钆铝石榴石(GdAG)基发光材料研究进展

薛秉国; 吕清洋; 王婷婷; 刘丽娜; 王世立; 朱海澄; 刘绍宏; 孙旭东

doi:10.37188/CJL.20200237

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钆铝石榴石(GdAG)基发光材料研究进展

特邀报告 | 更新时间：2020-12-10

- 钆铝石榴石(GdAG)基发光材料研究进展
- Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials
- 发光学报 2020年41卷第12期页码：1538-1553
- 作者机构：
  
  东北大学材料科学与工程学院, 辽宁沈阳 110819
- 作者简介：
  
  [ "薛秉国(1996-), 男, 湖南株洲人, 硕士研究生, 2018年于江苏科技大学获得学士学位, 主要从事闪烁薄膜的研究。E-mail:1800558@stu.neu.edu.cn" ]
  [ "刘绍宏(1981-), 男, 湖北十堰人, 博士, 副教授, 2010年于东北大学获得博士学位, 主要从事光功能材料的研究。E-mail:liush@smm.neu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51977027);教育部基本科研业务费项目(N182508026)
- DOI：10.37188/CJL.20200237
  中图分类号： O482.31
- 收稿：2020-08-05，
  
  录用：2020-8-31，
  
  纸质出版：2020-12
- 稿件说明：
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薛秉国, 吕清洋, 王婷婷, 等. 钆铝石榴石(GdAG)基发光材料研究进展[J]. 发光学报, 2020,41(12):1538-1553.

Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese Journal of Luminescence, 2020, 41(12): 1538-1553.
薛秉国, 吕清洋, 王婷婷, 等. 钆铝石榴石(GdAG)基发光材料研究进展[J]. 发光学报, 2020,41(12):1538-1553. DOI： 10.37188/CJL.20200237.

Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese Journal of Luminescence, 2020, 41(12): 1538-1553. DOI： 10.37188/CJL.20200237.

摘要

钆铝石榴石（Gd

，GdAG）是性能优异的发光基质材料，但其在高温煅烧时易发生分解，导致得到纯相GdAG基发光材料比较困难。近年来，研究证实通过小半径

（

=Y，Lu，Tb）取代部分Gd

，或通过离子半径更大的

来取代Al的位置扩大十二面体间隙，可以稳定GdAG晶格，得到纯相GdAG基发光材料。本文综述了GdAG基发光材料在晶格稳定化、下转换发光、上转换发光等方面的研究进展，并探讨了GdAG基单晶、薄膜和陶瓷的制备、性能及其在射线探测和医学成像等领域的应用前景。

Abstract

Gadolinium aluminum garnet(Gd

GdAG) is an excellent luminescent host material. But GdAG is easy to decompose during high temperature calcination

which makes it difficult to obtain a pure phase GdAG-based luminescent material. In recent years

research has confirmed that substituting the smaller radius

(

Tb) for part of Gd

or replacing the Al

with the larger radius

to expand the dodecahedral gap

can stabilize the GdAG lattice and thus obtain a pure phase GdAG-based luminescent material. This article reviews the research progress of GdAG-based luminescent materials including the lattice stabilization

down-conversion luminescence

and up-conversion luminescence

and also discusses the preparation and performances of GdAG-based single crystals

thin films and ceramics

and their applications in radiological detection and medical imaging.

关键词

Keywords

references

陈积阳, 施鹰, 冯涛, 等.闪烁陶瓷及其在医学X-CT上的应用[J].硅酸盐学报, 2004, 32(7):868-872.

CHEN J Y, SHI Y, FENG T, et al .. Scintillation ceramics and their application on medical X-CT[J]. J. Chin. Ceram. Soc ., 2004, 32(7):868-872. (in Chinese)

FENG X Q. Anti-site defects in YAG and LuAG crystals[J]. J. Inorg. Mater ., 2010, 25(8):785-794.

GEUSIC J E, MARCOS H M, VAN UITERT L G. Laser oscillations in Nd-doped yttrium aluminum, yttrium gallium and gadolinium garnets[J]. Appl. Phys. Lett ., 1964, 4(10):182-184.

汪超, 任国浩.石榴石系列闪烁晶体的研究进展[J].硅酸盐学报, 2015, 43(7):882-891.

WANG C, REN G H. Recent studies on garnet scintillation crystals[J]. J. Chin. Ceram. Soc ., 2015, 43(7):882-891. (in Chinese)

李会利, 刘学建, 黄莉萍.固相反应法制备Ce:LuAG透明陶瓷[J].无机材料学报, 2006, 21(5):1161-1166.

LI H L, LIU X J, HUANG L P. Fabrication of transparent Ce:LuAG ceramics by a solid-state reaction method[J]. J. Inorg. Mater ., 2006, 21(5):1161-1166. (in Chinese)

BLASSE G, BRIL A. Investigation of some Ce 3+ -activated phosphors[J]. J. Chem. Phys ., 1967, 47(12):5139-5145.

BOUKERIKA A, GUERBOUS L, CHELEF H, et al .. Preparation and characterization of bright high quality YAG:Eu 3+ thin films grown by sol-gel dip-coating technique[J]. Thin Solid Films , 2019, 683:74-81.

LI J G, LI X D, SUN X D, et al .. Monodispersed colloidal spheres for uniform Y 2 O 3 :Eu 3+ red-phosphor particles and greatly enhanced luminescence by simultaneous Gd 3+ doping[J]. J. Phys. Chem. C, 2008, 112(31):11707-11716.

LI J G, LI X D, SUN X D, et al .. Uniform colloidal spheres for (Y 1- x Gd x ) 2 O 3 ( x =0-1):formation mechanism, compositional impacts, and physicochemical properties of the oxides[J]. Chem. Mat ., 2008, 20(6):2274-2281.

LI Y H, HONG G Y. Synthesis and luminescence properties of nanocrystalline Gd 2 O 3 :Eu 3+ by combustion process[J]. J. Lumin ., 2007, 124(2):297-301.

DENG Y, FOWLKES J D, FITZ-GERALD J M, et al .. Combinatorial thin film synthesis of Gd-doped Y 3 Al 5 O 12 ultraviolet emitting materials[J]. Appl. Phys . A, 2005, 80(4):787-789.

DENG Y, FOWLKES J D, RACK P D, et al .. Thin film RF magnetron sputtering of gadolinium-doped yttrium aluminum garnet ultraviolet emitting materials[J]. Opt. Mater ., 2006, 29(2-3):183-191.

NISHIURA S, TANABE S, FUJIOKA K, et al .. Preparation of transparent Ce 3+ :GdYAG ceramics phosphors for white LED[J]. IOP Conf. Ser.:Mater. Sci. Eng ., 2011, 18:102005.

KUČERA M, NIKL M, HANUŠ M, et al .. Gd 3+ to Ce 3+ energy transfer in multi-component GdLuAG and GdYAG garnet scintillators[J]. Phys. Status Solidi R. Res. Lett ., 2013, 7(8):571-574.

MIZUNO M, YAMADA T, NOGUCHI T. Phase diagrams of the systems Al 2 O 3 -Eu 2 O 3 and Al 2 O 3 -Gd 2 O 3 at high temperatures[J]. Yogyo-Kyokai-Shi , 1977, 85(11):543-548.

MIZUNO M, YAMADA T. Phase diagram of the system Ga 2 O 3 -Sm 2 O 3 at high temperatures[J]. J. Ceram. Soc. Jpn. , 1989, 97(1131):1334-1338.

MIZUNO M, YAMADA T, NOGUCHI T. Phase diagram of the system Al 2 O 3 -Dy 2 O 3 at high temperatures[J]. J. Ceram. Soc. Jpn. , 1979, 86(8):360-364.

SHISHIDO T, OKAMURA K, YAJIMA S. Gd 3 Al 5 O 12 phase obtained by crystallization of amorphous Gd 2 O 3 ·5/3Al 2 O 3 [J]. J. Am. Ceram. Soc ., 1978, 61(7-8):373-375.

LI J K, LI J G, ZHANG Z J, et al .. Gadolinium aluminate garnet (Gd 3 Al 5 O 12 ):crystal structure stabilization via lutetium doping and properties of the (Gd 1- x Lu x ) 3 Al 5 O 12 solid solutions ( x =0-0.5)[J]. J. Am. Ceram. Soc ., 2012, 95(3):931-936.

CHAUDHURY S, PARIDA S C, PILLAI K, et al .. High-temperature X-ray diffraction and specific heat studies on GdAlO 3 , Gd 3 Al 5 O 12 and Gd 4 Al 2 O 9 [J]. J. Solid State Chem ., 2007, 180(8):2393-2399.

XIA Z G, MEIJERINK A. Ce 3+ -doped garnet phosphors:composition modification, luminescence properties and applications[J]. Chem. Soc. Rev ., 2017, 46(1):275-299.

WANG W Z, LI J K, TENG X, et al .. Luminescence properties of Y 3+ stabilized Gd 3 Al 5 O 12 :Tb 3+ /Ce 3+ phosphors with yellow light-emitting for warm white LEDs[J]. J. Lumin ., 2018, 202:176-185.

NAZAROV M, NOH D Y, SOHN J, et al .. Influence of additional Eu 3+ coactivator on the luminescence properties of Tb 3 Al 5 O 12 :Ce 3+ , Eu 3+ [J]. Opt. Mater ., 2008, 30(9):1387-1392.

ZORENKO Y, GORBENKO V, VOZNYAK T, et al .. Luminescence and Tb 3+ -Ce 3+ -Eu 3+ ion energy transfer in single-crystalline films of Tb 3 Al 5 O 12 :Ce, Eu garnet[J]. J. Lumin ., 2008, 128(4):652-660.

LI J K, LI J G, WU X L, et al .. Crystal structure stabilization of gadolinium aluminum garnet (Gd 3 Al 5 O 12 ) and photoluminescence properties[J]. Key Eng. Mater ., 2013, 544:245-251.

CHIANG C C, TSAI M S, HON M H. Preparation of cerium-activated GAG phosphor powders influence of co-doping on crystallinity and luminescent properties[J]. J. Electrochem. Soc ., 2007, 154(10):J326-J329.

苑航, 陈宇潇, 王英杰, 等.无机闪烁体钆镓铝石榴石(GAGG)的性能研究及应用[J].现代工业经济和信息化, 2018, 8(11):24-26.

YUAN H, CHEN Y X, WANG Y J, et al .. Inorganic scintillator gadolinium gallium aluminum garnet(GAGG)'s performance research and application[J]. Mod. Ind. Econ. Inform ., 2018, 8(11):24-26. (in Chinese)

OGIEGłO J M, KATELNIKOVAS A, ZYCH A, et al .. Luminescence and luminescence quenching in Gd 3 (Ga, Al) 5 O 12 scintillators doped with Ce 3+ [J]. J. Phys. Chem. A, 2013, 117(12):2479-2484.

CAO Q, HE L N, FENG X J, et al .. Effect of annealing on the structural and optical properties of β -Ga 2 O 3 films prepared on gadolinium gallium garnet (110) by MOCVD[J]. Ceram. Int ., 2018, 44(1):830-835.

PIAO R Q, XU Q, ZHANG Z B, et al .. A study on ratiometric thermometry based on upconversion emissions of erbium ions in gadolinium gallium garnet single-crystal[J]. J. Lumin ., 2018, 204:116-121.

RONDA C. Luminescent materials with quantum efficiency larger than 1, status and prospects[J]. J. Lumin ., 2002, 100(1-4):301-305.

LI J G, SAKKA Y. Recent progress in advanced optical materials based on gadolinium aluminate garnet (Gd 3 Al 5 O 12 )[J]. Sci. Technol. Adv. Mater ., 2015, 16(1):014902-1-18.

DORENBOS P. The 5d level positions of the trivalent lanthanides in inorganic compounds[J]. J. Lumin ., 2000, 91(3-4):155-176.

WU J L, GUNDIAH G, CHEETHAM A K. Structure-property correlations in Ce-doped garnet phosphors for use in solid state lighting[J]. Chem. Phys. Lett ., 2007, 441(4-6):250-254.

DOTSENKO V P, BEREZOVSKAYA I V, VOLOSHINOVSKII A S, et al .. Luminescence properties and electronic structure of Ce 3+ -doped gadolinium aluminum garnet[J]. Mater. Res. Bull ., 2015, 64:151-155.

BACHMANN V M. Studies on Luminescence and Quenching Mechanisms in Phosphors for Light Emitting Diodes [D]. Netherlands: Utrecht University, 2007.

JOSHI C, YADAV P, MOHARIL S V. Improved white light emitting diode characteristics by coating GdAG:Ce phosphor[J]. Trans. Electr. Electron. Mater , 2014, 15(2):69-72.

LI J K, LI J G, LIU S H, et al .. The development of Ce 3+ -activated (Gd, Lu) 3 Al 5 O 12 garnet solid solutions as efficient yellow-emitting phosphors[J]. Sci. Technol. Adv. Mater ., 2013, 14(5):054201-1-9.

JAIN A, KOYANI R, MUñOZ C, et al .. Blue light triggered generation of reactive oxygen species from silica coated Gd 3 Al 5 O 12 :Ce 3+ nanoparticles loaded with rose Bengal[J]. Data Brief , 2018, 20:1023-1028.

JAIN A, KOYANI R, MUÑOZ C, et al .. Magnetic-luminescent cerium-doped gadolinium aluminum garnet nanoparticles for simultaneous imaging and photodynamic therapy of cancer cells[J]. J. Colloid Interface Sci ., 2018, 526:220-229.

CASTILLO R R, VALLET-REGÍ M. Functional mesoporous silica nanocomposites:biomedical applications and biosafety[J]. Int. J. Mol. Sci ., 2019, 20(4):929-1-30.

DENG Z H, CHEN J, LIU Z G, et al .. Structure, chemical state and luminescent properties of Ce, Gd:YAG transparent ceramic for flip-chip white LED application[J]. Chin. J. Struct. Chem ., 2018, 37(6):948-954.

LI M J, WU Y C, YEN F S, et al .. Influence of ionic mobility on the phase transformation route in Y 3 Al 5 O 12 (YAG) stoichiometry[J]. J. Eur. Ceram. Soc ., 2011, 31(12):2099-2106.

XIAO W G, LIU X F, ZHANG J H, et al .. Realizing visible light excitation of Tb 3+ via highly efficient energy transfer from Ce 3+ for LED-based applications[J]. Adv. Opt. Mater ., 2019, 7(9):1801677.

HERNÁNDEZ-ADAME L, MÉNDEZ-BLAS A, RUIZ-GARCÍA J, et al .. Synthesis, characterization, and photoluminescence properties of Gd:Tb oxysulfide colloidal particles[J]. Chem. Eng. J ., 2014, 258:136-145.

TENG X, LI J K, DUAN G B, et al .. Development of Tb 3+ activated gadolinium aluminate garnet (Gd 3 Al 5 O 12 ) as highly efficient green-emitting phosphors[J]. J. Lumin ., 2016, 179:165-170.

GUO K, HUANG M L, CHEN H H, et al .. Comparative study on photoluminescence of amorphous and nano-crystalline YAG:Tb phosphors prepared by a combustion method[J]. J. Non-Cryst. Solids , 2012, 358(1):88-92.

PARK J Y, JUNG H C, RAJU G S R, et al .. Solvothermal synthesis and luminescence properties of Tb 3+ -doped gadolinium aluminum garnet[J]. J. Lumin ., 2010, 130(3):478-482.

Hertle E, Chepyga L, Batentschuk M, et al .. Influence of codoping on the luminescence properties of YAG:Dy for high temperature phosphor thermometry[J]. J. Lumin ., 2017, 182:200-207.

ISHIWADA N, FUJII E, YOKOMORI T. Evaluation of Dy-doped phosphors (YAG:Dy, Al 2 O 3 :Dy, and Y 2 SiO 5 :Dy) as thermographic phosphors[J]. J. Lumin ., 2018, 196:492-497.

HASHEMI A, VETTER A, JOVICIC G, et al .. Temperature measurements using YAG:Dy and YAG:Sm under diode laser excitation (405 nm)[J]. Meas. Sci. Technol ., 2015, 26(7):075202.

LI J K, LI J G, LIU S H, et al .. Greatly enhanced Dy 3+ emission via efficient energy transfer in gadolinium aluminate garnet (Gd 3 Al 5 O 12 ) stabilized with Lu 3+ [J]. J. Mater. Chem. C, 2013, 1(45):7614-7622.

HERTLE E E, CHEPYGA L, OSVET A, et al .. (Gd, Lu)AlO 3 :Dy 3+ and (Gd, Lu) 3 Al 5 O 12 :Dy 3+ as high-temperature thermographic phosphors[J]. Meas. Sci. Technol ., 2019, 30(3):034001.

RYBA-ROMANOWSKI W, KOMAR J, NIEDŹWIEDZKI T, et al .. Excited state relaxation dynamics and up-conversion phenomena in Gd 3 (Al, Ga) 5 O 12 single crystals co-doped with holmium and ytterbium[J]. J. Lumin ., 2016, 656:573-580.

NIEDŹWIEDZKI T, RYBA-ROMANOWSKI W, KOMAR J, et al .. Excited state relaxation dynamics and up-conversion phenomena in Gd 3 (Al, Ga) 5 O 12 single crystals co-doped with erbium and ytterbium[J]. J. Lumin ., 2016, 177:219-227.

KOMAR J, SOLARZ P, JEOWSKI A, et al .. Investigation of intrinsic and extrinsic defects in solid solution Gd 3 (Al, Ga) 5 O 12 crystals grown by the Czochralski method[J]. J. Alloys Compd ., 2016, 688:96-103.

LI J K, LI J G, LI J, et al .. Photoluminescent properties of new up-conversion phosphors of Yb/Tm co-doped (Gd 1- x -Lu x ) 3 Al 5 O 12 ( x =0.1-0.5) garnet solid solutions[J]. J. Alloys Compd ., 2014, 582:623-627.

BOHACEK P, KRASNIKOV A, KUČERA M, et al .. Defects creation in the undoped Gd 3 (Ga, Al) 5 O 12 single crystals and Ce 3+ -doped Gd 3 (Ga, Al) 5 O 12 single crystals and epitaxial films under irradiation in the Gd 3+ -related absorption bands[J]. Opt. Mater ., 2019, 88:601-605.

KAMADA K, YANAGIDA T, PEJCHAL J, et al .. Scintillator-oriented combinatorial search in Ce-doped (Y, Gd) 3 (Ga, Al) 5 O 12 multicomponent garnet compounds[J]. J. Phys. D -Appl. Phys ., 2011, 44(50):505104.

FERRI A, GOLA A, SERRA N, et al .. Performance of FBK high-density SiPM technology coupled to Ce:LYSO and Ce:GAGG for TOF-PET[J]. Phys. Med. Biol ., 2014, 59(4):869-880.

KAMADA K, YANAGIDA T, PEJCHAL J, et al .. Crystal growth and scintillation properties of Ce doped Gd 3 (Ga, Al) 5 O 12 single crystals[J]. IEEE Trans. Nucl. Sci ., 2012, 59(5):2112-2115.

KUROSAWA S, SHOJI Y, YOKOTA Y, et al .. Czochralski growth of Gd 3 (Al 5- x Ga x )O 12 (GAGG) single crystals and their scintillation properties[J]. J. Cryst. Growth , 2014, 393:134-137.

ZORENKO Y, GORBENKO V, ZORENKO T, et al .. High-perfomance Ce-doped multicomponent garnet single crystalline film scintillators[J]. Phys. Status Solidi R. Res. Lett ., 2015, 9(8):489-493.

ZORENKO Y, GORBENKO V, VASYLKIV J, et al .. Growth and luminescent properties of scintillators based on the single crystalline films of Lu 3- x Gd x Al 5 O 12 :Ce garnet[J]. Mater. Res. Bull ., 2015, 64:355-363.

BOK J, LALINSKY' O, HANUŠ M, et al .. GAGG:Ce single crystalline films:new perspective scintillators for electron detection in SEM[J]. Ultramicroscopy , 2016, 163:1-5.

LI J, SAHI S, GROZA M, et al .. Optical and scintillation properties of Ce 3+ -doped LuAG and YAG transparent ceramics:a comparative study[J]. J. Am. Ceram. Soc ., 2017, 100(1):150-156.

CHEN X Q, QIN H M, ZHANG Y, et al .. Highly transparent ZrO 2 -doped (Ce, Gd) 3 Al 3 Ga 2 O 12 ceramics prepared via oxygen sintering[J]. J. Eur. Ceram. Soc ., 2015, 35(14):3879-3883.

XU J, UEDA J, TANABE S. Design of deep-red persistent phosphors of Gd 3 Al 5- x Ga x O 12 :Cr 3+ transparent ceramics sensitized by Eu 3+ as an electron trap using conduction band engineering[J]. Opt. Mater. Express , 2015, 5(5):963-968.

YANAGIDA T, KAMADA K, FUJIMOTO Y, et al .. Comparative study of ceramic and single crystal Ce:GAGG scintillator[J]. Opt. Mater ., 2013, 35(12):2480-2485.

OMIDVARI N, SHARMA R, GANKA T R, et al .. Characterization of 1.2×1.2 mm 2 silicon photomultipliers with Ce:LYSO, Ce:GAGG, and Pr:LuAG scintillation crystals as detector modules for positron emission tomography[J]. J. Instrum ., 2017, 12(4):P04012.

LIU S, SUN P, LIU Y F, et al .. Warm white light with a high color-rendering index from a single Gd 3 Al 4 GaO 12 :Ce 3+ transparent ceramic for high-power LEDs and LDs[J]. ACS Appl. Mater. Interfaces , 2019, 11(2):2130-2139.

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