具有超顺磁和可见/近红外发光性质的双功能介孔磁/光纳米复合材料

冯婧; 周亮; 王卓; 宋术岩; 葛昕; 张洪杰

doi:10.3788/fgxb20133409.1103

您当前的位置：

首页 >

文章列表页 >

具有超顺磁和可见/近红外发光性质的双功能介孔磁/光纳米复合材料

材料合成及性能 | 更新时间：2020-08-12

- 具有超顺磁和可见/近红外发光性质的双功能介孔磁/光纳米复合材料
- Bifunctional Mesoporous Magnetic/Luminescent Nanocomposite with Superparamagnetic and Visible/Near-IR Emission Properties
- 发光学报 2013年34卷第9期页码：1103-1107
- 作者机构：
  
  中国科学院长春应用化学研究所稀土资源利用国家重点实验室, 吉林长春 130022
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21001100)();国家高科技研究发展计划(863计划)(2011AA03A407)();吉林省科技创新人才培育计划青年基金(201201008)
- DOI：10.3788/fgxb20133409.1103
  中图分类号： O482.3;O482.52+2
- 收稿日期：2013-05-10，
  
  修回日期：2013-07-11，
  
  纸质出版日期：2013-09-10
- 稿件说明：
移动端阅览
冯婧, 周亮, 王卓, 宋术岩, 葛昕, 张洪杰. 具有超顺磁和可见/近红外发光性质的双功能介孔磁/光纳米复合材料[J]. 发光学报, 2013,34(9): 1103-1107

FENG Jing, ZHOU Liang, WANG Zhuo, SONG Shu-yan, GE Xin, ZHANG Hong-jie. Bifunctional Mesoporous Magnetic/Luminescent Nanocomposite with Superparamagnetic and Visible/Near-IR Emission Properties[J]. Chinese Journal of Luminescence, 2013,34(9): 1103-1107
冯婧, 周亮, 王卓, 宋术岩, 葛昕, 张洪杰. 具有超顺磁和可见/近红外发光性质的双功能介孔磁/光纳米复合材料[J]. 发光学报, 2013,34(9): 1103-1107 DOI： 10.3788/fgxb20133409.1103.

FENG Jing, ZHOU Liang, WANG Zhuo, SONG Shu-yan, GE Xin, ZHANG Hong-jie. Bifunctional Mesoporous Magnetic/Luminescent Nanocomposite with Superparamagnetic and Visible/Near-IR Emission Properties[J]. Chinese Journal of Luminescence, 2013,34(9): 1103-1107 DOI： 10.3788/fgxb20133409.1103.

摘要

合成了两种双功能介孔磁/光纳米复合材料。磁性Fe

纳米粒子作为核被包覆于介孔二氧化硅纳米球中

稀土铽和铒配合物分别通过硅烷化的配体PABA-Si和phen-Si共价嫁接于介孔球的网络中。研究了所制备的双功能纳米复合材料的结构、磁性、荧光发射性质

结果表明

双功能纳米复合材料具有介孔结构、超顺磁特性和相应稀土配合物的特征荧光发射性质。

Abstract

Two bifunctional mesoporous magnetic/luminescent nanocomposites were fabricated. Magnetic (Fe

) cores encapsulated in the mesoporous silica nanospheres and the terbium and erbium complex covalently bonded to the framework of mesoporous silica through the chelate ligand N-(4-benzoic acid-yl)

N'-(propyltriethoxysilyl) (PABA-Si) and 5-[N

N-bis-3-(triethoxysilyl)propyl]ureyl-1

10-phenanthroline (phen-Si)

respectively. The structure

magnetism

and photoluminescence properties of the obtained bifunctional nanocomposites were investigated. The results reveal that the nanospheres possess mesostructures

superparamagnetic behavior

and characteristic luminescence properties of the corresponding lanthanide complexes.

关键词

Keywords

references

Kresge C T, Leonowicz M E, Roth W J, et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism [J]. Nature, 1992, 359(6397):710-712.[2] Beck J S, Vartuli J C, Roth W J, et al. A new family of mesoporous molecular sieves prepared with liquid crystal templates [J]. J. Am. Chem. Soc., 1992, 114(27):10834-10843.[3] Peng C Y, Zhang H J, Yu J B, et al. Synthesis, characterization, and luminescence properties of the ternary europium complex covalently bonded to mesoporous SBA-15 [J]. J. Phys. Chem. B, 2005, 109(32):15278-15287.[4] Feng J, Fan W Q, Song S Y, et al. Fabrication and characterization of magnetic mesoporous silica nanospheres covalently bonded with europium complex [J]. Dalton Trans., 2010, 39(21):5166-5171.[5] Corot C, Robert P, Idee J M, et al. Recent advances in iron oxide nanocrystal technology for medical imaging [J]. Adv. Drug Delivery Rev., 2006, 58(14):1471-1504.[6] Liu F Y, Fu L S, Wang J, et al. Luminescent hybrid films obtained by covalent grafting of terbium complex to silica network [J]. Thin Solid Films, 2002, 419(1-2):178-183.[7] Li H R, Lin J, Zhang H J, et al. Preparation and luminescence properties of hybrid materials containing europium(Ⅲ) complexes covalently bonded to a silica matrix [J]. Chem. Mater., 2002, 14(9):3651-3655.[8] Xu H, Cui L L, Tong N H, et al. Development of high magnetization Fe3O4/polystyrene/silica nanospheres via combined miniemulsion/emulsion polymerization [J]. J. Am. Chem. Soc., 2006, 128(49):15582-15583.[9] Kerker M, Kratohvil J P. Manual of symbols and terminology for physicochemical quantities and units, appendix Ⅱ: Definitions, terminology and symbols in colloid and surface chemistry, Part 1.14: Light scattering [J]. Pure Appl. Chem., 1983, 55(6):931-941.[10] Zhang W H, Lu X B, Xiu J H, et al. Synthesis and characterization of bifunctionalized ordered mesoporous materials [J]. Adv. Funct. Mater., 2004, 14(6):544-552.[11] Zhang L, Qiao S Z, Jin Y G, et al. Fabrication and size-selective bioseparation of magnetic silica nanospheres with highly ordered periodic mesostructure [J]. Adv. Funct. Mater., 2008, 18(20):3203-3212.[12] Guo X M, Guo H D, Fu L S, et al. Novel hybrid periodic mesoporous organosilica material grafting with Tb complex: Synthesis, characterization and photoluminescence property [J]. Micropor. Mesopor. Mater., 2009, 119(1-3):252-258.[13] Kuriki K, Koike Y, Okamoto Y. Plastic optical fiber lasers and amplifiers containing lanthanide complexes [J]. Chem. Rev., 2002, 102(6):2347-2356.

浏览量

102

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

静电纺丝技术制备Eu(BPA)₃phen/聚丙烯腈纤维及其性能

基于稀土配合物和离子液体的新型稀土发光材料研究进展

球磨法制备Tm³⁺/Yb³⁺掺杂NaGdF₄ 的上转换发光及顺磁性质研究

煅烧温度对Ba_1.2Ca_0.64SiO₄：0.10Eu，0.06Mn粉体发光性能的影响

新型三元配合物Tb(DPAB)₃IP的制备与发光性能