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中山大学 光电材料与技术国家重点实验室,广东 广州,510275
收稿日期:2011-01-06,
修回日期:2011-03-02,
网络出版日期:2011-06-22,
纸质出版日期:2011-06-22
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陈双文, 王振, 周翔. 红光颜色转换层调节的顶发射有机白光器件[J]. 发光学报, 2011,32(6): 576-580
CHEN Shuang-wen, WANG Zhen, ZHOU Xiang. Top-emitting White Organic Light-emitting Diodes with Red Color Conversion Layers[J]. Chinese Journal of Luminescence, 2011,32(6): 576-580
陈双文, 王振, 周翔. 红光颜色转换层调节的顶发射有机白光器件[J]. 发光学报, 2011,32(6): 576-580 DOI: 10.3788/fgxb20113206.0576.
CHEN Shuang-wen, WANG Zhen, ZHOU Xiang. Top-emitting White Organic Light-emitting Diodes with Red Color Conversion Layers[J]. Chinese Journal of Luminescence, 2011,32(6): 576-580 DOI: 10.3788/fgxb20113206.0576.
采用倒置结构顶发射蓝光器件和非掺杂型红光染料NPAMLI制备了TWOLED
研究了器件结构和光电性能的关系
器件结构为Glass/Al/Cs
2
CO
3
/Alq
3
/AND/NPB/MoO
3
/Au/Alq
3
/NPAMLI。NPAMLI的吸收谱与ADN的发光谱有较大的重叠
NPAMLI能够吸收ADN发出的部分蓝光并发射红光。实验中改变NPAMLI的厚度来调节器件发光颜色
当NPAMLI的厚度为300 nm时
器件的最高效率为1.25 cd/A (0.71 lm/W)
发光色坐标为(0.330
0.292)。
Top-emitting white organic light-emitting diodes (TWOLEDs) have attracted intensive attention due to their great potential for high-resolution full color active matrix display and lighting applications. We have investigated optical and electrical characteristics of the TWOLED combining electroluminescence (EL) of blue material (ADN) with top color conversion layer (CCL) based on non-doped red material (NPAMLI). The TWOLED
with structure of Glass substrate/Al/Cs
2
CO
3
/Alq
3
/ADN/NPB/MoO
3
/Au/Alq
3
/NPAMLI
was fabricated by vacuum thermal evaporation. The 10 nm thick Au was used as top semitransparent anode
the 40 nm thick Alq
3
was used as a capping layer to improve the light out-coupling
and the non-doped red material NPAMLI was used as the CCL. The NPAMLI CCL showed strong absorption from 450 nm to 550 nm
which matched well with the emission of the ADN. The EL spectra of the TWOLED additionally contained a red component from NPAMLI
which absorbed a part of the blue EL of the ADN
and converted this to its red fluorescence. Therefore
the TWOLED yielded a white light emission resulting from final mixture of color-converted red light and unabsorbed blue light. The TWOLED with a peak current (power) efficiency of 1.25 cd/A (0.71 lm/W)
CIE coordinates of (0.330
0.292)
and a color rendering index of around 87.5
has been obtained.
Kim M S, Jeong C H, Lim J T, et al. White top-emitting organic light-emitting diodes using one-emissive layer of the DCJTB doped DPVBi layer [J]. Thin Solid Films, 2008, 516 (11):3590-3594.[2] Hsu S F, Lee C C, Hwang S W, et al. Highly efficient top-emitting white organic electroluminescent devices [J]. Appl. Phys. Lett., 2005, 86 (25):253508-1-3.[3] Kanno H, Sun Y R, Forrest S R. High-efficiency top-emissive white-light-emitting organic electrophosphorescent devices [J]. Appl. Phys. Lett., 2005, 86 (26):263502-1-3.[4] Ji W Y, Zhang L T, Gao R X, et al. Top-emitting white organic light-emitting devices with down-conversion phosphors: Theory and experiment [J]. Optics Express, 2008, 16 (20):15489-15494.[5] Zhang Z L, Jiang X Y, Zhu W Q, et al. White organic light emitting diodes and its stability [J]. Chin. J. Lumin.(发光学报), 2005, 26 (2):149-152 (in Chinese).[6] Zhang Chunyu, Lu Jingbin, Qin Li, et al. Design and fabrication of organic light emitting white color microcavity device [J]. Chin. J. Lumin.(发光学报), 2009, 30 (5):596-600 (in Chinese).[7] Wang Hongjie, Zhang Chunyu. Simulation of microcavity organic light-emitting device at different exciton positions [J]. Chin. J. Lumin. (发光学报), 2010, 31 (2):167-170 (in Chinese).[8] Zhang Chunyu, Lu Jingbin, Guo Shuxu, et al. Performance of resonant cavity mirrors of microcavity organic light-emitting device [J]. Chin. J. Lumin. (发光学报), 2010, 31 (4):493-497 (in Chinese).[9] Wu W C, Yeh H C, Chan L H, et al. Red organic light-emitting diodes with a non-doping amorphous red emitter [J]. Adv. Mater., 2002, 14 (15):1072-1075.[10] Thomas K R J, Lin J T, Tao Y T, et al. Star-shaped thieno- -pyrazines: A new class of red-emitting electro-luminescent materials [J]. Adv. Mater., 2002, 14 (11):822-826.[11] Shi J M, Tang C W. Anthracene derivatives for stable blue-emitting organic electroluminescence devices [J]. Appl. Phys. Lett., 2002, 80 (17):3201-3203.[12] Li Y Q, Fung M K, Xie Z, et al. An efficient pure blue organic light-emitting device with low driving voltages [J]. Adv. Mater., 2002, 14 (18):1317-1321.[13] Qiao Xiaoping, Yuan Yongbo, Zhou Xiang. Improvement of OLED outcoupling efficiency using microsphere monolayer [J]. Chin. J. Lumin.(发光学报), 2010, 31 (2):171-175 (in Chinese).
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