白光LED用红色荧光粉CaSnO3 ∶ Eu3+的 制备及光学性质

付作岭; 付喜宏; 孙桂娟

doi:10.3788/fgxb20113207.0660

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白光LED用红色荧光粉CaSnO₃ ∶ Eu³⁺的制备及光学性质

材料合成及性能研究 | 更新时间：2020-08-12

- 白光LED用红色荧光粉CaSnO₃ ∶ Eu³⁺的制备及光学性质
- Preparation and Optical Properties of Red Emitting Phosphor CaSnO₃ ∶ Eu³⁺ for White LED
- 发光学报 2011年32卷第7期页码：660-664
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 吉林大学物理学院,吉林长春,130012
  3. 吉林大学超硬材料国家重点实验室,吉林长春,130012
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11004081)();中央高校基本科研业务费专项基金(450060326085)();吉林省留学人员科技创新创业基金(3D5112191411)资助
- DOI：10.3788/fgxb20113207.0660
  中图分类号： O482.31
- 收稿日期：2011-02-15，
  
  修回日期：2011-05-14，
  
  网络出版日期：2011-07-22，
  
  纸质出版日期：2011-07-22
- 稿件说明：
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付作岭, 付喜宏, 孙桂娟. 白光LED用红色荧光粉CaSnO3 ∶ Eu3+的制备及光学性质[J]. 发光学报, 2011,32(7): 660-664

FU Zuo-ling, FU Xi-hong, SUN Gui-juan. Preparation and Optical Properties of Red Emitting Phosphor CaSnO3 ∶ Eu3+ for White LED[J]. Chinese Journal of Luminescence, 2011,32(7): 660-664
付作岭, 付喜宏, 孙桂娟. 白光LED用红色荧光粉CaSnO3 ∶ Eu3+的制备及光学性质[J]. 发光学报, 2011,32(7): 660-664 DOI： 10.3788/fgxb20113207.0660.

FU Zuo-ling, FU Xi-hong, SUN Gui-juan. Preparation and Optical Properties of Red Emitting Phosphor CaSnO3 ∶ Eu3+ for White LED[J]. Chinese Journal of Luminescence, 2011,32(7): 660-664 DOI： 10.3788/fgxb20113207.0660.

摘要

采用水热法制备了CaSnO

∶ Eu

红色荧光粉

利用X射线粉末衍射、场发射扫描电镜和荧光光谱对CaSnO

∶ Eu

粉末进行了表征。实验结果表明

这种新型的荧光粉可以被紫外光280 nm、近紫外光395 nm和蓝光465 nm有效地激发

发射主峰位于614 nm。光谱分析结果表明

离子在晶体结构中占据了非反演对称中心的位置。395

465 nm的吸收与目前广泛应用的紫外和蓝光LED芯片的输出波长匹配。因此

这种荧光粉是一种可能应用在白光LED上的红色荧光材料。

Abstract

Europium (Ⅲ)-doped CaSnO

was prepared by hydrothermal method. The sample was characte-rized by X-ray diffraction

field emission-scanning electron microscopy (FE-SEM) and photoluminescence (PL). The experimental results indicate that this phosphor can be effectively excited by charge-transfer band (280 nm)

ultraviolet light 395 nm and blue light 465 nm. The wavelengths at 395 nm and 465 nm are nicely fitting with the emission wavelengths of widely applied ultraviolet or blue LED chips.

关键词

Keywords

references

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