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1.长春师范大学 物理学院, 吉林 长春 130032
2.中国科学院长春光学精密机械与物理研究所 发光学及应用国家重点实验室, 吉林 长春 130033
[ "李敏 (1999-),女,山东济南人,硕士研究生,2021年于长春师范大学获得学士学位,主要从事稀土发光材料的研究。" ]
[ "孙晓园(1978-),女,黑龙江克山人,博士,教授,2008年于中国科学院长春光学精密机械与物理研究所获得博士学位,主要从事稀土发光材料及功能微结构的研究。" ]
收稿日期:2023-06-20,
修回日期:2023-07-07,
纸质出版日期:2023-11-05
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李敏,孙晓园,范小暄等.Sr6Lu2Al4O15∶Tb3+荧光粉的发光特性[J].发光学报,2023,44(11):1940-1949.
LI Min,SUN Xiaoyuan,FAN Xiaoxuan,et al.Photoluminescence Properties of Sr6Lu2Al4O15∶Tb3+ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1940-1949.
李敏,孙晓园,范小暄等.Sr6Lu2Al4O15∶Tb3+荧光粉的发光特性[J].发光学报,2023,44(11):1940-1949. DOI: 10.37188/CJL.20230147.
LI Min,SUN Xiaoyuan,FAN Xiaoxuan,et al.Photoluminescence Properties of Sr6Lu2Al4O15∶Tb3+ Phosphor[J].Chinese Journal of Luminescence,2023,44(11):1940-1949. DOI: 10.37188/CJL.20230147.
采用高温固相法制备了颜色可调的Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
荧光粉,并研究了其晶体结构、发光特性和浓度猝灭机理。研究了Tb
3+
浓度对样品发光性质的影响。在紫外光激发下,当
x
=0.01时,Tb
3+
的
5
D
3
⁃
7
F
6
跃迁强度最强,峰值位于381 nm;当
x
=0.15时,Tb
3+
的
5
D
4
⁃
7
F
5
跃迁强度最强,峰值位于545 nm。随着Tb
3+
掺杂浓度的升高,样品的发光颜色从蓝光变为黄绿光。分析了Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
荧光粉的浓度猝灭机理。测量了荧光粉的荧光寿命、热稳定性、量子效率。结果表明,Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
是一种新型的发光颜色可调的荧光粉。
The phosphors Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
were synthesized through the solid-state reaction technique. The structure, photoluminescence properties and concentration quenching mechanisms were researched. The dependence of photoluminescence intensities on Tb
3+
concentration was studied. Upon excitation with UV excitation, when the doping concentration
x
=0.01, the strongest peak located around 381 nm, which arise from
5
D
3
-
7
F
6
transition of Tb
3+
; when the doping concentration
x
=0.15, the strongest peak located around 545 nm, which arise from
5
D
4
-
7
F
5
transition of Tb
3+
. The luminescence color changes from blue to yellowish green by adjusting the doping concentration of Tb
3+
. The concentration quenching mechanisms of Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
were studied. The lifetime, thermal stability and quantum efficiency were measured. The Sr
6
Lu
2-2
x
Al
4
O
15
∶
x
Tb
3+
phosphor is a novel color-tunable phosphor.
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