新型双&beta;-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光

刘万云; 霍平; 伍晓春; 梅光泉

doi:10.3788/fgxb20113201.0033

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新型双β-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光

材料合成及性能研究 | 更新时间：2020-08-12

- 新型双β-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光
- Synthesis, Luminescent Properties of New Ternary Complex of Eu³⁺ with Bis(β-diketone) and 1,10-phenanthroline
- 发光学报 2011年32卷第1期页码：33-37
- 作者机构：
  
  1. 宜春学院江西省高校应用化学与化学生物学重点实验室, 江西宜春 336000
  2. 宜春学院江西省天然药物活性成分研究重点实验室,江西宜春,336000
  3. 宜春学院化学与生物工程学院,江西宜春,336000
- 作者简介：
- 基金信息：
  
  江西省自然科学基金(2008GZH0063)();江西省教育厅科技项目(GJJ08528,GJJ09636)资助项目()
- DOI：10.3788/fgxb20113201.0033
  中图分类号： O482.31
- 收稿日期：2010-01-11，
  
  修回日期：2010-04-01，
  
  网络出版日期：2011-01-22，
  
  纸质出版日期：2011-01-22
- 稿件说明：
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刘万云, 霍平, 伍晓春, 梅光泉. 新型双β-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光[J]. 发光学报, 2011,32(1): 33-37

LIU Wan-yun, HUO Ping, WU Xiao-chun, MEI Guang-quan. Synthesis, Luminescent Properties of New Ternary Complex of Eu<sup>3+</sup> with Bis(β-diketone) and 1,10-phenanthroline[J]. Chinese Journal of Luminescence, 2011,32(1): 33-37
刘万云, 霍平, 伍晓春, 梅光泉. 新型双β-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光[J]. 发光学报, 2011,32(1): 33-37 DOI： 10.3788/fgxb20113201.0033.

LIU Wan-yun, HUO Ping, WU Xiao-chun, MEI Guang-quan. Synthesis, Luminescent Properties of New Ternary Complex of Eu<sup>3+</sup> with Bis(β-diketone) and 1,10-phenanthroline[J]. Chinese Journal of Luminescence, 2011,32(1): 33-37 DOI： 10.3788/fgxb20113201.0033.

摘要

合成了一个新型双-二酮有机配体1

3-双苯、邻菲罗啉和铕的三元配合物

并应用红外光谱、紫外-可见光谱、元素分析和热重-差热分析等对配合物进行了组成确定和结构表征。荧光分析结果表明

配合物612 nm 处的发射光谱为中心离子Eu

的特征红光

属

跃迁带

峰形尖锐

单色性好

表明该固体铕双-二酮配合物是一种潜在的红色发光材料。

Abstract

A new ternary complex of Eu

with bis(-diketone) ligand 1

3-bis benzene and 1

10-phenanthroline was synthesized. The properties of this complex were characterized by IR

UV-Visible spectrometry

elemental analysis and TG-DSC.The photoluminescence of complex indicated that there is a sharp and strong red emission peak at 612 nm attributed to

transition of Eu

ion. The results showed that this Eu

-bis(-diketone) complex would be a potential excellent red emission material.

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Keywords

references

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新型双β-二酮、邻菲罗啉和铕(Ⅲ)三元配合物的合成与发光

Synthesis, Luminescent Properties of New Ternary Complex of Eu3+ with Bis(β-diketone) and 1,10-phenanthroline

DOI：10.3788/fgxb20113201.0033

摘要

Abstract

关键词

Keywords

references

Synthesis, Luminescent Properties of New Ternary Complex of Eu³⁺ with Bis(β-diketone) and 1,10-phenanthroline