7
:Eu
3+
更强的红光发射
其原因是在Gd
3
PO
7
:Eu
3+
中存在Gd
3+
到Eu
3+
的有效能量传递过程。两个样品的发射光谱峰值位于618 nm
属于Eu
3+
的
5
D
0
7
F
2
跃迁。Eu
3+
在材料中处于较低的格位对称环境
具有很好的色纯度。
Abstract
Gd
3
PO
7
:Eu
3+
and La
3
PO
7
:Eu
3+
samples were prepared by conventional solid-state reaction route. X-ray diffraction and scanning of electron microscopy were employed to characterize the samples. The excitation and emission spectra from VUV to visible wavelength were obtained at the room temperature. It is found that the host absorption band of Gd
3
PO
7
:Eu
3+
is weaker under VUV excitation
but the red luminescence intensity of Gd
3
PO
7
:Eu
3+
is stronger than La
3
PO
7
:Eu
3+
under UV excitation. There is an efficient energy-transfer process from Gd
3+
to Eu
3+
. The two samples major emission peaks from
5
D
0
to
7
F
2
transition of Eu
3+
locate at 618 nm. The results of emission spectra indicate that the local symmetry of the Eu
3+
ions is lower and the color purity is better in these oxyphosphates samples.
关键词
Keywords
references
Dillip G R, Dhoble S J, Manoj L, et al. A potential red emitting K4Ca(PO4)2:Eu3+ phosphor for white light emitting diodes [J]. J. Lumin., 2012, 132(11):3072-3076.[2] Dorman J A, Choi J H, Kuzmanich G, et al. High-quality white light using core-shell RE3+:LaPO4(RE=Eu,Tb,Dy,Ce) phosphors [J]. Phys. Chem. C, 2012, 116(23):12854-12860.[3] Wu C F, Wang Y H, Wang D. Optical properties of Tb3+ ion in LnP3O9(Ln=Y,Gd) host matrix [J]. Solid-State Lett., 2008, 11(2):J9-J11.[4] Luo Q L, Shen S D, Lu G Z, et al. Synthesis of cubic ordered mesoporous YPO4:Ln3+ and their photoluminescence pro-perties [J]. J. Mater.Chem., 2009, 19(43):8079-8085.[5] fang Y P, Xu A W, Song R Q, et al. Systematic synthesis and characterization of singe-crystal lanthanide orthophosphate nanowires [J]. J. Am. Chem. Soc., 2003, 125(51):16025-16034.[6] Luwang M N, Ningthoujam R S, Jagannath, et al. Effects of Ce3+ codoping and annealing on phase transformation and luminescence of Eu3+-doped YPO4 nanorods:D2O solvent effect [J]. J. Am. Chem. Soc., 2010, 132(8):2759-2768.[7] Zhang L H, Yin M L, You H P, et al. Mutifuntional GdPO4:Eu3+ hollow spheres:Synthesis and magnetic and luminescent properties [J]. Inorg. Chem., 2011, 50(21):10608-10613.[8] Song H W, Yu L X, Lu S Z, et al. Remarkable differences in photoluminescent properties between LaPO4:Eu one-dimensional nanowires and zero-dimensional nanoparticles [J]. Appl. Phys. Lett., 2004, 85(3):470-472.[9] Yan B, Gu J F. Controlled chemical co-precipitation and solid phase synthesis, microstructure and photoluminescence of La3PO7:Eu3+ phosphors [J]. J. Non-Cryst. Solids, 2009, 355(14-15):826-829.[10] Di W H, Wang X J, Chen B J, et al. Preparation, characterization and VUV luminescence property of YPO4:Tb phosphor for a PDP [J]. Opt. Mater., 2005, 27(8):1386-1390.[11] Rao R P. Tb3+ activated green phosphors for plasma display panel applications [J]. J. Electrochem. Soc., 2003, 150(8):H165-H171.[12] Sohn K S, Zeon W, Chang H, et al. Combinatorial search for new red phosphors of high efficiency at VUV excitation basedontheYRO4 (R= As, Nb, P, V) system [J]. Chem. Mater., 2002, 14(5):2140-2148.[13] Jin Y, Qin W P, Zhang J S, et al. La3PO7:Eu3+ nanoparticles: A novel red phosphor [J]. Mater. Lett., 2008, 62(17-18):3146-3148.[14] Wei Z G, Sun L D, Liao C S, et al. Size-dependent chromaticity in YBO3:Eu nanocrystals: Correlation with microstructure and site symmetry [J]. J. Phys. Chem. B, 2002, 106(41):10610-10617.[15] Wu X Y, You H P, Cui H T, et al. Vacuum ultraviolet optical properties of (La,Gd)PO4:RE3+(Re=Tb) [J]. Mater. Res. Bull., 2002, 37(9):1531-1538[16] Wu C F, Wang Y H. Hydrothermal synthesis and luminescent properties of (La,Gd)PO4:Tb phosphors under VUV excitation [J]. Mater. Lett., 2007, 61(11-12):2416-2418.[17] Nakazawa E, Shiga F. Vacuum ultraviolet luminescence-excitation spectra of RPO4:Eu3+(R=Y, La, Gd and Lu) [J]. J. Lumin., 1977, 15(3):255-259.[18] Dirksen G J, Blasse G. Tetracalcium gadolinium oxoborate(Ca4GdO(BO3)3 as a new host lattice for luminescent materials [J]. J. Alloys. Compd., 1993, 191(1):121-126.[19] Zeng X Q, Hong G Y, You H P, et al. Luminescent properties of Gd3PO7:Eu in UV/VUV region [J]. Chin. Phys. Lett., 2001, 18(5):690-691.[20] Xie Y, Wang T, Wang H B. Luminescence properties of Y(VP)O4:Eu3+ phosphor doped with alkali earths and rare earths [J]. Chin. J. Liq. Cryst. Disp. (液晶与显示), 2011, 26(5):587-591 (in Chinese).
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