高长径比Eu3+掺杂Y2O3荧光陶瓷纤维的制备及其发光性能

张立振; 王子豪; 黄娇; 唐飞

doi:10.37188/CJL.20210297

您当前的位置：

首页 >

文章列表页 >

高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能

材料合成及性能 | 更新时间：2021-12-17

- 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能
  增强出版
- Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio
- 发光学报 2021年42卷第12期页码：1891-1899
- 作者机构：
  
  1.江苏师范大学物理与电子工程学院　江苏省先进激光材料与器件重点实验室，江苏　徐州　221116
  2.中国人民解放军32506部队，江苏　徐州　221116
- 作者简介：
  
  [ "张立振(1994-)，男，江苏徐州人，硕士研究生，2019年于长春理工大学获得学士学位，主要从事无机发光材料制备及性能的研究。E-mail: 2020201181@jsnu.edu.cn" ]
  [ "唐飞(1985-)，男，江苏淮安人，博士，教授，2013年于中国科学院福建物质结构研究所获得博士学位，主要从事透明陶瓷、高效发光材料及光谱物理等方向的研究。E-mail: ftang@jsnu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金青年项目(51902144);江苏省自然科学基金青年项目(BK20191003);2020年江苏省特聘教授项目;2020年江苏省“中红外激光技术”双创团队
- DOI：10.37188/CJL.20210297
  中图分类号： O482.31
- 收稿日期：2021-09-08，
  
  修回日期：2021-09-25，
  
  纸质出版日期：2021-12
- 稿件说明：
移动端阅览
张立振, 王子豪, 黄娇, 等. 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能[J]. 发光学报, 2021,42(12):1891-1899.

Li-zhen ZHANG, Zi-hao WANG, Jiao HUANG, et al. Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio[J]. Chinese journal of luminescence, 2021, 42(12): 1891-1899.
张立振, 王子豪, 黄娇, 等. 高长径比Eu³⁺掺杂Y₂O₃荧光陶瓷纤维的制备及其发光性能[J]. 发光学报, 2021,42(12):1891-1899. DOI： 10.37188/CJL.20210297.

Li-zhen ZHANG, Zi-hao WANG, Jiao HUANG, et al. Fabrication and Photoluminescence Properties of Eu³⁺ Doped Y₂O₃ Ceramic Fiber with High Aspect Ratio[J]. Chinese journal of luminescence, 2021, 42(12): 1891-1899. DOI： 10.37188/CJL.20210297.

摘要

采用浆料直写(DIW)挤出成型工艺结合高温固相反应烧结技术，成功制备出高长径比稀土Eu

掺杂Y

荧光陶瓷纤维。分别研究了陶瓷膏体的流变性能、陶瓷纤维的相结构和荧光动力学、以及不同温度下陶瓷纤维的荧光光谱演变。研究结果表明，采用羟丙基甲基纤维素(HPMC)水凝胶作为陶瓷膏体的有机助剂，最佳的粉体固含量为55%。烧结温度

1 200 ℃下均可得到纯的陶瓷晶相，随着温度的升高，陶瓷相没有明显变化，但在1 300 ℃下烧结得到的样品荧光寿命最长，可达1.12 ms。进一步表征了该温度下烧结样品的变温光致发光光谱，随着温度从100 K上升至500 K，发光光谱的积分强度没有明显降低，表明所制备的样品具有优异的发光热稳定性。

Abstract

doped Y

ceramic fiber phosphor with high aspect ratio was successfully fabricated by using direct ink writing(DIW) extrusion process combined with high temperature solid-state reaction method. The rheological properties of ceramic paste

phase structure and luminescence kinetic of ceramic fiber

as well as the temperature dependent photoluminescence(PL) spectra were successively investigated. The obtained results indicated that the optimal solid content was 55% for the ceramic paste with HPMC hydrogels as the additive. Pure ceramic phase could be achieved at the sintering temperature of

1 200 ℃. With increasing the temperature to 1 500 ℃

no significant change was observed for the phase structure. From the steady-state and transient PL spectra

the optimum luminescence performance was observed for the sample sintered at 1 300 ℃ with the luminescence lifetime of 1.12 ms. Finally

the temperature dependence of PL spectra was carefully studied

and the luminescence properties were not deteriorated with increasing temperature from 100 K to 500 K. Such a result may indicate an excellent luminescence thermal stability for our ceramic fiber.

关键词

Keywords

references

LIU H W , YU D D , NIU P J , et al . Lifetime prediction of a multi-chip high-power LED light source based on artificial neural networks [J]. Results Phys. , 2019 , 12 : 361 - 367 .

JI J H , JO G , HA J G , et al . Recycled thermal energy from high power light emitting diode light source [J]. J. Nanosci. Nanotechnol. , 2018 , 18 ( 9 ): 6029 - 6032 .

QIU Y J , WANG L L , WANG H L , et al . Bipolar ripple cancellation method to achieve single-stage electrolytic-capacitor-less high-power LED driver [J]. IEEE J. Emerg. Sel. Top. Power Electron , 2015 , 3 ( 3 ): 698 - 713 .

YOKOGAWA T , OYA M , FUJIKANE M . A high power InGaN-LED on an m-plane GaN substrate [J]. Electron. Commun. Japan , 2015 , 98 ( 5 ): 15 - 22 .

LU X Y , HUA T C , WANG Y P , et al . Thermal analysis of high power LED package with heat pipe heat sink [J]. Microelectronics J. , 2011 , 42 ( 11 ): 1257 - 1262 .

HAMIDNIA M , LUO Y , WANG X D . Application of micro/nano technology for thermal management of high power LED packaging—a review [J]. Appl. Therm. Eng. , 2018 , 145 : 637 - 651 .

WANG B , LIN H , XU J , et al . CaMg2Al16O27∶Mn4+-based red phosphor∶a potential color converter for high-powered warm W-LED [J]. ACS Appl. Mater. Interfaces , 2014 , 6 ( 24 ): 22905 - 22913 .

PUST P , WEILER V , HECHT C , et al . Narrow-band red-emitting Sr[LiAl3N4]∶Eu2+ as a next-generation LED-phosphor material [J]. Nat. Mater. , 2014 , 13 ( 9 ): 891 - 896 .

BUCEVAC D , KRSTIC V . The effect of SiC addition on photoluminescence of YAG∶Ce phosphor for white LED [J]. J. Eur. Ceram. Soc. , 2018 , 38 ( 16 ): 5519 - 5524 .

CHEN J J , ZHAO Y , MAO Z Y , et al . CaAlSiN3∶Eu2+-based color-converting coating application for white LEDs∶reduction of blue-light harm and enhancement of CRI value [J]. Mater. Res. Bull. , 2017 , 90 : 212 - 217 .

HASEGAWA T . Design and fabrication of bismith-silicate photonic crystal fiber [J]. Opt. Commun. , 2012 , 285 ( 19 ): 3939 - 3944 .

FAUGAS B , HAWKINS T , KUCERA C , et al . Molten core fabrication of bismuth germanium oxide Bi4Ge3O12 crystalline core fibers [J]. J. Am. Ceram. Soc. , 2018 , 101 ( 9 ): 4340 - 4349 .

DU P , YU J S . Near-ultraviolet light induced visible emissions in Er3+-activated La2MoO6 nanoparticles for solid-state lighting and non-contact thermometry [J]. Chem. Eng. J. , 2017 , 327 : 109 - 119 .

CAO Y , HUANG F , LIN H , et al . A novel optical thermometry strategy based on diverse thermal response from two intervalence charge transfer states [J]. Adv. Funct. Mater. , 2016 , 26 ( 18 ): 3139 - 3145 .

TREJGIS K , BEDNARKIEWICZ A , MARCINIAK L . Engineering excited state absorption based nanothermometry for temperature sensing and imaging [J]. Nanoscale , 2020 , 12 ( 7 ): 4667 - 4675 .

YAO Q , HU P , SUN P , et al . YAG∶Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting [J]. Adv. Mater. , 2020 , 32 ( 19 ): 1907888 .

BOYER M , CARRION A J F , ORY S , et al . Transparent Polycrystalline SrREGa3O7 melilite ceramics∶potential phosphors for tuneable solid state lighting [J]. J. Mater. Chem. C , 2016 , 4 ( 15 ): 3238 - 3247 .

TANG F , LI H Q , TIAN K Z , et al . Luminescence characteristics and vibronic coupling behavior of a highly efficient Eu2+-activated RbLi7Si2O8 green phosphor for wide color gamut WLEDs [J]. ACS Appl. Electron. Mater. , 2020 , 2 ( 11 ): 3749 - 3755 .

TANG F , LI H Q , TIAN K Z , et al . Steady-state and time-resolved upconversion photoluminescence in Yb3+-Er3+ co-doped transparent ceramics of YAG [J]. Opt. Lett. , 2020 , 45 ( 20 ): 5712 - 5715 .

CERVANTES-LÓPEZ J L , RANGEL R , MENESES-RODRÍGUEZ D , et al . Ce,Eu incorporation through doping of ALD-ZnO thin films for enhancing their photoluminescent properties [J]. Nanotechnology , 2021 , 32 ( 14 ): 145601 .

LIN H , HU T , CHENG Y , et al . Glass ceramic phosphors∶towards long-lifetime high-power white light-emitting-diode applications—a review [J]. Laser Photon. Rev. , 2018 , 12 ( 6 ): 1700344-1-31 .

HUANG Y Q , BAI G X , ZHAO Y J , et al . Yb/Ho codoped layered perovskite bismuth titanate microcrystals with upconversion luminescence∶fabrication,characterization,and application in optical fiber ratiometric thermometry [J]. Inorg. Chem. , 2020 , 59 ( 19 ): 14229 - 14235 .

郑昌仁 , 徐敏 , 吴石山 , 等 . 丁二烯-苯乙烯嵌段共聚物溶液粘度的测定和研究 [J]. 高分子材料科学与工程 , 2001 , 17 ( 6 ): 78 - 82 .

ZHENG C R , XU M , WU S S , et al . Measurement and investigation on SBS block copolymer solution viscosity [J]. Polymer Mater. Sci. Eng. , 2001 , 17 ( 6 ): 78 - 82 . (in Chinese)

张军 , 吴石山 , 郑昌仁 , 等 . SBS浓溶液流动行为与粘度模型的研究 [J]. 高分子材料科学与工程 , 2002 , 18 ( 5 ): 163 - 166 .

ZHANG J , WU S S , ZHENG C R , et al . The study of flowing action and viscosity model of SBS concentrated solution [J]. Polymer Mater. Sci. Eng. , 2002 , 18 ( 5 ): 163 - 166 . (in Chinese)

TIAN Z H , DUAN L , WU L , et al . Rheological properties of glutaraldehyde-crosslinked collagen solutions analyzed quantitatively using mechanical models [J]. Mater. Sci. Eng. C,Mater. Biol. Appl. , 2016 , 63 : 10 - 17 .

ZHAO H , TANG F , XIE Y Z , et al . Fabrication and rheological behavior of tape-casting slurry for ultra-thin multilayer transparent ceramics [J]. Int. J. Appl. Ceram. Technol. , 2020 , 17 ( 3 ): 1255 - 1263 .

DU P , HUANG X Y , YU J S . Facile synthesis of bifunctional Eu3+-activated NaBiF4 red-emitting nanoparticles for simultaneous white light-emitting diodes and field emission displays [J]. Chem. Eng. J. , 2018 , 337 : 91 - 100 .

杨国辉 , 王小军 , 陈彩花 , 等 . 基于Eu3+还原制备Eu3+-Eu2+共存发光材料的研究进展 [J]. 发光学报 , 2017 , 38 ( 11 ): 1475 - 1485 .

YANG G H , WANG X J , CHEN C H , et al . Research progress in Eu3+-Eu2+ coexisting luminescent materials based on the reduction of Eu3+ [J]. Chin. J. Lumin. , 2017 , 38 ( 11 ): 1475 - 1485 . (in Chinese)

TANG F , SU Z C , LAO X Z , et al . The key roles of 4f-level splitting and vibronic coupling in the high-efficiency luminescence of Ce3+ ion in LuAG transparent ceramic phosphors [J]. J. Lumin. , 2020 , 225 : 117360 .

SU Z C , XU S J . A generalized model for time-resolved luminescence of localized carriers and applications∶dispersive thermodynamics of localized carriers [J]. Sci. Rep. , 2017 , 7 ( 1 ): 13-1-8 .

SHABLINSKII A P , POVOLOTSKII A V , DROZDOVA I A , et al . New luminescent BaBi2-xEuxB2O7 glassmaterials [J]. Glass Phys. Chem. , 2019 , 45 ( 1 ): 74 - 78 .

吕滨 , 程鹏 , 陈红兵 , 等 . Y/Gd/Eu三元稀土层状化合物的离子交换行为与光学性能 [J]. 稀有金属材料与工程 , 2019 , 48 ( 2 ): 559 - 565 .

LU B , CHENG P , CHEN H B , et al . Anion-exchange behavior and optical properties of ternary Y/Gd/Eu layered rare-earth hydroxides [J]. Rare Metal Mat. Eng. , 2019 , 48 ( 2 ): 559 - 565 . (in Chinese)

浏览量

574

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

一种提升LED光输出稳定性的有机-无机锰卤化物及其亮度优化

Er³⁺掺杂AlScN薄膜发光及铁电性能的协同调控

Sr₃AlO₄F∶Eu³⁺，Dy³⁺，Na⁺发光材料性能

光致发光气凝胶研究进展