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1.中国科学院福建物质结构研究所 光电子材料化学与物理重点实验室, 福建 福州 350002
2.福州大学 化学学院, 福建 福州 350108
3.中国福建光电信息科学与技术创新实验室(闽都创新实验室), 福建 福州 350108
[ "方高阳(1995-),男,江西赣州人,硕士研究生,2019年于南昌航空大学获得学士学位,主要从事激光晶体的研究。 E-mail: fanggaoyang@fjirsm.ac.cn" ]
[ "涂朝阳(1963-),男,福建福州人,博士,研究员,博士生导师,2003年于中国科学院福建物质结构研究所获得博士学位,主要从事激光晶体和非线性光学晶体新材料的探索研究。 E-mail: Tcy@fjirsm.ac.cn" ]
收稿日期:2022-03-19,
修回日期:2022-04-03,
纸质出版日期:2022-11-05
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方高阳,王燕,游振宇等.Sr3Gd(BO3)3∶Dy3+/RE3+(RE=Tb, Eu)晶体的生长、发光性质及能量传递[J].发光学报,2022,43(11):1721-1732.
FANG Gao-yang,WANG Yan,YOU Zhen-yu,et al.Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr3Gd(BO3)3∶Dy3+/RE3+(RE=Tb, Eu) Crystals[J].Chinese Journal of Luminescence,2022,43(11):1721-1732.
方高阳,王燕,游振宇等.Sr3Gd(BO3)3∶Dy3+/RE3+(RE=Tb, Eu)晶体的生长、发光性质及能量传递[J].发光学报,2022,43(11):1721-1732. DOI: 10.37188/CJL.20220094.
FANG Gao-yang,WANG Yan,YOU Zhen-yu,et al.Crystal Growth, Spectral Properties and Energy Transfer Mechanisms of Sr3Gd(BO3)3∶Dy3+/RE3+(RE=Tb, Eu) Crystals[J].Chinese Journal of Luminescence,2022,43(11):1721-1732. DOI: 10.37188/CJL.20220094.
黄光激光在医疗美容、原子冷却与捕获、激光雷达等领域具有潜在的应用前景,因此,黄光激光器的研究具有重要意义。Dy
3+
因其
4
F
9/2
→
6
H
13/2
辐射跃迁而成为黄光激光的最佳激活离子,但是其在可见光波段为自旋禁戒跃迁,导致其吸收截面和发射截面都很小,从而引起黄光激光输出困难。本文通过提拉法成功生长了Dy
3+
∶Sr
3
Gd(BO
3
)
3
(缩写Dy
3+
∶SGB)、Dy
3+
/Tb
3+
∶SGB和Dy
3+
/Eu
3+
∶SGB晶体,通过室温偏振吸收谱、发射谱、荧光衰减曲线以及Judd-Ofelt理论计算分析了其光谱性能和能量传递机制。研究表明,共掺Tb
3+
和Eu
3+
增大了Dy
3+
在黄光波段的发射截面和荧光量子效率,有利于Dy
3+
的黄光输出。此外,证明了Dy
3+
/Tb
3+
∶SGB晶体中发生了Dy
3+
和Tb
3+
之间相互能量传递过程,Dy
3+
/Eu
3+
∶SGB晶体中仅有Dy
3+
→Eu
3+
的能量传递过程。
The yellow lasers are of great importance as they have potential applications in the areas such as medical aesthetics, atomic cooling and trapping, and radar. Dy
3+
is the best activating ion for yellow lasers due to its
4
F
9/2
→
6
H
13/2
radiative transition, but its spin-forbidden transition in the visible wavelength leads to a small absorption and emission cross section, which causes difficulties in yellow laser output. In this paper, Dy
3+
∶Sr
3
Gd(BO
3
)
3
(abbreviation Dy
3+
∶SGB), Dy
3+
/Tb
3+
∶SGB and Dy
3+
/Eu
3+
∶SGB crystals were successfully grown by the Czochralski method, and their spectral properties and energy transfer mechanisms were analyzed by room-temperature polarization absorption spectra, emission spectra, fluorescence decay curves and Judd-Ofelt theoretical calculations. It is shown that the co-dopant of Tb
3+
and Eu
3+
increases the emission cross section and fluorescence quantum efficiency of Dy
3+
in the yellow emission band, which is favorable to the yellow laser output of Dy
3+
. In addition, it is demonstrated that a mutual energy transfer process between Dy
3+
and Tb
3+
occurs in Dy
3+
/Tb
3+
∶SGB crystals and only Dy
3+
→Eu
3+
in Dy
3+
/Eu
3+
∶SGB crystals.
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