Zn2SiO4∶Mn2+, Sm3+发光材料的制备与荧光性能

张志伟; 张卫国; 牛少莉

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Zn₂SiO₄∶Mn²⁺, Sm³⁺发光材料的制备与荧光性能

材料合成及性能研究 | 更新时间：2020-08-12

- Zn₂SiO₄∶Mn²⁺, Sm³⁺发光材料的制备与荧光性能
- Fabrication and Luminescence Properties of Zn₂SiO₄(ZnB₂O₄) ∶ Mn²⁺ ,Sm³⁺ Phosphors
- 发光学报 2011年32卷第2期页码：144-148
- 作者机构：
  
  河北科技师范学院,河北秦皇岛,066600
- 作者简介：
- 基金信息：
  
  国家自然科学基金(50361003)();河北科技师范学院创新团队基金资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2010-08-23，
  
  修回日期：2010-10-15，
  
  网络出版日期：2011-02-22，
  
  纸质出版日期：2011-02-22
- 稿件说明：
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张志伟, 张卫国, 牛少莉. Zn2SiO4∶Mn2+, Sm3+发光材料的制备与荧光性能[J]. 发光学报, 2011,32(2): 144-148

ZHANG Zhi-wei, ZHANG Wei-guo, Niu Shao-li. Fabrication and Luminescence Properties of Zn2SiO4(ZnB2O4) ∶ Mn2+ ,Sm3+ Phosphors[J]. Chinese Journal of Luminescence, 2011,32(2): 144-148
张志伟, 张卫国, 牛少莉. Zn2SiO4∶Mn2+, Sm3+发光材料的制备与荧光性能[J]. 发光学报, 2011,32(2): 144-148 DOI：

ZHANG Zhi-wei, ZHANG Wei-guo, Niu Shao-li. Fabrication and Luminescence Properties of Zn2SiO4(ZnB2O4) ∶ Mn2+ ,Sm3+ Phosphors[J]. Chinese Journal of Luminescence, 2011,32(2): 144-148 DOI：

摘要

使用高温固相法首次合成了Zn

SiO

(ZnB

) ∶ Mn

发光材料

探讨了烧结温度、Sm

含量对样品荧光性能的影响。利用X射线衍射(XRD)、荧光光谱等分析手段对Zn

SiO

(ZnB

) ∶ Mn

粉末的结构、发光性能进行了表征。确定了该荧光材料的最佳合成条件

离子掺杂浓度等。实验结果表明:组成为Zn

SiO

(ZnB

) ∶ 1.2%Mn

8%Sm

的样品在950 ℃还原气氛下烧结

发光强度最高;反应生成的ZnB

和掺杂Sm

可以大幅提高材料发光强度。

Abstract

SiO

(ZnB

) ∶ Mn

phosphors was fabricated by solid reaction method. The influences of sintered temperature and Sm

content on the luminescence properties of Zn

SiO

(ZnB

) ∶ Mn

phosphors were studied. Powder structure and luminescence properties were characterized by means of XRD

excitation and emission spectra. The experimental results indicate that Zn

SiO

(ZnB

) ∶ Mn

has two excitation peaks at 220 nm and 250 nm

the luminescence intensity is the largest when the sintered temperature is at 950 ℃ in reducing atmosphere

and the emission peaks at 521 nm. The ZnB

as a part of host produced in the reaction can improve the luminescence intensity. At 950 ℃

there are most ZnB

reaction products

meanwhile

ZnB

has the best crystalline properties. With the Sm

content increased

the phase is not changed

however

to a large extent

the luminescence intensity can be improved. When the Sm

mole fraction is 8%

the intensity is the most and 5 times stronger than that for 4% Sm

. With the increasing of Sm

mole fraction

the luminescence emission peak has blue-shift from 540 nm to 521 nm.

关键词

Keywords

references

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