核壳结构纳米颗粒Gd2O3：Tb3+/SiOx 的制备及发光性能研究

欧梅桂; 蔡少韩; 杨春林; Pascal Perriat

doi:10.3788/fgxb20133405.0554

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核壳结构纳米颗粒Gd₂O₃：Tb³⁺/SiO_x 的制备及发光性能研究

材料合成及性能 | 更新时间：2020-08-12

- 核壳结构纳米颗粒Gd₂O₃：Tb³⁺/SiO_x 的制备及发光性能研究
- Preparation and Luminescent Properties of Core-shell Nanoparticles Gd₂O₃：Tb³⁺/SiO_x
- 发光学报 2013年34卷第5期页码：554-558
- 作者机构：
  
  1. 贵州大学材料与冶金学院,贵州贵阳,550025
  2. 贵阳学院化学与材料系,贵州贵阳,550003
  3. 里昂国立应用科学院里昂,法国,69621
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51201040)();贵州省科技厅国际合作项目(黔科合外G字[2011]7009 号,黔科合外G字[2012]7034 号)资助项目()
- DOI：10.3788/fgxb20133405.0554
  中图分类号： O482.31
- 收稿日期：2013-01-24，
  
  修回日期：2013-03-14，
  
  网络出版日期：2013-03-22，
  
  纸质出版日期：2013-05-10
- 稿件说明：
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欧梅桂, 蔡少韩, 杨春林, Pascal Perriat. 核壳结构纳米颗粒Gd2O3：Tb3+/SiOx 的制备及发光性能研究[J]. 发光学报, 2013,34(5): 554-558

OU Mei-gui, CAI Shao-han, YANG Chun-lin, Pascal Perriat. Preparation and Luminescent Properties of Core-shell Nanoparticles Gd2O3：Tb3+/SiOx[J]. Chinese Journal of Luminescence, 2013,34(5): 554-558
欧梅桂, 蔡少韩, 杨春林, Pascal Perriat. 核壳结构纳米颗粒Gd2O3：Tb3+/SiOx 的制备及发光性能研究[J]. 发光学报, 2013,34(5): 554-558 DOI： 10.3788/fgxb20133405.0554.

OU Mei-gui, CAI Shao-han, YANG Chun-lin, Pascal Perriat. Preparation and Luminescent Properties of Core-shell Nanoparticles Gd2O3：Tb3+/SiOx[J]. Chinese Journal of Luminescence, 2013,34(5): 554-558 DOI： 10.3788/fgxb20133405.0554.

摘要

以二甘醇为溶剂合成Gd

:Tb

纳米颗粒

并在其表面包覆聚硅氧烷层

得到核壳结构纳米颗粒Gd

:Tb

/SiO

。为了研究Tb

离子掺杂浓度对纳米颗粒发光性能的影响

采用几种不同Tb

掺杂浓度进行纳米颗粒的合成

并对其发光性能进行了检测。结果表明:包裹聚硅氧烷层后的Gd

:Tb

纳米颗粒分散较好

聚硅氧烷层不会减弱Gd

:Tb

纳米颗粒的发光性能。Tb

掺杂浓度对核壳结构纳米颗粒Gd

:Tb

/SiO

的发光存在浓度猝灭现象

猝灭摩尔分数为5%。这种具有发光特性的核壳结构纳米颗粒可作为生物传感器的探针用于生物分子的检测。

Abstract

-doped Gd

particles were synthesized in a polyol (diethylene glycol) medium. Core-shell nanoparticles Gd

:Tb

/SiO

were obtained by encapsulating Gd

:Tb

in a polysiloxane shell. In order to study the effect of Tb

ion doping concentration on luminescent properties of particles

synthesis were carried out with different Tb

doping concentrations

then luminescence of nanoparticles was measured. The result showed that nanoparticles Gd

:Tb

coated by polysiloxane were well-dispersed

and polysiloxane shell did not diminish luminescence of nanoparticles Gd

:Tb

.Tb

doping concentration effected the luminescent properties of core-shell particles Gd

:Tb

/SiO

by a quenching phenomenon when the Tb

doping mole fractioin exceeded 5%. The luminescent core-shell nanoparticles can be used as a biosensor probe in the detection of biological molecules.

关键词

Keywords

references

Liu J X, Huang Y H. Research & developments of nanomaterials & nanotechnology [J]. Mater. Rev. (材料导报), 2001, 15(8):29-31 (in Chinese).[2] Liu Z, Ling W, Xu B S, et al. The preparation methods and scientific development of nanostructured materials [J]. Mater. Sci. Technol. (材料科学与工艺), 2000, 8(3):103-108 (in Chinese).[3] Guo H, Sun Y, Zhou Y L. The investigation progress of rare earth doped nanocrystals [J]. Chin. Sci. Technol. Inform.(中国科技信息), 2010,104(12):211-212 (in Chinese).[4] Peng A H, Xie E Q, Jiang N, et al. The photoluminescence characterization of rare earths (Tb,Gd) embedded into porous silicon [J]. Acta Phys. Sinica (物理学报), 2003, 52(7):1792-1795 (in Chinese).[5] Ou M G, Mutelet B, Martini M, et al. Optimization of the synthesis of nanostructured Tb3+-doped Gd2O3 by in-situ luminescence following up [J]. J. Colloid Interf. Sci., 2009, 333(2):684-689.[6] Yang C L, Zeng J. Preparation and size investigation of nanoparticle Gd2O3:Tb3+ [J]. J. Guiyang College Natural Sciences (贵阳学院学报:自然科学版), 2010, 5(3):45-47 (in Chinese).[7] Guo Y F, Ma W M, Wen L, et al. Preparation and spectrm characteristics of (Y,Gd)2O3:Eu3+ nanoparticles [J]. Acta Metallurgica Sinica (金属学报), 2008, 44(9):1149-1152 (in Chinese).[8] Li Q, Gao L, Yan D S. Recent advances in nanoscale luminescent materials of rare earth compounds [J]. J.Inorg.Mater.(无机材料学报), 2001, 16(1):17-22 (in Chinese).[9] Huang Q P, Hong Z L, Zhang P Y, et al. Fabrication progress of rare earth doped oxysulfide phosphors [J]. Mater.Rev.(材料导报), 2006, 20(3):9-11 (in Chinese).[10] Zhang X S, Dong X Y, Li L, et al. Preparation and luminescence properties of YAGG:Tb,Gd thin films [J]. J. Optoelectronics Laser (光电子·激光), 2008, 19(5):636-639 (in Chinese).[11] Wang L S, Lin J, Zhou Y H. Synthesis of spherical YbO3:Eu phosphors by spray pyrolysis method [J]. Chem. J. Chin. Univ.(高等学校化学学报), 2004, 25(1):11-15 (in Chinese).[12] Liu L F, Lu S C. Preparation and luminescent properties of nanocrystalline Gd2O3:Eu3+ [J]. Chin. J. Lumin.(发光学报), 2009, 30(2):228-232 (in Chinese).[13] Ou Yang F P, Tang B. Study on energy transfer of Y2O2S:Tb nanocrystals [J]. Rare Metal Mater. Eng.(稀有金属材料与工程), 2003, 32(7):522-525 (in Chinese).[14] Hu Y J,Li C Z,Cong D Z, et al. Mechanism analysis and preparation of core-shell TiO2/SiO2 nanoparticles by H2/air flame combustions [J]. J. Inorg. Mater.(无机材料学报), 2007, 22(2):206-208 (in Chinese).[15] Zhai H, Cao L X, Liu W, et al. Synthesis and optical properties of CdS:Mn/ZnS core/shell nanocrystals [J]. J. Funct. Mater.(功能材料), 2011, 42(10):1898-1901 (in Chinese).[16] Ou M G, Yang C L, Perriat P. Influence of gadolinium concentration upon size of core-shell Gd2O3:Tb3+ nanoparticles [J]. Mater. Rev.(材料导报), 2012, 26(8):25-28 (in Chinese).

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