Ag纳米晶对Tm/Yb共掺碲酸盐玻璃上转换发光性能的影响

张文俊; 林健; 孙光耀; 贾玉洁; 钱帅; 任军江; 戎亮

doi:10.3788/fgxb20133405.0559

您当前的位置：

首页 >

文章列表页 >

Ag纳米晶对Tm/Yb共掺碲酸盐玻璃上转换发光性能的影响

材料合成及性能 | 更新时间：2020-08-12

- Ag纳米晶对Tm/Yb共掺碲酸盐玻璃上转换发光性能的影响
- Influence of Silver Nanocrystallites on The Upconversion Properties in Tm/Yb Co-doped Tellurite Glasses
- 发光学报 2013年34卷第5期页码：559-564
- 作者机构：
  
  1. 同济大学材料科学与工程学院上海,201804
  2. 同济大学先进土木工程材料教育部重点实验室上海,200092
  3. 中国电子科技集团公司第二十三研究所上海,200437
- 作者简介：
- 基金信息：
  
  上海市科学技术委员会科研计划(12nm0504700)及预研基金(9140A02040111DZ3301)资助项目()
- DOI：10.3788/fgxb20133405.0559
  中图分类号： O482.31
- 收稿日期：2013-01-24，
  
  修回日期：2013-03-16，
  
  纸质出版日期：2013-05-10
- 稿件说明：
移动端阅览
张文俊, 林健, 孙光耀, 贾玉洁, 钱帅, 任军江, 戎亮. Ag纳米晶对Tm/Yb共掺碲酸盐玻璃上转换发光性能的影响[J]. 发光学报, 2013,34(5): 559-564

ZHANG Wen-jun, LIN Jian, SUN Guang-yao, JIA Yu-jie, QIAN Shuai, REN Jun-jiang, RONG Liang. Influence of Silver Nanocrystallites on The Upconversion Properties in Tm/Yb Co-doped Tellurite Glasses[J]. Chinese Journal of Luminescence, 2013,34(5): 559-564
张文俊, 林健, 孙光耀, 贾玉洁, 钱帅, 任军江, 戎亮. Ag纳米晶对Tm/Yb共掺碲酸盐玻璃上转换发光性能的影响[J]. 发光学报, 2013,34(5): 559-564 DOI： 10.3788/fgxb20133405.0559.

ZHANG Wen-jun, LIN Jian, SUN Guang-yao, JIA Yu-jie, QIAN Shuai, REN Jun-jiang, RONG Liang. Influence of Silver Nanocrystallites on The Upconversion Properties in Tm/Yb Co-doped Tellurite Glasses[J]. Chinese Journal of Luminescence, 2013,34(5): 559-564 DOI： 10.3788/fgxb20133405.0559.

摘要

在稀土离子掺杂碲酸盐玻璃中引入Ag纳米晶

通过等离子共振(SPR)可使荧光发射得到增强

上转换发光效率得到明显提升。研究了Ag纳米晶对Tm

/Yb

共掺碲酸盐玻璃上转换发光的影响

分析了上转换发光机理。结果发现

经过(330℃

30 min)热处理后

玻璃中析出了Ag纳米颗粒

尺寸为5~8 nm。Ag纳米晶的引入可使玻璃上转换蓝、红光由三光子吸收转变为双光子吸收。由于局域场表面等离子体共振增强以及Ag与Tm

之间的能量转移

使得含Ag纳米晶玻璃的荧光强度比不含Ag纳米晶的玻璃提高了约5倍。

Abstract

By introducing Ag nanocrystallites into rare earth ions doped tellurite glass

the fluorescence intensity were enhanced through surface plasmon resonance (SPR)

and the up-conversion luminous efficiency were improved obviously. The influence of Ag nanocrystallites on Tm

/Yb

co-doped tellurate glass was studied

and the up-conversion luminescence mechanism was also discussed. The results show that Ag nanocrystallites with the size from 5 to 8 nm were gained by heat treatment under 330℃ for 30 min. After introducing Ag nanocrystallites

the three-photon absorption of blue-red transition in glass turn to two-photon absorption. Because of the enhanced local field surface plasmon resonance and the energy transfer between Ag and Tm

the fluorescence intensity of Ag-contained glass is 5 times more than glass without Ag nanocrystallites.

关键词

Keywords

references

Reza D M, Sahar M R, Ghoshal S K, et al. Effect of AgCl on spectroscopic properties of erbium doped zinc tellurite glass [J]. J. Molec. Structure, 2013, 1035:6-12.[2] Singh S K, Giri N K, Rai D K, et al. Enhanced upconversion emission in Er3+-doped tellurite glass containing silver nanoparticles [J]. Solid State Sci., 2010, 12(8):1480-1483.[3] Dousti M R, Sahar M R, Ghoshal S K, et al. Up-conversion enhancement in Er3+-Ag co-doped zinc tellurite glass effect of heat treatment [J]. J. Non-Cryst. Solids, 2012, 358(22):2939-2942.[4] De Assumpo T A A, Da Silva D M, Kassab L R P, et al. Influence of the temperature on the nucleation of silver nanoparticles in Tm3+/Yb3+ codoped PbO-GeO2 glasses [J]. J. Non-Cryst. Solids, 2010, 356(44/45/46/47/48/49):2465-2467.[5] Amjad R J, Sahar M R, Ghoshal S K, et al. Enhanced infrared to visible upconversion emission in Er3+ doped phosphate glass: Role of silver nanoparticles [J]. J. Lumin., 2012, 132(10):2714-2718.[6] Xu W, Chen D, Yan Q, et al. Silver metal enhanced photoluminescence of Tm3+ doped GeS2-Ga2S3-CsCl glasses[J]. J. Non-Cryst. Solids, 2012, 358(23):3065-3068.[7] De Assumpo T A A, Da Silva D M, Camilo M E, et al. Frequency upconversion properties of Tm3+ doped TeO2-ZnO glasses containing silver nanoparticles [J]. J. Alloys Comp., 2012, 536(1):5504-5506.[8] Chen D D, Chen B Y, Liu Y H, et al. Thermal stability and structure of glass systems of TeO2-ZnO [J]. Bull. Chin. Ceram. Soc.(硅酸盐通报), 2004, (5):86-89 (in Chinese).[9] Zhang J J, Duan Z C, He D B, et al. Progress and study on rare earth ions doped oxyfluoride glass ceramics for upconversion luminescence [J]. Laser & Optoelectronics Progress (激光与光电子学进展), 2005, 42(6):2-7 (in Chinese).[10] Som T, Karmakar B. Nano silver: Antimony glass hybrid nanocomposites and their enhanced fluorescence application [J]. Solid State Sci., 2011, 13(5):887-895.[11] Dai S X, Yang J H, Li S G, et al. Luminescence of Tm3+-doped tellurite glass pumped at 793 nm [J]. Acta Optica Sinica (光学学报), 2003, 23(1):105-108 (in Chinese).[12] Haro-Gonzlez P, Martn I R, Capuj N E, et al. Optical amplification by upconversion in Tm-Yb fluoroindate glass [J]. Opt. Mater., 2010, 32(10):1349-1351.[13] Wu Y, Xu T F, Shen X, et al. Influence of silver nanoparticles on the upconversion properties in Tm3+/Yb3+ codoped bismuth germanate glasses [J]. Acta Optica Sinica (光学学报), 2011, 31(7):271-275 (in Chinese).

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Ag纳米晶和辅助电场的引入对TeO₂-ZnO-Bi₂O₃玻璃发光性能的影响

Tm³⁺掺杂碲酸盐微结构光纤激光器

Er³⁺/Tm³⁺共掺碲酸盐玻璃光谱特性及能量传递