可用于白光LED的红色荧光粉NaGdTiO4∶Eu3+的制备及光学性质

李香萍; 仲海洋; 程丽红; 孙佳石; 张金苏; 王轶卓; 陈宝玖

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可用于白光LED的红色荧光粉NaGdTiO₄∶Eu³⁺的制备及光学性质

材料合成及性能研究 | 更新时间：2020-08-12

- 可用于白光LED的红色荧光粉NaGdTiO₄∶Eu³⁺的制备及光学性质
- Synthesis and Photoluminescence of NaGdTiO₄ ∶ Eu³⁺ Red Phosphors for White LEDs
- 发光学报 2011年32卷第2期页码：138-143
- 作者机构：
  
  1. 大连海事大学物理系,辽宁大连,116026
  2. 大连理工大学物理与光电工程学院,辽宁大连,116024
- 作者简介：
- 基金信息：
  
  国家自然科学基金(61078061)();中央高校基本科研业务费专项基金(2009QN126)资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2010-11-17，
  
  修回日期：2010-12-02，
  
  网络出版日期：2011-02-22，
  
  纸质出版日期：2011-02-22
- 稿件说明：
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李香萍, 仲海洋, 程丽红, 孙佳石, 张金苏, 王轶卓, 陈宝玖. 可用于白光LED的红色荧光粉NaGdTiO4∶Eu3+的制备及光学性质[J]. 发光学报, 2011,32(2): 138-143

LI Xiang-ping, ZHONG Hai-yang, CHENG Li-hong, SUN Jia-shi, ZHANG Jin-su, WANG Yi-zhuo, CHEN Bao-jiu. Synthesis and Photoluminescence of NaGdTiO4 ∶ Eu3+ Red Phosphors for White LEDs[J]. Chinese Journal of Luminescence, 2011,32(2): 138-143
李香萍, 仲海洋, 程丽红, 孙佳石, 张金苏, 王轶卓, 陈宝玖. 可用于白光LED的红色荧光粉NaGdTiO4∶Eu3+的制备及光学性质[J]. 发光学报, 2011,32(2): 138-143 DOI：

LI Xiang-ping, ZHONG Hai-yang, CHENG Li-hong, SUN Jia-shi, ZHANG Jin-su, WANG Yi-zhuo, CHEN Bao-jiu. Synthesis and Photoluminescence of NaGdTiO4 ∶ Eu3+ Red Phosphors for White LEDs[J]. Chinese Journal of Luminescence, 2011,32(2): 138-143 DOI：

摘要

采用高温固相反应法制备了NaGdTiO

∶ Eu

红色荧光粉。利用X射线衍射和荧光光谱对NaGdTiO

∶ Eu

粉末进行了表征

研究了TiO

含量和Eu

掺杂摩尔分数对粉末晶体结构和发光性能的影响。当TiO

的量在当量反应基础上增加50%时

制得了单一正交相NaGdTiO

。荧光光谱测试结果显示

样品在紫外区存在强的宽激发带

对应于NaGdTiO

基质的吸收。在281 nm紫外光激发下

样品显示出强的红光发射

表明NaGdTiO

基质到Eu

之间存在有效的能量传递。该类钛酸盐红色荧光粉在近紫外光激发型白光LED中具有潜在的应用价值。

Abstract

-doped NaGdTiO

red phosphors were synthesized by conventional solid state reaction method. The effects of TiO

content and Eu

mole fraction on the crystal structure and photoluminescence properties were investigated by X-ray diffraction and fluorescent spectra. The XRD patterns showed that the resultants with single orthogonal phase structure were achieved when TiO

content increased by 50% on the basis of stoichiometric reaction composition. In the excitation spectra of single orthogonal structure NaGdTiO

∶ Eu

phosphors

by monitoring 618 nm

the charge transfer bands (CTB) of Eu

-O

and NaGdTiO

matrix absorption centered at around 250 nm and 281 nm were observed

respectively. Under 281 nm excitation

strong red emission was observed at 618 nm originating from the

electric dipole transition of Eu

which suggests that there exist effective energy transfer from NaGdTiO

matrix to Eu

. The calculated emission color coordinates of NaGdTiO

∶ 20% Eu

are

x=0.63

=0.34. These results show that NaGdTiO

∶ Eu

phosphors might have potential applications in whit light-emitting diodes (LEDs).

关键词

Keywords

references

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