Yb3+和Er3+共掺杂的Y2O3,Y2O2S 和NaYS2粉末材料的上转换发光

张继森; 张立国; 任建岳; 段配华; 骆永石; 吕少哲

doi:10.3788/fgxb20133405.0542

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Yb³⁺和Er³⁺共掺杂的Y₂O₃,Y₂O₂S 和NaYS₂粉末材料的上转换发光

材料合成及性能 | 更新时间：2020-08-12

- Yb³⁺和Er³⁺共掺杂的Y₂O₃,Y₂O₂S 和NaYS₂粉末材料的上转换发光
- Upconversion Emission Properties in Yb³⁺-Er³⁺ Co-doped Y₂O₃, Y₂O₂S and NaYS₂ Powder Materials
- 发光学报 2013年34卷第5期页码：542-546
- 作者机构：
  
  中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11174276,11174278)资助项目()
- DOI：10.3788/fgxb20133405.0542
  中图分类号： O482.31
- 收稿日期：2013-02-28，
  
  修回日期：2013-04-01，
  
  网络出版日期：2013-03-22，
  
  纸质出版日期：2013-05-10
- 稿件说明：
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张继森, 张立国, 任建岳, 段配华, 骆永石, 吕少哲. Yb3+和Er3+共掺杂的Y2O3,Y2O2S 和NaYS2粉末材料的上转换发光[J]. 发光学报, 2013,34(5): 542-546

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue, DUAN Pei-hua, LUO Yong-shi, LÜ Shao-zhe. Upconversion Emission Properties in Yb3+-Er3+ Co-doped Y2O3, Y2O2S and NaYS2 Powder Materials[J]. Chinese Journal of Luminescence, 2013,34(5): 542-546
张继森, 张立国, 任建岳, 段配华, 骆永石, 吕少哲. Yb3+和Er3+共掺杂的Y2O3,Y2O2S 和NaYS2粉末材料的上转换发光[J]. 发光学报, 2013,34(5): 542-546 DOI： 10.3788/fgxb20133405.0542.

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue, DUAN Pei-hua, LUO Yong-shi, LÜ Shao-zhe. Upconversion Emission Properties in Yb3+-Er3+ Co-doped Y2O3, Y2O2S and NaYS2 Powder Materials[J]. Chinese Journal of Luminescence, 2013,34(5): 542-546 DOI： 10.3788/fgxb20133405.0542.

摘要

在980 nm LED激光器激发下

研究了 Yb

-Er

共掺杂的Y

S和NaYS

粉末材料的上转换发射特性。比较了Y

:0.20 Yb

0.03Er

和Y

S:0.20 Yb

0.03Er

以及NaYS

:0.20 Yb

0.03Er

粉末样品的上转换发光光谱

探讨了Er

上转换发射对基质的依赖性

分析了S

-Yb

和S

-Er

电荷转移态对Yb

-Er

间能量传递和能级间跃迁几率的影响

借助于能级图解释了在不同基质中Yb

-Er

间的能量传递和Er

的上转换发光机制。

Abstract

:0.20Yb

0.03Er

and Y

S: 0.20Yb

0.03Er

and NaYS

:0.20Yb

0.03Er

powder samples were synthesized with solid-state and solution reacting methods

respectively. The upconversion (UC) emission properties under a continuous-wave semiconductor laser diode excitation at 980 nm were studied. The relationship between UC emission features and the hosts was explored. Effects of the S

-Yb

and S

-Er

charge transfer state (CTS) on the transfer-energy rate from Yb

to Er

and the transition rate between the Er

levels were analyzed in details. Furthermore

the energy-transfer processes between Yb

and Er

based on the energy matching conditions and the UC emission mechanism were discussed with schematic energy-level schemes.

关键词

Keywords

references

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