空心半球形SrWO4和SrWO4：Tb3+/Eu3+球形颗粒的合成及发光性能

岳丹; 李春阳; 马彩云; 刘春霞; 王振领

doi:10.3788/fgxb20133409.1155

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空心半球形SrWO₄和SrWO₄：Tb³⁺/Eu³⁺球形颗粒的合成及发光性能

材料合成及性能 | 更新时间：2020-08-12

- 空心半球形SrWO₄和SrWO₄：Tb³⁺/Eu³⁺球形颗粒的合成及发光性能
- Synthesis and Luminescent Properties of Hollow Semi-sphere SrWO₄ and SrWO₄：Tb³⁺/Eu³⁺ Microsphere
- 发光学报 2013年34卷第9期页码：1155-1160
- 作者机构：
  
  1. 郑州大学化学与分子工程学院, 河南郑州 450001
  2. 周口师范学院稀土功能材料及应用重点实验室, 河南周口 466001
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21171179)();河南省科技创新杰出青年基金(豫科人组[2012]1号)();国家人力资源和社会保障部留学人员科技活动项目(人社厅函[2011]
- DOI：10.3788/fgxb20133409.1155
  中图分类号： O482.31
- 收稿日期：2013-05-09，
  
  修回日期：2013-07-03，
  
  纸质出版日期：2013-09-10
- 稿件说明：
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岳丹, 李春阳, 马彩云, 刘春霞, 王振领. 空心半球形SrWO4和SrWO4：Tb3+/Eu3+球形颗粒的合成及发光性能[J]. 发光学报, 2013,34(9): 1155-1160

YUE Dan, LI Chun-yang, MA Cai-yun, LIU Chun-xia, WANG Zhen-ling. Synthesis and Luminescent Properties of Hollow Semi-sphere SrWO4 and SrWO4：Tb3+/Eu3+ Microsphere[J]. Chinese Journal of Luminescence, 2013,34(9): 1155-1160
岳丹, 李春阳, 马彩云, 刘春霞, 王振领. 空心半球形SrWO4和SrWO4：Tb3+/Eu3+球形颗粒的合成及发光性能[J]. 发光学报, 2013,34(9): 1155-1160 DOI： 10.3788/fgxb20133409.1155.

YUE Dan, LI Chun-yang, MA Cai-yun, LIU Chun-xia, WANG Zhen-ling. Synthesis and Luminescent Properties of Hollow Semi-sphere SrWO4 and SrWO4：Tb3+/Eu3+ Microsphere[J]. Chinese Journal of Luminescence, 2013,34(9): 1155-1160 DOI： 10.3788/fgxb20133409.1155.

摘要

采用水热法制备了空心半球形SrWO

及Tb

、Eu

掺杂的SrWO

球形颗粒

利用XRD、SEM、荧光光谱等研究其物相、形貌及发光性能。未掺杂的SrWO

具有空心半球形形貌

属四方晶系。SrWO

:Tb

及SrWO

:Eu

为球形颗粒

其相结构与未掺杂样品类似

形貌从空心半球形转变为球形颗粒。随着Tb

掺杂浓度的增加

SrWO

:Tb

的形貌从球状变成由纳米棒构成的花状;随着Eu

掺杂浓度的增加

样品中出现了单斜相的Eu

其形貌也发生了明显的变化。在紫外光激发下

SrWO

:Tb

及SrWO

:Eu

的发射光谱由钨酸根的宽带发射和掺杂离子的特征发射组成

分别表现出绿光和红光发射。Tb

的最佳掺杂摩尔分数为3%

的最佳掺杂摩尔分数为25%。

Abstract

Hollow semi-sphere SrWO

and rare earth ions (Tb

) doped SrWO

microspheres were synthesized by hydrothermal treatment and characterized by XRD

SEM and photoluminescence (PL) spectrum. The results indicate that the undoped SrWO

has hollow semi-sphere morphology

with a tetragonal phase structure. The phase structure of SrWO

doped with Tb

or Eu

is similar to that of the undoped SrWO

while the morphology transforms from hollow semi-sphere to microsphere. With the increasing of Tb

doping concentration

the morphology of SrWO

:Tb

changes from microsphere to micro-flower composed of many nanorods. The increasing of Eu

doping concentration leads to the presence of monoclinic phase Eu

and the morphology change of SrWO

:Eu

. Under the excitation of UV light

the emission spectra of SrWO

:Tb

and SrWO

:Eu

are mainly attributed to the characteristic emission of Tb

(

transitions

3) and Eu

(

transitions

respectively. The optimal doping mole fractions are 3% for Tb

and 25% for Eu

in SrWO

关键词

Keywords

references

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