ZnS：Mn纳米晶的制备及其发光性能研究

李刚; 李丽华; 顾永军; 李谦; 黄金亮

doi:10.3788/fgxb20133407.0861

您当前的位置：

首页 >

文章列表页 >

ZnS：Mn纳米晶的制备及其发光性能研究

材料合成及性能 | 更新时间：2020-08-12

- ZnS：Mn纳米晶的制备及其发光性能研究
- Preparation and Luminescence Properties of ZnS：Mn Nanocrystalline
- 发光学报 2013年34卷第7期页码：861-865
- 作者机构：
  
  河南科技大学材料科学与工程学院, 河南洛阳 471003
- 作者简介：
- 基金信息：
  
  河南省教育厅重点项目(13A430236)();河南省国际科技合作计划(0346620012)();河南科技大学青年基金(13000850)资助项目()
- DOI：10.3788/fgxb20133407.0861
  中图分类号： O482.31
- 收稿日期：2013-03-25，
  
  修回日期：2013-05-20，
  
  纸质出版日期：2013-07-10
- 稿件说明：
移动端阅览
李刚, 李丽华, 顾永军, 李谦, 黄金亮. ZnS：Mn纳米晶的制备及其发光性能研究[J]. 发光学报, 2013,34(7): 861-865

LI Gang, LI Li-hua, GU Yong-jun, LI Qian, HUANG Jin-liang. Preparation and Luminescence Properties of ZnS：Mn Nanocrystalline[J]. Chinese Journal of Luminescence, 2013,34(7): 861-865
李刚, 李丽华, 顾永军, 李谦, 黄金亮. ZnS：Mn纳米晶的制备及其发光性能研究[J]. 发光学报, 2013,34(7): 861-865 DOI： 10.3788/fgxb20133407.0861.

LI Gang, LI Li-hua, GU Yong-jun, LI Qian, HUANG Jin-liang. Preparation and Luminescence Properties of ZnS：Mn Nanocrystalline[J]. Chinese Journal of Luminescence, 2013,34(7): 861-865 DOI： 10.3788/fgxb20133407.0861.

摘要

以C

BrN为表面活性剂

采用水热法合成了ZnS:Mn纳米晶

分别利用XRD、TEM、荧光光谱仪对其物相、形貌及光学性能进行了研究。结果表明:ZnS:Mn纳米晶为闪锌矿ZnS结构

颗粒近似球形

平均粒径为4~8 nm。荧光光谱显示

ZnS:Mn纳米晶的荧光发射峰强度随着Mn

掺杂浓度和表面活性剂含量的增加而逐渐增强。

Abstract

Using C

BrN as surfactant

ZnS:Mn nanocrystallines were synthesized by hydrothermal method. The phase

size and luminescent properties of the nanocrystals were characterized by X-ray diffraction (XRD)

transmission electron microscopy (TEM) and fluorescence photometer. The results show that ZnS:Mn nanocrystals are 4~8 nm of particle size and have a cubic zinc blend crystal structure. The fluorescence spectra showed that the emission peak increased with the increment of Mn-doped concentration and the increment of surfactant.

关键词

Keywords

references

Gurlo A, Ivanovskaya M, Pfau A, et al. Sol-gel prepared In2O3 thin films[J]. Thin Solid Films, 1997, 30(7):288-293.[2] Huang H H, Yan F Q, Kck Y M, et al. Synthesis characterization and nonlinear optical properties of copper nanoparticles[J]. Langmuir, 1997, 13(2):172-175.[3] Dong G Y, Li X W, Wei Z Z, et al. Investigation of influences of concentration of Mn and Cu dopants on the decay process of photogenerated charge carriers in the ZnS:Mn,Cu luminescence materials[J]. Acta Phys. Sinica (物理学报), 2003, 52(3):745-750 (in Chinese).[4] Bhargava R N, Gallagher D, Hong X, et al. Optical properties of manganese-doped nanocrystals of ZnS[J]. Phys. Rev. Lett., 1994, 72(3):416-419.[5] Bol A A, Mel J A. On the incorporation of trivalent rare earth ions in Ⅱ-Ⅵ semiconductor nanocrystals[J]. J. Phys. Chem. B, 2001, 10(5):10197-10202.[6] Chen L, Zhang J H, Luo Y S, et al. Effect of Zn2+ and Mn2+ introduction on the luminescent properties of colloidal ZnS:Mn2+ nanoparticles[J]. Appl. Phys. Lett., 2004, 84(1):112-114.[7] Jiang D X, Cao L X, Su G, et al. Synthesis and photoluminescent properties of ZnS:Mn/CdS nanoparticles with core/shell structure[J]. Chin. J. Lumin.(发光学报), 2009, 30(6):832-837 (in Chinese).[8] Dong G Y, Lin L, Wei Z R, et al. Effect of annealing on brightness of ZnS:Cu, Mn ACEL material[J]. Chin. J. Lumin. (发光学报), 2005, 26(6):732-736 (in Chinese).[9] Xu Y Z, Hu H. Preparation and photoluminescence properties of ZnS nanocrystals co-doped with Mn2+ and Pb2+[J]. Chin. J. Lumin. (发光学报), 2007, 28(4):589-593 (in Chinese).[10] Sapra S, Prakash A, Ghangrekar A, et al. Emission properties of manganese-doped ZnS nanocrystals[J]. J. Phys. Chem. B, 2005, 109(5):1663-1668.[11] Kulkarni S K, Winkler U, Yang X G, et al. Investigations on chemically capped CdS,ZnS and ZnCdS nanoparticles[J]. Appl. Surf. Sci., 2001, 169(1):438-446.[12] Lu H Y, Chu S S. The characteristics of low-temperature-synthesized ZnS and ZnO nanoparticles[J]. J. Cryst. Growth, 2004, 269(24):385-391.[13] Derfus A M, Chan C W, Bhatia S N, et al. Probing the cytotoxicity of semiconductor quantum dots[J]. Nano Lett., 2004, 4(1):11-18.[14] Sung J C, Dusica M, Manasi J, et al. Long-term exposure to CdTe quantum dots causes functional impair-ments in live cells[J]. Langmuir, 2007, 23(4):1974-1980.[15] Wang X, Ma X L, Feng X, et al. Controlled synthesis and characterization of ZnSe and ZnS quantum dots[J]. Chin. J. Lumin. (发光学报), 2009, 30(6):818-823 (in Chinese).[16] Rogach A L, Kornowski A, Gao M Y, et al. Synthesis and characterization of a size series of extremely small thiol-stabilized CdSe nanocrystals[J]. J. Phys. Chem. B, 1999, 103(16):3065-3069.[17] Nanda J, Sameer S, Sarma D D, et al. Size-selected zinc sulfide nanocrystallites:Synthesis, structure,and optical studies[J]. Chem. Mater., 2000, 12(6):1018-1024.[18] Ma Y, Qi L M, Ma J M, et al. Facile synthesis of hollow ZnS nanospheres in block copolymersolutions[J]. Langmuir, 2003, 19(4):4040-4042.

浏览量

304

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

KYb₂F₇∶2% Er³⁺荧光材料的制备、发光机制及温度传感性能

离子掺杂钙钛矿量子点玻璃研究进展

激光诱导聚二甲基硅氧烷制备石墨烯量子点

新型钙钛矿纳米晶复合玻璃制备方法研究进展

碱金属共掺MgSc₂O₄:Er³⁺/Yb³⁺纳米晶的上转换发光性能