基于咪唑并吡啶类配体新型磷光材料的合成与表征

孙军; 张玉祥; 席敏; 薛震; 张宏科; 何海晓

doi:10.3788/fgxb20123301.0041

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基于咪唑并吡啶类配体新型磷光材料的合成与表征

材料合成及性能研究 | 更新时间：2020-08-12

- 基于咪唑并吡啶类配体新型磷光材料的合成与表征
- Synthesis and Characterization of A New Framework Imidazo[1,2-a]pyridine Phosphorescent Ir(Ⅲ) Complexes
- 发光学报 2012年33卷第1期页码：41-44
- 作者机构：
  
  西安瑞联近代电子材料有限责任公司,陕西西安,710077
- 作者简介：
- 基金信息：
  
  国家"();863"();项目基金(2008AA03A328)资助项目()
- DOI：10.3788/fgxb20123301.0041
  中图分类号： TN383+.1
- 收稿日期：2011-10-14，
  
  修回日期：2011-11-13，
  
  网络出版日期：2012-01-10，
  
  纸质出版日期：2012-01-10
- 稿件说明：
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孙军, 张玉祥, 席敏, 薛震, 张宏科, 何海晓. 基于咪唑并吡啶类配体新型磷光材料的合成与表征[J]. 发光学报, 2012,33(1): 41-44

SUN Jun, ZHANG Yu-xiang, XI Min, XUE Zhen, ZHANG Hong-ke, HE Hai-xiao. Synthesis and Characterization of A New Framework Imidazo[1,2-a]pyridine Phosphorescent Ir(Ⅲ) Complexes[J]. 发光学报, 2012,33(1): 41-44
孙军, 张玉祥, 席敏, 薛震, 张宏科, 何海晓. 基于咪唑并吡啶类配体新型磷光材料的合成与表征[J]. 发光学报, 2012,33(1): 41-44 DOI： 10.3788/fgxb20123301.0041.

SUN Jun, ZHANG Yu-xiang, XI Min, XUE Zhen, ZHANG Hong-ke, HE Hai-xiao. Synthesis and Characterization of A New Framework Imidazo[1,2-a]pyridine Phosphorescent Ir(Ⅲ) Complexes[J]. 发光学报, 2012,33(1): 41-44 DOI： 10.3788/fgxb20123301.0041.

摘要

设计开发了系列新型咪唑并吡啶类铱(Ⅲ)配合物(BIPy)

Ir(acac)、(PIPy)

Ir(acac)、 (4'-MPIPy)

-Ir(acac)。在化合物Ⅲ中

当

=Ph时得到(BIPy)

Ir(acac)材料

其中BIPy和acac分别表示2-(4-联苯基)咪唑并吡啶和乙酰丙酮。将(BIPy)

Ir(acac)掺杂在N

N'-二咔唑-(1

1'-联苯)-4

4'-二胺(CBP)中制备了高效OLEDs器件

器件的最大电流效率为26.7 cd/A

最大亮度为18 000 cd/cm

色坐标为(0.32

0.60)

是首次报道的新型苯基咪唑并吡啶类铱(Ⅲ)配合物绿色磷光材料。

Abstract

Three iridium(Ⅲ) containing imidazo[1

2-a]pyridine complexes (PIPy)

Ir(acac)

(4'-MPIPy)

Ir(acac)

(BIPy)

Ir(acac) were synthesized based on reaction of iridium trichloride hydrate

2-Biphenyl-4-yl-imidazo[1

2-a]pyridine with acetylacetone. Doping multiplayer OLEDs were respectively fabricated based on (BIPy)

Ir(acac) with electron transporting ability. The doping device showed strong saturated green electrophosphorescent emission

the emission peak wavelength 516 nm and brightness of 18 000 cd/m

current efficiency of 26.7 cd/A with Commission International de L'Eclairage(CIE) coordinates of (0.32

0.60). This is the first report on new green phosphorescent material based on Ir(Ⅲ) complex.

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Keywords

references

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