Y2O2S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性

姬同坤; 姜洪义

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Y₂O₂S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性

材料合成及性能研究 | 更新时间：2020-08-12

- Y₂O₂S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性
- Thermal Stability of Red Afterglow Phosphor Y₂O₂S ∶ Eu,Mg,Ti,Gd
- 发光学报 2011年32卷第2期页码：122-126
- 作者机构：
  
  武汉理工大学材料科学与工程学院,湖北武汉,430070
- 作者简介：
- 基金信息：
  
  中央高校基本科研业务专项基金(2010-ZY-CL-021)资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2010-06-04，
  
  修回日期：2010-09-11，
  
  网络出版日期：2011-02-22，
  
  纸质出版日期：2011-02-22
- 稿件说明：
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姬同坤, 姜洪义. Y2O2S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性[J]. 发光学报, 2011,32(2): 122-126

JI Tong-kun, JIANG Hong-yi. Thermal Stability of Red Afterglow Phosphor Y2O2S ∶ Eu,Mg,Ti,Gd[J]. Chinese Journal of Luminescence, 2011,32(2): 122-126
姬同坤, 姜洪义. Y2O2S∶Eu, Mg, Ti, Gd 红色长余辉发光材料的热稳定性[J]. 发光学报, 2011,32(2): 122-126 DOI：

JI Tong-kun, JIANG Hong-yi. Thermal Stability of Red Afterglow Phosphor Y2O2S ∶ Eu,Mg,Ti,Gd[J]. Chinese Journal of Luminescence, 2011,32(2): 122-126 DOI：

摘要

采用高温固相法制备了Y

S ∶ Eu

Gd红色长余辉材料

研究了热处理工艺对材料稳定性的影响。用X射线衍射表征该材料的相组成

用激发光谱、发射光谱、余辉亮度对材料的发光性能进行表征。结果表明:热处理温度在600 ℃以下时

材料的发光性能不变;当热处理温度达到800 ℃时

发光性能缓慢下降;当热处理温度达到1 000 ℃时

主晶相Y

S变成Y

和Y

发光性能急剧下降。与铝酸盐及硫化物发光材料相比

S ∶ Eu

Gd红色长余辉材料具有较好的热稳定性。

Abstract

In this paper

red afterglow phosphor Y

S ∶ Eu

Gd was prepared by solid state reaction method and the thermal stability was studied in detail. The obtained phosphor compositions were characterized by X-ray diffraction (XRD). Luminescent properties were investigated by measuring emission spectra

excitation spectra and decay curves. When the heating temperature rises from 200 to 600 ℃

the major phase is Y

S and the luminescent properties are almost unchanged. When the heating temperature is 800 ℃

the Y

and Y

phase are observed. The peak position and peak pattern of emission spectrum are unchanged

but the intensity of emission spectrum is decreased. The excitation spectrum shows the same variation regularity. The relative intensity at 5 min (after the excitation source was turn off) is decreased to 80% compared with the one without heating process. When the heating temperature is increased to 1 000 ℃

the major phase is changed to Y

and Y

the intensity of emission spectrum is very low. The afterglow phenomenon almost disappears. The thermal stability of Y

S ∶ Eu

Gd phosphor is better than that of sulfide and aluminates phosphors. Thus

the Y

S ∶ Eu

Gd phosphor is a promising candidate of red afterglow luminescent material which can resistant to higher temperature environment.

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Keywords

references

Zhou Wei, Du Haiyai, GaO Bin, et al. Summary of study on non-radioactive persistent red phosphors [J]. J. Beijing Technology and Business University (Natural Science Edition)(北京工商大学学报,自然科学版), 2001, 19 (3):5-8 (in Chinese).[2] Sun Jibing, Wang Hairong, An Yaqin, et al. Progress on long persistence luminescent materials [J]. Rare Metal Mat. Eng. (稀有金属材料与工程), 2008, 37 (2):189-194 (in Chinese).[3] Chen Xuehua, Hu Yihua, Wang Yinhai, et al. Valence-change of Eu and its effect on the luminescent properties of long afterglow phosphor SrAl2O4 ∶ Eu, Dy [J]. Chin. J. Lumin. (发光学报), 2009, 30 (1):40-46 (in Chinese).[4] Lu Hao, Liu Aimei, Xiong Pingfan, et al. Temperature impact on luminescence performances of long-lasting afterglow glass [J]. Chin. J. Lumin. (发光学报), 2009, 30 (4):554-558 (in Chinese).[5] Dongdong Jia, Weiyi Jia, Evans D R, et al. Trapping processes in CaS ∶ Eu2+ ,Tm3+ [J]. J. Appl. Phys., 2000, 88 (6):3402-3407.[6] Yin Shengyu, Chen Donghua, Tang Wanjun, et al. Synthesis of CaTiO3 ∶ Pr persistent phosphors by a modified solid-state reaction [J]. Mater. Sci. Eng. B, 2007, 136 (2-3):193-196.[7] Shen Leijun, Zhao Zengqi, Han Li, et al. Effect of Zn,Cd on the luminescent properties of CaTiO3 ∶ Pr3+ [J]. Chin. J. Lumin.(发光学报), 2007, 28 (1):74-78 (in Chinese).[8] Zhang Ping, Xu Mingxia, Zheng Zhentai, et al. Rapid formation of red long afterglow phosphor Sr3Al2O6 ∶ Eu2+ , Dy3+ by microwave irradiation [J]. Mater. Sci. Eng. B, 2007, 136 (2-3):159-164.[9] Yan Wuzhao, Lin Lin, Chen Yonghu, et al. New red long afterglow aluminate materials doped with Mn4+ [J]. Chin. J. Lumin.(发光学报), 2008, 29 (1):114-118 (in Chinese).[10] Murazaki Y, Arai K, Ichinomiya K. A new long persistence red phosphor [J]. Rare Earths Jpn., 1999, 35 (1):41-45.[11] Zhou Xinmu, Zeng Huihui. Synthesis and characterization of new long lasting red phosphors Y2O2S ∶ Eu, Si, M(M=Mg, Ca, Sr, Ba) [J]. Chin. J. Lumin.(发光学报), 2010, 31 (1):59-63 (in Chinese).[12] Yang Zhiping, Guo Zhi, Wang Wenjie, et al. Synthesis of Y2O2S ∶ Eu3+ , Mg2+ ,Ti4+ red phosphor by flux fusion method and its characteristic [J]. Chin. J. Lumin.(发光学报), 2004, 25 (2):183-187 (in Chinese).[13] Wei Yashu, Zhang Jinchao, Song Li. Study on the firing condition and flux in synthesizing Y2O2S ∶ Eu3+ ,Mg2+ ,Ti4+ red afterglow phosphor [J]. Chin. J. Appl. Chem.(应用化学), 2005, 22 (12):1342-1346 (in Chinese).[14] Yang Zhiping, Guo Zhi, Zhu Shengchao, et al. Effect of Eu3+ molar ratio on the spectra of Y2O2S ∶ Eu3+ ,Mg2+ , Ti4+ red phosphor [J]. Spectroscopy Spect. Anal. (发谱学与光谱分析), 2004, 24 (12):1506-1510 (in Chinese).[15] Wang Yuhua, Wang Zhilong. Characterization of Y2O2S ∶ Eu3+ , Mg2+ , Ti4+ long-lasting phosphor synthesized by flux method [J]. J. Rare Earth, 2006, 24 (1):25-28.[16] Zhang Xiyan, Bai Zhaohui, Guan Xin, et al. Preparation of long persistent phosphorescence SrAl2O4 ∶ Eu2+ ,Dy3+ phosphors by solid state reaction and characterization [J]. Rare Metal Mat. Eng. (稀有金属材料与工程), 2003, 32 (5):379-382 (in Chinese).[17] Zhang Yue, Li Yadong. Synthesis and characterization of monodisperse doped ZnS nanospheres with enhanced thermal stability [J]. J. Phys. Chem. B, 2004, 108 (46):17805-17811.[18] Zhu Hongyang, Yang Haibin, Fu Wuyou, et al. The improvement of thermal stability of BaMgAl10O17 ∶ Eu2+ coated with MgO [J]. Mater. Lett., 2008, 62 (4-5):784-786.[19] Xiao Zhiguo, Luo Xixian. Long Afterglow Phosphors and Its Production [M]. Beijing: Chemical Industry Press, 2005:42 (in Chinese).

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