稀土铝磷酸盐玻璃中镨离子的可见光致发光

韩晓哲; 付方方; 陈宝玖; 马铁成; 林海

doi:10.3788/fgxb20133410.1306

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稀土铝磷酸盐玻璃中镨离子的可见光致发光

材料合成及性能 | 更新时间：2020-08-12

- 稀土铝磷酸盐玻璃中镨离子的可见光致发光
- Visible Photoluminescence of Praseodymium Ions in Rare-earth Aluminum Phosphate Glass
- 发光学报 2013年34卷第10期页码：1306-1312
- 作者机构：
  
  1. 大连海事大学物理系, 辽宁大连 116026
  2. 大连工业大学纺织与材料工程学院,辽宁大连,116034
- 作者简介：
- 基金信息：
  
  辽宁省自然科学基金(201202011)资助项目()
- DOI：10.3788/fgxb20133410.1306
  中图分类号： O432;O482.31
- 收稿日期：2013-05-04，
  
  修回日期：2013-06-24，
  
  纸质出版日期：2013-10-10
- 稿件说明：
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韩晓哲, 付方方, 陈宝玖, 马铁成, 林海. 稀土铝磷酸盐玻璃中镨离子的可见光致发光[J]. 发光学报, 2013,34(10): 1306-1312

HAN Xiao-zhe, FU Fang-fang, Chen Bao-jiu, MA Tie-cheng, LIN Hai. Visible Photoluminescence of Praseodymium Ions in Rare-earth Aluminum Phosphate Glass[J]. Chinese Journal of Luminescence, 2013,34(10): 1306-1312
韩晓哲, 付方方, 陈宝玖, 马铁成, 林海. 稀土铝磷酸盐玻璃中镨离子的可见光致发光[J]. 发光学报, 2013,34(10): 1306-1312 DOI： 10.3788/fgxb20133410.1306.

HAN Xiao-zhe, FU Fang-fang, Chen Bao-jiu, MA Tie-cheng, LIN Hai. Visible Photoluminescence of Praseodymium Ions in Rare-earth Aluminum Phosphate Glass[J]. Chinese Journal of Luminescence, 2013,34(10): 1306-1312 DOI： 10.3788/fgxb20133410.1306.

摘要

研究了稀土铝磷酸盐5.8Li

O-3CaO-5BaO-6Al

-4.2La

-66P

(LCBALP)玻璃中镨离子的可见光致发光特性

采用积分球测试系统对其绝对荧光光谱进行表征。

的自发辐射跃迁几率和最大受激发射截面分别为926.5 s

-1

和3.510

-21

。在蓝色LED激发下

镨离子可见特征发射峰的辐射通量和光通量分别为112.6 W和29.7 mlm

其可见特征发射的总荧光量子产率为4.1%。光学玻璃中镨离子的光谱评估为其在光电子器件和紧凑型照明光源领域的发展提供了重要的参考依据。

Abstract

Visible photoluminescence properties of praseodymium ions in rare-earth aluminum phosphate 5.8Li

O-3CaO-5BaO-16Al

-4.2La

-66P

(LCBALP) glass were investigated and the absolute fluorescence spectra were measured and calibrated in an integrating sphere. The spontaneous emission probability and the maximum stimulated emission cross-section corresponding to the

transition are 926.5 s

-1

and 3.510

-21

respectively. Under the blue LED excitation

the radiant flux and the luminous flux for the visible emission bands of LCBALP glass are identified to be 112.6 W and 29.7 mlm

respectively. The total quantum yield for the visible fluorescence is determined to be 4.1%. The spectral evaluations of praseodymium ions in optical glass provide a reliable reference in developing optoelectronic devices and compact lighting sources.

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Keywords

references

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