碲掺杂钙-铝-锗酸盐玻璃宽带近红外发光及其调控机理

周港杰; 胡艺萱; 谭林玲; 康世亮; 林常规

doi:10.37188/CJL.20210337

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碲掺杂钙-铝-锗酸盐玻璃宽带近红外发光及其调控机理

材料合成及性能 | 更新时间：2022-01-14

- 碲掺杂钙-铝-锗酸盐玻璃宽带近红外发光及其调控机理
  增强出版
- Broadband Near-infrared Luminescence and Regulation Mechanism of Tellurium-doped Calcium-Aluminum-germanate Glass
- 发光学报 2022年43卷第1期页码：51-57
- 作者机构：
  
  宁波大学高等技术研究院　红外材料及器件实验室，浙江　宁波　315211
- 作者简介：
  
  [ "周港杰(1998-)，男，浙江绍兴人，硕士研究生，2020年于宁波工程学院获得学士学位，主要从事飞秒激光诱导玻璃析出晶体及其光学性能方面的研究。E-mail: zgj2817@163.com" ]
  [ "谭林玲(1991-)，女，陕西安康人，博士，讲师，2020年于华南理工大学获得博士学位，主要从事新型超宽带激光玻璃及光纤激光的研究。E-mail: tanlinling @nbu.edu.cn" ]
  [ "林常规(1984-)，男，浙江温州人，博士，研究员，2010年于武汉理工大学获得博士学位，主要从事特种玻璃材料光功能开发及其器件化(包括玻璃晶化机理、光功能玻璃陶瓷材料、红外玻璃材料、基于硫系玻璃的红外光学系统等)的研究。E-mail: linchanggui@nbu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(62105170)
- DOI：10.37188/CJL.20210337
  中图分类号： O482.31
- 收稿：2021-10-28，
  
  修回：2021-11-09，
  
  纸质出版：2022-01
- 稿件说明：
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周港杰, 胡艺萱, 谭林玲, 等. 碲掺杂钙-铝-锗酸盐玻璃宽带近红外发光及其调控机理[J]. 发光学报, 2022,43(1):51-57.

Gang-jie ZHOU, Yi-xuan HU, Lin-ling TAN, et al. Broadband Near-infrared Luminescence and Regulation Mechanism of Tellurium-doped Calcium-Aluminum-germanate Glass[J]. Chinese Journal of Luminescence, 2022, 43(1): 51-57.
周港杰, 胡艺萱, 谭林玲, 等. 碲掺杂钙-铝-锗酸盐玻璃宽带近红外发光及其调控机理[J]. 发光学报, 2022,43(1):51-57. DOI： 10.37188/CJL.20210337.

Gang-jie ZHOU, Yi-xuan HU, Lin-ling TAN, et al. Broadband Near-infrared Luminescence and Regulation Mechanism of Tellurium-doped Calcium-Aluminum-germanate Glass[J]. Chinese Journal of Luminescence, 2022, 43(1): 51-57. DOI： 10.37188/CJL.20210337.

摘要

可调宽带近红外发光材料作为红外光源和可调谐光纤激光器核心组件，在高容量光纤通信、成像和遥感等现代技术中发挥着至关重要的作用。本文研究了碲掺杂钙-铝-锗酸盐玻璃的宽带近红外发光性能调控方案及其机理。通过引入碳构建还原气氛，还原TeO

原料为碲原子；再优化CaO、Al

含量，调整碲掺杂钙-铝-锗酸盐玻璃中碲拓扑笼的结构和大小，稳定并调控碲团簇发光中心，实现高效且可调谐的宽带近红外发光。最后通过改变TeO

掺杂含量，提供可形成团簇的合适含量碲源，进一步增强碲近红外发光，并揭示了碲近红外发光性能调控机理。本研究为未来宽带、高效、可调谐的近红外发光材料设计提供了重要指导，推进了其在宽带光放大器和可调谐激光器中的应用。

Abstract

Tunable broadband near-infrared(NIR)-emitting materials play a crucial role as NIR light sources and tunable fiber lasers in modern technologies such as high-capacity telecommunication

imaging

and remote sensing. In this work

we report the control scheme and mechanism of the broadband near-infrared luminescence properties in the tellurium-doped calcium-aluminum-germanate glass. By introducing carbon to construct a reducing atmosphere

the raw material TeO

is reduced to tellurium element. Through optimizing CaO and Al

content

the configurations and size of topological cages in tellurium doped calcium-aluminum-germanate glass were adjusted to stabilize and tailor tellurium clusters

enabling tunable NIR emission. Furthermore

adjusting the content of TeO

provides optimal tellurium source to form clusters

and thus enhancing tellurium NIR luminescence. The regulation mechanism of tellurium NIR luminescence performance in the calcium-aluminum-germanate glass is clarified. This work provides important guidance for the design of broadband

efficient and tunable NIR luminescent materials

promoting their practical application in broadband optical amplifiers and tunable lasers.

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references

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