白光LED用红色荧光粉KLa(MoO4)2：Eu3+的制备及发光性能

侯利; 吉日嘎兰图; 齐向东; 付作岭

doi:10.3788/fgxb20133408.0965

您当前的位置：

首页 >

文章列表页 >

白光LED用红色荧光粉KLa(MoO₄)₂：Eu³⁺的制备及发光性能

材料合成及性能 | 更新时间：2020-08-12

- 白光LED用红色荧光粉KLa(MoO₄)₂：Eu³⁺的制备及发光性能
- Preparation and Optical Properties of Red Emitting Phosphor KLa(MoO₄)₂：Eu³⁺ for White LEDs
- 发光学报 2013年34卷第8期页码：965-969
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 吉林大学物理学院超硬材料国家重点实验室,吉林长春,130012
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11004081)();教育部留学回国人员科研启动基金(3C1128541411)();中央高校基本科研业务费(450060491220)();吉林省
- DOI：10.3788/fgxb20133408.0965
  中图分类号： O482.31
- 收稿日期：2013-05-02，
  
  修回日期：2013-05-15，
  
  纸质出版日期：2013-08-10
- 稿件说明：
移动端阅览
侯利, 吉日嘎兰图, 齐向东, 付作岭. 白光LED用红色荧光粉KLa(MoO4)2：Eu3+的制备及发光性能[J]. 发光学报, 2013,34(8): 965-969

HOU Li, Jirigalantu, QI Xiang-dong, FU Zuo-ling. Preparation and Optical Properties of Red Emitting Phosphor KLa(MoO4)2：Eu3+ for White LEDs[J]. Chinese Journal of Luminescence, 2013,34(8): 965-969
侯利, 吉日嘎兰图, 齐向东, 付作岭. 白光LED用红色荧光粉KLa(MoO4)2：Eu3+的制备及发光性能[J]. 发光学报, 2013,34(8): 965-969 DOI： 10.3788/fgxb20133408.0965.

HOU Li, Jirigalantu, QI Xiang-dong, FU Zuo-ling. Preparation and Optical Properties of Red Emitting Phosphor KLa(MoO4)2：Eu3+ for White LEDs[J]. Chinese Journal of Luminescence, 2013,34(8): 965-969 DOI： 10.3788/fgxb20133408.0965.

摘要

采用水热法制备红色荧光粉KLa(MoO

)

：Eu

通过X射线粉末衍射(XRD)、场发射扫描电镜(FE-SEM)和荧光光谱(PL)对样品进行了表征。实验结果表明：pH值是合成样品KLa(MoO

)

：Eu

的关键因素

当溶液pH值接近7时

荧光粉的纯度较高

分散性良好、粒度均匀、呈规则球形。这种荧光材料可以被紫外光279 nm、近紫外光395 nm和蓝光465 nm有效激发

发射主峰位于617 nm

是一种可应用于白光LED转换用的新型红色荧光粉。

Abstract

-doped KLa(MoO

)

phosphor was prepared successfully

via

the hydrothermal process. And it was characterized by X-ray diffraction (XRD)

field emission-scanning electron microscopy (FE-SEM) and photoluminescence (PL)

respectively. The experimental results indicate that the pH values of the reaction solution have important effects on the phase structures and the morphologies of the products. A crystallization pH value of 7 was optimal. This phosphor can be effectively excited by 279

395

465 nm and emits red light at 617 nm with line spectra. The optical properties suggest that KLa(MoO

)

：Eu

is an efficient red-emitting phosphor for white LEDs applications.

关键词

Keywords

references

Gao F, Liang L F, Guo C F. Preparation and luminescence of red light-emitting phosphors based on Li3Ba2Ln3-xEux(MoO4)8 by sol-gel method [J]. Chin. J. Lumin.(发光学报), 2009, 30(5)：610-616 (in Chinese).[2] Hu Y S, Zhuang W D, Ye H Q, et al. A novel red phosphor for white light emitting diodes [J]. J. Alloys Compd., 2005, 390(1-2)：226-229.[3] Neeraj S, Kijima N, Cheetham A K. Novel red phosphors for solid-state lighting： The system NaM(WO4)2-x(MoO4)x：Eu3+(M=Gd, Y, Bi) [J]. Chem. Phys. Lett., 2004, 387(1-3)：2-6.[4] Ci Z P, Wang Y H, Zhang J C, et al. Ca1-xMo1-ySiyO4：Eu3+x： A novel red phosphor for white light emitting diodes [J]. Phys. B, 2008, 403(4)：670-674.[5] Wang Z J, Li P L, Yang Z P, et al. Luminescent characteristics of KCaPO4：Tb3+ green phosphor [J]. J. Funct. Mater.(功能材料), 2011, 42(5)：884-887 (in Chinese).[6] Li G H, Li L L, Gan S C, et al. Hydrothermal synthesis and luminescent properties of NaLa(MoO4)2：Eu3+,Tb3+ phosphors [J]. J. Alloys Compd., 2013, 550(1)：1-8.[7] You H P, Yang M, Jia Y C, et al. Synthesis and luminescent properties of NaLa(MoO4)2：Eu3+ shuttle-like nanorods composed of nanoparticles [J]. Cryst. Eng. Comm., 2011, 13：4046-4052.[8] Bu W B, Chen Z X, Shi J L, et al. Oleic acid/Oleylamine cooperative-controlled crystallization mechanism for monodisperse tetragonal bipyramid NaLa(MoO4)2 nanocrystals [J]. J. Phys. Chem. C, 2009, 113(28)：12176-12185.[9] Kolesov B A, Kozeeva L P. Raman study of cation distribution in the scheelite-like double molybdates and tungstates [J]. J. Struct. Chem., 1993, 34(4)：534-539.[10] Wang Z L, Liang H B, Zhou L Y, et al. Luminescence of (Li0.333Na0.334K0.333)Eu(MoO4)2 and its application in near UV InGaN-based light-emitting diode [J]. Chem. Phys. Lett., 2005, 412(4-6)：313-316.[11] Xie Y, Wang T, Wang H B. Luminescence properties of Y(VP)O4：Eu3+ phosphor doped with alkali earths and rare earths [J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2011, 26(5)：587-591(in Chinese).[12] Li X, Hu Y H, Wang Y H, et al. On the synthesis of NaxSr1-2xMoO4：Eux3+ and their luminescent properties [J]. J. Guangdong Univ. Technol.(广东工业大学学报), 2010, 27(4)：32-35 (in Chinese).[13] Zhang J H, Lv W, Hao Z D, et al. Color-tunable white-light emitting BaMg2Al6Si9O30：Eu2+,Tb3+,Mn2+ phosphors via energy transfer [J]. Chin. Opt.(中国光学), 2012, 5(3)：203-208 (in Chinese).[14] Du H Y, Wei Z P, Sun L J, et al. Luminescent properties of ZnS：Mn nanoparticles dependent on doping concentration [J]. Chin. Opt.(中国光学), 2013, 6(1)：111-116 (in Chinese).[15] Wang F, Fan X P, Pi D B, et al. Hydrothermal synthesis and luminescence behavior of rare-earth-doped NaLa(WO4)2 powders [J]. J. Solid State Chem., 2005, 178(3)：825-830.[16] Su Q. Rare Earth Chemistry [M]. Zhengzhou： Henan Science and Technology Press, 1993：296.[17] Fang Y P, Xu A W, Song R Q, et al. Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires [J]. J. Am. Chem. Soc., 2003, 125(51)：16025-16034.[18] Judd B R. Optical absorption intensities of rare-earth ions [J]. Phys. Rev., 1962, 127(3)：750-761.[19] Ofelt G S. Intensities of crystal spectra of rare-earth ions [J]. J. Chem. Phys., 1962, 37(3)：511-520.[20] Lian J B, Sun X D, Liu Z G, et al. Synthesis and optical properties of (Gd1-x,Eux)2O2SO4 nano-phosphors by a novel co-precipitation method [J]. Mater. Res. Bull., 2009, 44(9)：1822-1827.[21] Mahalingam V, Vetrone F, Capobianco J A, et al. Structural and optical investigation of colloidal Ln3+/Yb3+ co-doped KY3F10 nanocrystals [J]. J. Mater. Chem., 2009, 19(20)：3149-3152.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Eu³⁺掺杂诱导CsAgCl₂相变及其光学温度传感性质

NBT-Eu纳米粉体的水热合成及其发光性能研究

水热合成碳颗粒的结构和发光性能

微米级NaYF₄:Eu³⁺的水热合成及其荧光性能研究

中空球形CaWO₄：Eu³⁺荧光粉体的水热合成及发光性能