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中国计量学院 光学与电子科技学院,浙江 杭州,310018
收稿日期:2010-10-14,
修回日期:2010-11-22,
网络出版日期:2011-04-22,
纸质出版日期:2011-04-22
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李晨霞, 韦萍, 尹雷, 叶仁广, 华有杰, 徐时清. Ti<sup>4+</sup> 掺杂硼硅酸盐微晶玻璃的光谱特性[J]. 发光学报, 2011,32(4): 353-357
LI Chen-xia, WEI Ping, YIN Lei, YE Ren-guang, DENG De-gang, HUA You-jie, XU Shi-qing. Optical Properties of Ti<sup>4+</sup> Doped Glass Ceramics[J]. Chinese Journal of Luminescence, 2011,32(4): 353-357
李晨霞, 韦萍, 尹雷, 叶仁广, 华有杰, 徐时清. Ti<sup>4+</sup> 掺杂硼硅酸盐微晶玻璃的光谱特性[J]. 发光学报, 2011,32(4): 353-357 DOI: 10.3788/fgxb20113204.0353.
LI Chen-xia, WEI Ping, YIN Lei, YE Ren-guang, DENG De-gang, HUA You-jie, XU Shi-qing. Optical Properties of Ti<sup>4+</sup> Doped Glass Ceramics[J]. Chinese Journal of Luminescence, 2011,32(4): 353-357 DOI: 10.3788/fgxb20113204.0353.
制备了Ti
4+
掺杂硼硅酸盐玻璃
根据玻璃样品的差热分析(DTA)进行微晶化处理
测试了Ti
4+
掺杂硼硅酸盐微晶玻璃的X射线衍射(XRD)谱、透射电镜(TEM)图像、吸收光谱和发射光谱。根据Scherrer公式计算了BaYF
5
微晶的平均晶粒尺寸并与TEM图像进行比对。在紫外光激发下
观察到Ti
4+
掺杂BaYF
5
硼硅酸盐微晶玻璃强烈的宽带发光(300~800 nm)
对应于Ti
4+
(3d
0
)-O
2-
(2s
2
3p
6
)的电荷迁移跃迁
与未经热处理玻璃样品相比
微晶玻璃的发光强度增强。通过优化热处理温度和掺杂浓度
得到了紫外光激发下发白光的Ti
4+
掺杂BaYF
5
硼硅酸盐玻璃
对应的色坐标为 (0.261
0.351)。
Ti
4+
doped borosilicate glass has been prepared. The as-made glass was heat-treated and crystallized. X-ray diffraction (XRD)
TEM
absorption spectrum and emission spectrum of glass ceramics were measured. Crystallite size of BaYF
5
glass ceramics were calculated by Scherrer formula and the comparing with the result of TEM. White emission band (300~800 nm) originated from the charge transferring of Ti
4+
(3d
0
)-O
2-
(2s
2
3p
6
) can be observed in Ti
4+
doped borosilicate glass ceramics. Comparing with the as-made glass
significantly increased luminescence was observed in the glass ceramics. By optimizing the heat treat temperature and concentration of Ti
4+
borosilicate glass ceramics with CIE coordinate (0.261
0.351) can be obtained which is close to the standard white-light illumination (0.333
0.333).
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