植物生长LED用Sr2MgAl22O36∶Mn4+荧光玻璃的制备与发光性质

杨茂林; 郑俊丽; 余丽萍; 廉世勋; 周文理

doi:10.37188/CJL.20210022

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植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质

发光学应用及交叉前沿 | 更新时间：2021-05-20

- 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质
- Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED
- 发光学报 2021年42卷第5期页码：717-723
- 作者机构：
  
  湖南师范大学　化学化工学院，湖南　长沙　 410081
- 作者简介：
  
  [ "杨茂林(1995-)，女，重庆人，硕士研究生,2018年于重庆科技学院获得学士学位，主要从事荧光粉及荧光玻璃的研究。E-mail: 695256997@qq.com" ]
  [ "周文理(1982-)，男，湖南邵东人，博士，副教授,2012年于中山大学获得博士学位，主要从事照明与显示用无机发光材料的研究。E-mail: chemwlzhou@hunnu.edu.cn" ]
- 基金信息：
  
  国家重点研发计划(2016YFB0302403);国家自然科学基金(21501058)
- DOI：10.37188/CJL.20210022
  中图分类号： O482.31
- 收稿：2021-01-12，
  
  修回：2021-01-20，
  
  纸质出版：2021-05-01
- 稿件说明：
移动端阅览
杨茂林, 郑俊丽, 余丽萍, 等. 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质[J]. 发光学报, 2021,42(5):717-723.

Mao-lin YANG, Jun-li ZHENG, Li-ping YU, et al. Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED[J]. Chinese Journal of Luminescence, 2021, 42(5): 717-723.
杨茂林, 郑俊丽, 余丽萍, 等. 植物生长LED用Sr₂MgAl₂₂O₃₆∶Mn⁴⁺荧光玻璃的制备与发光性质[J]. 发光学报, 2021,42(5):717-723. DOI： 10.37188/CJL.20210022.

Mao-lin YANG, Jun-li ZHENG, Li-ping YU, et al. Preparation and Luminescent Properties of Sr₂MgAl₂₂O₃₆∶Mn⁴⁺ Phosphor-in-glass for Plant Growth LED[J]. Chinese Journal of Luminescence, 2021, 42(5): 717-723. DOI： 10.37188/CJL.20210022.

摘要

采用两步烧结法低温制备了Sr

MgAl

∶Mn

-(SiO

-Al

-ZnO-BaO)荧光玻璃(SMA∶Mn

-PiG)。通过X射线衍射、扫描电镜、光致激发和发射光谱、荧光衰减曲线等手段对其物相、成分与发光性能进行了研究。实验结果表明，形成PiG后

SMA∶Mn

荧光粉的物相和元素组成保持不变。不同SAM∶Mn

含量的PiG样品在328 nm光激发下，在661 nm处均显示强的发射带，归属于荧光粉中Mn

的

E→

跃迁，发光光谱与植物光敏色素的红区吸收光谱匹配良好。随着荧光粉含量的增加

SAM∶Mn

-PiG的发光强度逐渐增大。15%SMA∶Mn

-PiG样品的内、外量子效率分别为26%和20%，低于SMA∶Mn

荧光粉的59%和40%。相比于SMA∶Mn

荧光粉，荧光玻璃的吸收效率和热稳定性略有提高。通过与高功率紫外芯片封装

SMA∶Mn

-PiG红光LED器件在100 mA驱动电流下展现了最高的电致发光强度。

Abstract

MgAl

∶Mn

-(SiO

-Al

-ZnO-BaO-B

) phosphor in glass(SMA∶Mn

-PiG) was prepared by a two-step co-sintering technology at low temperature. The phase

composition and luminescent properties of PiG samples were investigated by X-ray diffraction(XRD)

scanning electron microscope(SEM)

excitation and photoluminescence spectra

fluorescence decay curve

etc

. Experimental results show that the phase and elemental composition of SMA∶Mn

phosphor were well preserved after forming PiG. Under 328 nm excitation

PiG samples with different SAM∶Mn

content all showed strong emission band peaked at 661 nm due to

E→

transition of Mn

ions. The emission spectrum of SMA∶Mn

-PiG well matches absorption spectra of plant phytochromes. With the increase of phosphor content

the photoluminescence intensity of SAM∶Mn

-PiG gradually increases. Internal quantum efficiency(IQE) and external quantum efficiency(EQE) of 15% SMA∶Mn

-PiG samples are 26% and 20%

respectively

which are lower than 59% and 40% of SMA∶Mn

phosphor. Compared with SMA∶Mn

phosphor

absorption efficiency and thermal stability of SAM∶Mn

-PiG are slightly enhanced. With packaging with high-power UV chip

SMA∶Mn

-PiG red LED device exhibits high electroluminescence intensity

and the highest value is measured at 100 mA.

关键词

Keywords

references

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