N掺杂纳米ZnO的制备及光催化性能

曹萍; 白越

doi:10.3788/fgxb20133410.1328

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N掺杂纳米ZnO的制备及光催化性能

材料合成及性能 | 更新时间：2020-08-12

- N掺杂纳米ZnO的制备及光催化性能
- Preparation and Photocatalytic Properties of N-doped Nano-ZnO
- 发光学报 2013年34卷第10期页码：1328-1331
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,130033
  2. 长春工程学院, 吉林长春 130012
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11104018)();吉林省科技发展计划(201101090)();吉林省教育厅项目(2012284)资助()
- DOI：10.3788/fgxb20133410.1328
  中图分类号： O484.4
- 收稿日期：2013-04-02，
  
  修回日期：2013-07-22，
  
  纸质出版日期：2013-10-10
- 稿件说明：
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曹萍, 白越. N掺杂纳米ZnO的制备及光催化性能[J]. 发光学报, 2013,34(10): 1328-1331

CAO Ping, BAI Yue. Preparation and Photocatalytic Properties of N-doped Nano-ZnO[J]. Chinese Journal of Luminescence, 2013,34(10): 1328-1331
曹萍, 白越. N掺杂纳米ZnO的制备及光催化性能[J]. 发光学报, 2013,34(10): 1328-1331 DOI： 10.3788/fgxb20133410.1328.

CAO Ping, BAI Yue. Preparation and Photocatalytic Properties of N-doped Nano-ZnO[J]. Chinese Journal of Luminescence, 2013,34(10): 1328-1331 DOI： 10.3788/fgxb20133410.1328.

摘要

通过NH

等离子体后处理引入N使其进入到ZnO晶格中

制备出了N掺杂的纳米ZnO光催化剂。通过测试

研究了该样品的结构性质、表面形貌和在不同催化剂浓度、不同反应物浓度、氧气等条件下光催化降解甲基橙的降解效率。分析结果表明

N的掺杂提高了光催化剂的光催化效率。

Abstract

The nano-ZnO was grown by electrochemical deposition method. In order to introduce N

the NH

plasma post treatment was used. X-ray diffraction spectroscopy analyses indicate that N doping can not disturb the structure of ZnO. No additional peaks are observed in the sample. X-ray photoelectron spectroscopy analyses also indicate that N atoms permeate into the ZnO lattice and replace the O sites without changing the wurtzite structure. N doping enhances the separation efficiency of the photogenerated electron and hole

thereby improving the catalytic efficiency of the photocatalyst.

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references

Zhu H Y, Jiang R, Guan Y J, et al. Effect of key operational factors on decolorization of methyl orange during H2O2 assisted CdS/TiO2/ploymer nanocomposite thin films under simulated solar light irradiation [J]. Sep. Purif. Technol., 2010, 74(2):187-194.[2] Karatasios I, Katsiotis M S, Likodimos V, et al. Photo-induced carbonation of lime-TiO2 mortars [J]. Appl. Catal. B, 2010, 95(1-2):78-86.[3] Liu P S, Cai W P, Fang M, et al. Room temperature synthesized rutile TiO2 nanoparticles induced by laser ablation in liquid and their photocatalytic activity [J]. Nanotechnology, 2009, 20(28):285707-1-4.[4] Lee H Y, Lan W L, Tseng T Y, et al. Optical control of phase transformation in Fe-doped TiO2 nanoparticles [J].Nanotechnology, 2009, 20(31):315702-1-4.[5] Narayan H, Alemu H, Macheli L, et al. Synthesis and characterization of Y3+-doped TiO2 nanocomposites for photocatalytic applications [J]. Nanotechnology, 2009, 20(25):255601-1-5.[6] Wu G S, Wen J L, Nigro S, et al. One-step synthesis of N-and F-codoped mesoporous TiO2 photocatalysts with high visible light activity [J]. Nanotechnology, 2010, 21(8):085701-1-4.[7] Du X, He J H, Zhao Y Q. Facile preparation of F and N codoped pinecone-like titania hollow microparticles with visible light photocatalytic activity [J]. J. Phys. Chem. C, 2009, 113(32):14151-14158.[8] Huo Y N, Jin Y, Zhu J, et al. Highly active TiO2-x-yNxFy visible photocatalyst prepared under supercritical conditions in NH4F/EtOH fluid [J]. Appl. Catal. B, 2009, 89(3-4):543-550.[9] Li X P, Cao P J, Su S C, et al. Investigation on near band edge UV luminescence of ZnO thin films [J]. Chin. J. Lumin.(发光学报), 2012, 33(5):481-485(in Chinese).[10] He Z Y, Zhang Q H, Li Y G, et al. Distribution-tunable growth of ZnO nanorods on the inner walls of microcapillaries from reverse micelle deriving seed patterns [J]. Mater. Chem. Phys., 2010, 119(1-2):222-229.[11] He Z Y, Li Y G, Zhang Q H, et al. Capillary microchannel-based microreactors with highly durable ZnO/TiO2 nanorod arrays for rapid, high efficiency and continuous-flow photocatalysis [J]. Appl. Catal. B, 2010, 93(3-4):376-382.[12] Zhu Y F, Shen W Z. Synthesis of ZnO compound nanostructures via a chemical route for photovoltaic applications [J]. Appl. Surf. Sci., 2010, 256(24):7472-7477.[13] Xu F, Zhang P, Navrotsky A, et al. Hierarchically assembled porous ZnO nanoparticles: Synthesis, surface energy, and photocatalytic activity [J]. Chem. Mater., 2007, 19(23):5680-5686.[14] Luo T Y, Wei Z P, Li J H, et al. Synthesis and characterization of CdS/ZnO nano-compositesstructure and enhanced photocatalytic [J]. Chin. J. Lumin.(发光学报), 2011, 32(7):680-685 (in Chinese).[15] Asahi R, Morikawa T, Ohwaki T, et al. Visible-light photocatalysis in nitrogen-doped titanium oxides [J]. Science, 2001, 293(5528):269-271.

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