Ce3+离子激活的(氟)磷酸盐基质发光材料的光谱特性

梁宏斌; 田梓峰; 钟玖平; 潘国强; 张国斌; 石军岩; 苏锵

doi:10.3788/fgxb20113205.0411

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Ce³⁺离子激活的(氟)磷酸盐基质发光材料的光谱特性

特邀报告 | 更新时间：2020-08-12

- Ce³⁺离子激活的(氟)磷酸盐基质发光材料的光谱特性
- Luminescence of Ce³⁺ Activated (Fluoro-) Phosphates Under VUV-UV and X-ray Excitation
- 发光学报 2011年32卷第5期页码：411-416
- 作者机构：
  
  1. 中国科学技术大学国家同步辐射实验室合肥,230029
  2. 中山大学化学与化学工程学院光电材料与技术国家重点实验室生物无机与合成化学教育部重点实验室,广东广州,510275
- 作者简介：
- 基金信息：
  
  国家自然科学基金(10979027, 20871121)();广东省自然科学基金(9151027501000003)资助项目()
- DOI：10.3788/fgxb20113205.0411
  中图分类号： O482.31;O614.33
- 收稿日期：2011-01-26，
  
  修回日期：2011-03-23，
  
  网络出版日期：2011-05-22，
  
  纸质出版日期：2011-05-22
- 稿件说明：
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梁宏斌, 田梓峰, 钟玖平, 潘国强, 张国斌, 石军岩, 苏锵. Ce3+离子激活的(氟)磷酸盐基质发光材料的光谱特性[J]. 发光学报, 2011,32(5): 411-416

LIANG Hong-bin, TIAN Zi-feng, ZHONG Jiu-ping, PAN Guo-qiang, ZHANG Guo-bin, SHI Jun-yan, SU Qiang. Luminescence of Ce3+ Activated (Fluoro-) Phosphates Under VUV-UV and X-ray Excitation[J]. Chinese Journal of Luminescence, 2011,32(5): 411-416
梁宏斌, 田梓峰, 钟玖平, 潘国强, 张国斌, 石军岩, 苏锵. Ce3+离子激活的(氟)磷酸盐基质发光材料的光谱特性[J]. 发光学报, 2011,32(5): 411-416 DOI： 10.3788/fgxb20113205.0411.

LIANG Hong-bin, TIAN Zi-feng, ZHONG Jiu-ping, PAN Guo-qiang, ZHANG Guo-bin, SHI Jun-yan, SU Qiang. Luminescence of Ce3+ Activated (Fluoro-) Phosphates Under VUV-UV and X-ray Excitation[J]. Chinese Journal of Luminescence, 2011,32(5): 411-416 DOI： 10.3788/fgxb20113205.0411.

摘要

利用高温固相反应方法合成了Ce

离子激活的氟磷酸盐基质发光材料Na

0.99

0.01

和多磷酸盐基质发光材料

0.99

0.01

(PO

)

(

=Na

Cs)。通过光谱研究发现

在Na

0.99

0.01

的真空紫外-紫外(VUV-UV)激发光谱上

可以看到Ce

离子中心波长分别在316

266

235

216

206 nm等处的5个fd跃迁激发带

其5d

(

=5/2

7/2)发射峰分别位于350

375 nm

由此推测Ce

离子在该氟磷酸盐基质晶格中可能只占据一个格位。研究了Ce

离子激活多磷酸盐样品

0.99

0.01

(PO

)

(

=Na

Cs)在紫外光和X射线激发下的发光性质

发现该系列多磷酸盐样品在X射线激发下有较高的光产额

有可能被发展成为一类性能优良的闪烁体发光材料。

Abstract

activated phosphors

fluorophosphate Na

0.99

0.01

and polyphosphates

0.99

-Ce

0.01

(PO

)

(

=Na

Cs)

were prepared using a high-temperature solid-state reaction technique. Five excitation bands were observed at about 316

266

235

216

206 nm from Ce

5d in Na

0.99

0.01

and two emission bands from Ce

5d-4f were found at about 350

375 nm. On the basis of these observations

it is assumed that Ce

ions occupy one lattice site in Na

0.99

0.01

. The luminescence of

0.99

0.01

(PO

)

(

=Na

Cs) under X-ray excitation revealed that these phosphors have high light-yields under X-ray excitation

showing that they may be potential scintillation materials.

关键词

Keywords

references

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