金属有机框架材料在有机钙钛矿太阳能电池中的应用进展

何睿夫; 周非凡; 屈军乐; 宋军; 周炫

doi:10.37188/CJL.20210208

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金属有机框架材料在有机钙钛矿太阳能电池中的应用进展

材料合成及性能 | 更新时间：2021-11-23

- 金属有机框架材料在有机钙钛矿太阳能电池中的应用进展
  增强出版
- Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells
- 发光学报 2021年42卷第11期页码：1722-1738
- 作者机构：
  
  深圳大学　生物医学光子学研究中心/物理与光电工程学院，光电子器件与系统重点实验室，广东　深圳　518060
- 作者简介：
  
  [ "何睿夫(1998-)，男，安徽池州人，硕士研究生，2020年于长春理工大学获得学士学位，主要从事纳米光电子器件与材料应用的研究。E-mail: heruifu98@163.com" ]
  [ "周炫(1983-)，男，湖南永州人，博士，副研究员，2018年于中国香港浸会大学获得博士学位，主要从事新型光电功能材料及其在新能源与节能器件中应用的研究。E-mail: xzhou@aliyun.com" ]
- 基金信息：
  
  国家自然科学基金(61620106016;61835009;61775145);中国博士后科学基金(2019M653007);广东省重点领域研发计划(2019B110233004)
- DOI：10.37188/CJL.20210208
  中图分类号： O482.31
- 收稿日期：2021-06-23，
  
  修回日期：2021-07-15，
  
  纸质出版日期：2021-11-01
- 稿件说明：
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何睿夫, 周非凡, 屈军乐, 等. 金属有机框架材料在有机钙钛矿太阳能电池中的应用进展[J]. 发光学报, 2021,42(11):1722-1738.

Rui-fu HE, Fei-fan ZHOU, Jun-le QU, et al. Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells[J]. Chinese journal of luminescence, 2021, 42(11): 1722-1738.
何睿夫, 周非凡, 屈军乐, 等. 金属有机框架材料在有机钙钛矿太阳能电池中的应用进展[J]. 发光学报, 2021,42(11):1722-1738. DOI： 10.37188/CJL.20210208.

Rui-fu HE, Fei-fan ZHOU, Jun-le QU, et al. Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells[J]. Chinese journal of luminescence, 2021, 42(11): 1722-1738. DOI： 10.37188/CJL.20210208.

摘要

有机钙钛矿太阳能电池(OPSCs)的能量转换效率卓越，可以媲美单晶硅太阳能电池。但是，由于有机钙钛矿材料对水和空气十分敏感，因而当前面临着器件稳定性方面的挑战。金属有机框架(MOFs)与其衍生材料具有开放式孔道结构和非常大的比表面积，可以添加剂的形式用于电子、空穴传输层和混合钙钛矿-MOF光吸收层，或作为界面修饰层有效钝化钙钛矿吸收层的缺陷，并显著提升其能量转换效率及器件稳定性。本文介绍了MOFs的相关知识与MOFs结合OPSCs的研究现状，重点综述了近五年来MOFs在OPSCs中的应用与进展。

Abstract

Organic perovskite solar cells(OPSCs) have exhibited excellent power conversion efficiency

which is comparable to the monocrystalline silicon-based solar cells. But they still face the challenge of device stability due to the moisture and air sensitivities of organic perovskite materials. Metal-organic frameworks(MOFs) and their derivatives have open pore structure and large specific surface area. They can be used as additives in electron/hole transport layer

mixed perovskite MOF optical absorption layer

or as interface modification layer to effectively passivate the defects of perovskite absorption layer. In this way

the energy conversion efficiency and device stability of perovskite solar cells can be significantly improved. This paper introduces the related knowledge of MOFs and the research status of MOFs combined with OPSCs

focusing on the application and progress of MOFs in OPSCs in recent five years.

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references

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