YxAl5O12:Ce3+荧光粉的微结构及其发光特性

赵聪; 马明星; 韩涛; 曹仕秀; 雷宇; 朱达川

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Y_xAl₅O₁₂:Ce³⁺荧光粉的微结构及其发光特性

材料合成及性能研究 | 更新时间：2020-08-12

- Y_xAl₅O₁₂:Ce³⁺荧光粉的微结构及其发光特性
- Microstructure and Luminescence Characteristics of Y_xAl₅O₁₂:Ce³⁺ Phosphor
- 发光学报 2011年32卷第9期页码：874-879
- 作者机构：
  
  1. 四川大学材料科学与工程学院, 四川成都 610065
  2. 重庆文理学院材料交叉学科研究中心, 重庆市高校微纳米材料工程与技术重点实验室重庆,402168
- 作者简介：
- 基金信息：
  
  重庆市科学技术基金(CSTC, 2009AB4171)();重庆市高校新材料开发及应用研究创新团队(201042)资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2011-05-20，
  
  修回日期：2011-06-22，
  
  网络出版日期：2011-09-22，
  
  纸质出版日期：2011-09-22
- 稿件说明：
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赵聪, 马明星, 韩涛, 曹仕秀, 雷宇, 朱达川. YxAl5O12:Ce3+荧光粉的微结构及其发光特性[J]. 发光学报, 2011,32(9): 874-879

ZHAO Cong, MA Ming-xing, Han Tao, CAO Shi-xiu, Lei Yu, ZHU Da-chuan. Microstructure and Luminescence Characteristics of YxAl5O12:Ce3+ Phosphor[J]. Chinese Journal of Luminescence, 2011,32(9): 874-879
赵聪, 马明星, 韩涛, 曹仕秀, 雷宇, 朱达川. YxAl5O12:Ce3+荧光粉的微结构及其发光特性[J]. 发光学报, 2011,32(9): 874-879 DOI：

ZHAO Cong, MA Ming-xing, Han Tao, CAO Shi-xiu, Lei Yu, ZHU Da-chuan. Microstructure and Luminescence Characteristics of YxAl5O12:Ce3+ Phosphor[J]. Chinese Journal of Luminescence, 2011,32(9): 874-879 DOI：

摘要

采用共沉淀法合成Y

:Ce

系列荧光粉

用多晶X 射线衍射、SEM及荧光光谱对Y

:Ce

系列荧光粉的晶体结构、形貌及发光性能进行表征。结果表明:随着

从2.64递增到3.06

波长先缓慢红移

然后迅速蓝移;发光强度先增强

然后迅速减弱;当

=2.88时

出现了最大发射峰值波长(

=537 nm)和最高相对发光强度。当

＜2.64时

出现Al

杂相;

＞3.06时

粉体中出现YAM杂相。

在2.76~2.88区间时

材料结晶度高

容易分散。

Abstract

:Ce

phosphors have been synthesized by co-precipitation method. The crystalline structure

morphology and luminescence properties of Y

:Ce

phosphors have been investigated by X-ray diffraction (XRD)

Scanning Electron Microscope (SEM) and fluorescence spectrophotometer. The results show that the emission wavelengths of as-prepared phosphors display red-shift at first and then blue-shift appears with the molar of Y

increasing from 2.64 to 3.06. The emission intensity increases slowly with the mole of Y

increasing from 2.64 to 2.88

but the intensity decreases sharply with different Y

content when it was beyond 2.94. The maximum emission wavelength (

=537 nm) at the maximum intensity appears when

is 2.88. The impure phase-Al

appears when the content of Y

is below 2.64. When the mole of Y

exceeds 3.06

the impure phase-YAM appears

which has negative effects on the luminescence property of as-prepared phosphors. When the molar ratio of yttrium rises from 2.76 to 2.88

the powder is observed with high crystalline and easy dispersion.

关键词

Keywords

references

Chen Du, Chen Chao. Enhancement of red emission on YAG:Ce3+ phosphors for white LED [J]. J. Xiamen University (厦门大学学报), 2007, 46 (5):669-673 (in Chinese).[2] Sun Xiaoyuan, Zhang Jiahua, Zhang Xia, et al. A Single white phosphor suitable for near ultraviolet excitation applied to new generation white LED lighting [J]. Chin. J. Lumin. (发光学报), 2005, 26 (3):404-407 (in Chinese).[3] Zhang Kai. A study on the co-precipitation preparation and luminescence behavior of Ce-doped yttrium aluminum garnet phosphor . Shanghai: The Degree of Philosophical Doctor of Shanghai Jiao Tong University, 2008 (in Chinese).[4] Jiang Jifeng, Zhou Shaohua, Zhang Pengyue, et al. Synthesis of YAG:Ce3+ powders by the co-precipitation method [J]. Rare Metal Mater. Engin. (稀有金属材料与工程), 2008, 5 (S2):426-429 (in Chinese).[5] Zhang Ruixi, Wang Haibo, Lin Haifeng, et al. The dependence of LED emissive intensity on YAG:Ce3+ phosphor partickes sizes [J]. Chin. J. Lumin. (发光学报), 2009, 30 (6):782-７８６ (in Chinese).[6] Yanagitani T, Ygji H, Hiro Y. Production of yttrium aluminum garnet fine powder: Japan,10101333 . 1998-04-21.[7] Li Jiguang, Ikegami T, Lee Jongheun. Low-temperature fabrication of transparent yttrium aluminum garnet (YAG) ceramics without additives [J]. J. Am. Ceram. Soc., 2000, 83 (4):961-963.[8] Chen Jiyang, Shi Ying, Shi Jianlin, et al. Praperation and luminescence property of (Y,Gd)2O3:Eu nanopowder by complex precipitation [J]. J. Inorg. Mater. (无机材料学报), 2004, 19 (6):1260-1266 (in Chinese).[9] Yao Guangqing, Duan Jiefei, Ren Min, et al. Preparation and luminescence of blue light conversion material YAG:Ce [J]. Chin. J. Lumin. (发光学报), 2001, 22 (s):21-23 (in Chinese).[10] Li Panlai, Yang Zhiping, Wang Ying, et al. Luminescent characteristics of LiM(M=Ca, Sr, Ba)BO3:DY3+ phosphor [J]. Chin. J. Lumin. (发光学报), 2009, 30 (5):606-609 (in Chinese).[11] Batentschuk M, Osvet A, Schierning G, et al. Simultaneous excitation of Ce3+ and Eu3+ ions in Tb3Al5O12 [J]. Radiat. Meas., 2004, 38 (4):539-543.[12] Matsubaraa I, Paranthamana M, Allisonb S W, et al. Preparation of Cr-doped Y3Al5O12 phosphors by heterogeneous precipitation methods and their luminescent properties [J]. Mater. Res. Bull., 2000, 35 (1):217-224.[13] Hyun Kyoung Yang, Jung Hyun Jeong. Synthesis, crystal growth, and photoluminescence properties of YAG: Eu3+ phosphors by high-energy ball milling and solid-state reaction [J]. J. Phys. Chem., 2009, 114 (1):226-230.[14] Wang Lei, Zhang Xia, Hao Zhendong, et al. Energy transfering Y3Al5O12:Ce3+, Cr3+ and Y3Al5O12:Ce3+, Cr3+, Pr3+ phosphors [J]. Chin. J. Lumin. (发光学报), 2011, 32 (5):417-422 (in Chinese).[15] Feng Xiqi. Anti-site defects in YAG and LuAG crystals [J]. J. Inorg. Mater. (无机材料学报), 2010, 25 (8):785-794 (in Chinese).[16] Sang Ho Lee, Dae Soo Jung, Jin Man Han, et al. Fine-sized Y3Al5O12:Ce3+ phosphor powders prepared by spray pyrolysis from the spray solution with barium fluoride flux [J]. J. Alloys Compds., 2009, 477 (1-2):776-779.[17] Huang Kun. Lattice ralaxation and theory of multphonon transitions [J]. Progr. Phys. (物理学进展), 1981, 1 (1):31-85 (in Chinese).[18] Zhang Kai, Liu Hezhou, Wu Yating, et al. Temperature dependence of luminecscence and decay time of YAG:Ce nanophosphr [J]. J. Inorg. Mater. (无机材料学报), 2008, 23 (5):1045-1048 (in Chinese).[19] Pana Y X, Wanga W, Liua G K, et al. Correlation between structure variation and luminescence red shift in YAG:Ce [J]. J. Alloys Compds., 2009, 488 (2):638-642.

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