聚芴类发光材料的制备及其在柔性电致发光器件的应用

朱棣; 贺英; 潘照东; 张瑶斐; 陈杰; 孙卓; 王均安

doi:10.3788/fgxb20123301.0017

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聚芴类发光材料的制备及其在柔性电致发光器件的应用

材料合成及性能研究 | 更新时间：2020-08-12

- 聚芴类发光材料的制备及其在柔性电致发光器件的应用
- Synthesis of The Polyfluorene Luminescent Material and Its Application in Flexible Polymer Light-emitting Diode
- 发光学报 2012年33卷第1期页码：17-20
- 作者机构：
  
  1. 上海大学材料科学与工程学院高分子材料系上海,200072
  2. 上海大学材料科学与工程学院材料研究所上海,200072
  3. 华东师范大学纳米光电集成与先进装备教育部工程研究中心, 上海 200062
- 作者简介：
- 基金信息：
  
  上海市科委纳米技术专项基金(1052nm07400)();上海市重点学科建设项目(S30107)();上海大学研究生创新基金(SHUCX112228)资助项目()
- DOI：10.3788/fgxb20123301.0017
  中图分类号： TN383+.1
- 收稿日期：2011-09-12，
  
  修回日期：2011-10-14，
  
  网络出版日期：2012-01-10，
  
  纸质出版日期：2012-01-10
- 稿件说明：
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朱棣, 贺英, 潘照东, 张瑶斐, 陈杰, 孙卓, 王均安. 聚芴类发光材料的制备及其在柔性电致发光器件的应用[J]. 发光学报, 2012,33(1): 17-20

ZHU Di, HE Ying, PAN Zhao-dong, ZHANG Yao-fei, CHEN Jie, SUN Zhuo, WANG Jun-an. Synthesis of The Polyfluorene Luminescent Material and Its Application in Flexible Polymer Light-emitting Diode[J]. 发光学报, 2012,33(1): 17-20
朱棣, 贺英, 潘照东, 张瑶斐, 陈杰, 孙卓, 王均安. 聚芴类发光材料的制备及其在柔性电致发光器件的应用[J]. 发光学报, 2012,33(1): 17-20 DOI： 10.3788/fgxb20123301.0017.

ZHU Di, HE Ying, PAN Zhao-dong, ZHANG Yao-fei, CHEN Jie, SUN Zhuo, WANG Jun-an. Synthesis of The Polyfluorene Luminescent Material and Its Application in Flexible Polymer Light-emitting Diode[J]. 发光学报, 2012,33(1): 17-20 DOI： 10.3788/fgxb20123301.0017.

摘要

通过Heck反应合成了PFO/PPV共聚物

采用FT-IR、

H NMR、TGA等对共聚物结构进行了表征

其重均分子量为4 400

分子量分布为1.2。共聚物具有良好的热稳定性

在室温到700 ℃范围内只有一次明显的失重

初始分解温度为280 ℃

在350~450 ℃之间失重约50%。

HOMO

LUMO

、

分别为-6.09/-3.20、2.89 eV。利用UV-Vis和PL研究了共聚物的光学性能

结果表明

共聚物具有较强的荧光性

其荧光最大发射峰位于490 nm波长处。将制备的共聚物薄膜作为发光层

引入纳米ZnO作为功能层

在柔性PET衬底上制作的PLED器件的启动电压为4.2 eV

发蓝光。

Abstract

The copolymer of polyfluorene/poly(p-Phenylene vinylenes) (PFO/PPV) was synthesized through Heck reaction. The structure of the obtained copolymer was characterized by FT-IR

H NMR

TGA

etc.

The molecular weight and poly dispersity of the copolymer were 4 400 and 1.2

respectively. The copolymer had good thermal stability

it had only one weightlessness from RT to 700 ℃ and the weightlessness was about 50% at 350~450 ℃.

HOMO

LUMO

and

was-6.09/[KG-*4]-3.20 and 2.89 eV respectively. The optical properties

revealed by UV-Vis and PL

showed that copolymer had excellent luminescence

with a maximum peak of fluorescence emission at 490 nm. The copolymer was also tested as an emitting layer for flexible polymer light-emitting diode (PLED) device

where nano ZnO as a functional layer

showing a turn-on voltage of about 4.2 V and emitting blue electroluminescence.

关键词

Keywords

references

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