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1. 中南大学化学化工学院 功能材料化学研究所,湖南 长沙,410083
2. 义守大学 电子工程系,台湾 高雄,84001
收稿日期:2011-11-20,
修回日期:2011-12-08,
网络出版日期:2012-02-10,
纸质出版日期:2012-02-10
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周智, 王峰超, 刘素琴, 刘又年, 李臻, 横山明聪. 高效率荧光粉转换型白光有机发光二极管的制备和性能研究[J]. 发光学报, 2012,33(2): 176-181
ZHOU Zhi, WANG Feng-chao, LIU Su-qin, LIU You-nian, LI Zhen, YOKOYAMA Meiso. High Efficient Phosphor-converted White Organic Light-emitting Diodes with Red Sr<sub>2</sub>Si<sub>5</sub>N<sub>8</sub>∶Eu<sup>2+</sup> Color Conversion Layer[J]. Chinese Journal of Luminescence, 2012,33(2): 176-181
周智, 王峰超, 刘素琴, 刘又年, 李臻, 横山明聪. 高效率荧光粉转换型白光有机发光二极管的制备和性能研究[J]. 发光学报, 2012,33(2): 176-181 DOI: 10.3788/fgxb20123302.0176.
ZHOU Zhi, WANG Feng-chao, LIU Su-qin, LIU You-nian, LI Zhen, YOKOYAMA Meiso. High Efficient Phosphor-converted White Organic Light-emitting Diodes with Red Sr<sub>2</sub>Si<sub>5</sub>N<sub>8</sub>∶Eu<sup>2+</sup> Color Conversion Layer[J]. Chinese Journal of Luminescence, 2012,33(2): 176-181 DOI: 10.3788/fgxb20123302.0176.
制备了一种荧光粉转换型白光有机发光二级管(pc-WOLEDs)
器件由发蓝光的荧光装置和发红光的无机荧光粉Sr
2
Si
5
N
8
∶Eu
2+
颜色转化层(CCL)复合组成
前者通过真空镀膜得到
后者采用旋涂法制备。CCL发射的红光和未被吸收的蓝光复合产生白光
最大发光效率为22.1 cd/A
最大能量效率为11.26 lm/W
外量子效率为10.2%。该pc-WOLEDs的色坐标为(0.32
0.34)
非常接近标准白光(0.33
0.33)。稳定性实验结果显示
该器件在不同电流密度下表现出了良好的稳定性。
Phosphor-converted white organic light emitting diodes (pc-WOLEDs) are fabricated by combining blue OLED with red Sr
2
Si
5
N
8
∶Eu
2+
phosphor spin coated color conversion layer (CCL). The pc-WOLED shows maximum luminous efficiency of 22.1 cd/A
maximum power efficiency of 11.26 lm/W
external quantum efficiency of 10.2% and CIE coordinates of (0.32
0.34). Moreover
the output spectral and CIE coordinates of the pc-WOLED have a small shift in different driving current density
which demonstrate good color stability.
Wang Q, Ding J, Ma D, et al. Manipulating charges and excitons within a single-host system to accomplish efficiency/CRI/color-stability trade-off for high-performance OWLEDs [J]. Adv. Mater., 2009, 21(23):2397-2401.[2] Xu Yang, Wang Hua, Song Chunli, et al. Synthesis and luminescence characteristics of near-white light-emitting copolymer [J]. Chin.J. Lumin. (发光学报), 2010, 31(2):274-278 (in Chinese).[3] Reineke S, Lindner F, Schwartz G, et al. White organic light-emitting diodes with fluorescent tube efficiency [J]. Nature, 2009, 459(7244):234-238.[4] Sun Y, Forrest S R. High-efficiency white organic light emitting devices with three separate phosphorescent emission layers [J]. Appl. Phys. Lett., 2007, 91(26):263503-263505.[5] Qi X, Slootsky M, Forrest S. Stacked white organic light emitting devices consisting of separate red, green, and blue elements [J]. Appl. Phys. Lett., 2008, 93(19):193306-193308.[6] Li Y T, Chen H, Chu M H, et al. Organic light-emitting devices with a coupled microcavity [J]. Chin. J. Lumin.(发光学报), 2011, 32(11):1186-1191 (in English).[7] Duggal A R, Shiang J J, Heller C M, et al. Organic light-emitting devices for illumination quality white light [J]. Appl. Phys. Lett., 2002, 80(19):3470-3472.[8] Mikami A, Mizuno Y, Tekeda S. High efficiency ultraviolet light emitting organic devices and its application to white light source [J]. SID Symposium Digest of Technical Papers, 2008, 39(1):215-218.[9] Yuan Y B, Li S, Wang Z, et al. White organic light-emitting diodes combining vacuum deposited blue electrophosphorescent devices with red surface color conversion layers [J]. Opt. Express., 2009, 17(3):1577-1582.[10] Xi Cuisheng, Gao Yuanzhe, Wang Ping, et al. Synthesis and luminescent properties of LiGd(MoO4)2∶Eu3+ red phosphors for white LEDs [J].Chin.J. Lumin. (发光学报), 2010, 31(3):311-315 (in Chinese).[11] Bhansali U S, Jia H, Lopez M A Q, et al. Controlling the carrier recombination zone for improved color stability in a two-dopant fluorophore/phosphor white organic light-emitting diode [J]. Appl. Phys. Lett., 2009, 94(20):203501-1-3.[12] Gather M C, Alle R, Becker H, et al. On the origin of the color shift in white-emitting OLEDs [J]. Adv. Mater., 2007, 19(24):4460-4465.[13] With G, Hintzen H T. The effect of replacement of Sr by Ca on the structural and luminescence properties of the red-emitting Sr2Si5N8∶Eu2+ LED conversion phosphor [J]. J. Solid State Chem., 2008, 181(3):515-524.[14] Stuart E B, Nathan P, Hintzen H T, et al. Robust thermal performance of Sr2Si5N8∶Eu2+∶An efficient red emitting phosphon for light emitting diode based white lighting [J] . Appl. Phys. Lett., 2011, 99(24):241106-241108.[15] Li Y Q, van Steen J E J, Hintzen H T, et al. Luminescence properties of red-emitting M2Si5N8∶Eu2+(M=Ca,Sr,Ba)LED conversiion phosphors [J] . J. Alloy Compd., 2006, 417(1-2):273-279.
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