Er3+单掺和Er3+/Yb3+共掺碲酸盐玻璃的光谱性质及能量传递

姜慧鹏; 孙江亭; 黄慧敏; 郑双雁; 侯文远

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Er³⁺单掺和Er³⁺/Yb³⁺共掺碲酸盐玻璃的光谱性质及能量传递

材料合成及性能研究 | 更新时间：2020-08-12

- Er³⁺单掺和Er³⁺/Yb³⁺共掺碲酸盐玻璃的光谱性质及能量传递
- Spectroscopic Properties and Energy Transfer of Er³⁺-doped and Er³⁺/Yb³⁺ Co-doped Tellurite Glasses
- 发光学报 2011年32卷第12期页码：1221-1226
- 作者机构：
  
  哈尔滨师范大学物理与电子工程学院黑龙江省低维体系与介观物理重点实验室,黑龙江哈尔滨,150025
- 作者简介：
- 基金信息：
  
  黑龙江省教育厅科研项目(11551148)();黑龙江省科技厅高新技术攻关项目(GZ09A405)资助项目()
- DOI：
  中图分类号： O482.31
- 收稿日期：2011-09-03，
  
  修回日期：2011-10-08，
  
  网络出版日期：2011-12-22，
  
  纸质出版日期：2011-12-22
- 稿件说明：
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姜慧鹏, 孙江亭, 黄慧敏, 郑双雁, 侯文远. Er3+单掺和Er3+/Yb3+共掺碲酸盐玻璃的光谱性质及能量传递[J]. 发光学报, 2011,32(12): 1221-1226

JIANG Hui-peng, SUN Jiang-ting, HUANG Hui-min, ZHENG Shuang-yan, HOU Wen-yuan. Spectroscopic Properties and Energy Transfer of Er3+-doped and Er3+/Yb3+ Co-doped Tellurite Glasses[J]. Chinese Journal of Luminescence, 2011,32(12): 1221-1226
姜慧鹏, 孙江亭, 黄慧敏, 郑双雁, 侯文远. Er3+单掺和Er3+/Yb3+共掺碲酸盐玻璃的光谱性质及能量传递[J]. 发光学报, 2011,32(12): 1221-1226 DOI：

JIANG Hui-peng, SUN Jiang-ting, HUANG Hui-min, ZHENG Shuang-yan, HOU Wen-yuan. Spectroscopic Properties and Energy Transfer of Er3+-doped and Er3+/Yb3+ Co-doped Tellurite Glasses[J]. Chinese Journal of Luminescence, 2011,32(12): 1221-1226 DOI：

摘要

采用高温熔融法制备了新型Er

单掺和Er

/Yb

共掺的TeO

-Bi

-SiO

-B

玻璃

测试并分析了样品的吸收光谱、发射光谱以及Er

/Yb

共掺杂样品的发射光谱和荧光寿命。计算出了玻璃的J-O强度系数

(

6);系统讨论了Er

/Yb

共掺杂样品在808 nm激光激发下

与Er

近红外发射强度比值变化情况及Er

的反向能量传递机理。结果表明:Er

单掺玻璃系统在1.53 m附近的最大发射带宽可达90 nm;适量的Yb

引入到掺Er

玻璃中

可有效地减小Er

13/2

能级的消布居速率

提高Er

13/2

15/2

的发射强度和Er

13/2

能级的寿命。

Abstract

Erbium-doped fiber amplifier (EDFA)

utilizing the emission transition

13/2

15/2

of Er

is a key element of the 1.5 m window telecommunication system. In recent years

in order to raise amplifier gain parameters

many solutions

such as Er

/Yb

/Eu

/Sm

-doped

were introduced. In this paper

novel Er

-doped and Er

/Yb

co-doped TeO

-Bi

-SiO

-B

glass were prepared by high-temperature melt-quenching method. The absorption spectra and emission spectra of Er

- doped glass

the emission spectra and lifetimes of Er

/Yb

co-doped glass were measured and investigated. The intensity parameters

6) were calculated by using the theory of Judd-Ofelt. Under 808 nm semiconductor laser excitation

the infrared emission intensity ratio of Yb

ions to Er

ions and mechanism of counter energy transfer were discussed in Er

/Yb

co-doped glass. The results indicate that a maximum value of full width half maximum (FWHM) of 1.53 m infrared emission spectra is 90 nm in Er

-doped glasses

and the suitable content of Yb

ions is helpful for decreasing the disappearing population velocity of Er

13/2

level

increasing the emission intensity of Er

13/2

15/2

transition and lifetime of Er

13/2

level.

关键词

Keywords

references

Zhao Shilong, Wang Xiu, Fang Dawei, et al. Spectroscopic properties and thermal stability of Er3+-doped tungsten-tellurite glass for waveguide amplifier application [J]. J. Alloys Compds, 2006, 424 (1- 2):243-246.[2] Yu X C, Song F, Wang W T, et al. Comparison of optical parameters and luminescence between Er3+/Yb3+ co-doped phosphate glass ceramics and precursor glasses [J]. J. Appl. Phys., 2008, 104 (11):113105-1-4.[3] Liu Lisha, l Shuchen, Sun Jiangting. Spectroscopic properties and up-conversion luminescence Er3+/Yb3+ co-doped TeO2-WO3-Bi2O3 glass[J]. Acta Phys. Sin. (物理学报), 2010, 59 (9):6637-6641 (in Chinese).[4] Zhang Ming, Yu Hua, Hu Nan, et al. Luminescent properties of Er3+/Yb3+ codoped tellurite glass ceramic [J]. Chin. J. Lumin. (发光学报), 2011, 32 (8):761-765 (in English).[5] Zhou Yaxun, Wan Jun, Dai Shixun. Effect of Yb3+ on infrared and upconversion emission of Er3+-doped tellurite-based glasses [J]. Chinese Journal of Lasers (中国激光), 2007, 34 (12):1689-1693 (in Chinese).[6] Judd B R. Optical absorption intensities of rare-earth ions [J]. J. Phys. Rev., 1962, 127 (3):750-761.[7] Ofelt S. Intensities of crystal spectra of rare-earth ions [J]. J. Chem. Phys., 1962, 37 (3):511-520.[8] Oomen E W J L, Van Dongen A M A. Eu3+ in oxide glasses dependence of the emission spectrum upon glass composition [J]. J. Non-Cryst. Solids, 1989, 111 (2-3):205-213.[9] Tanabe S. Optical transitions of rare earth ions for amplifiers [J]. J. Non-Cryst. Solids, 1999, 259 (1-3):1-9.[10] McCumber D E. Theory of phonon-terminated optical masers [J]. Phys. Rev., 1964, 134 (2A):299-306.[11] Wu Zhaojun, Sun Jiangting, Zhang Jiahua, et al. Study on spectroscopic properties and thermal stability of novel erbium-doped tellurite glasses [J]. Journal of Optoelectronics Laser (光电子激光), 2008, 1 9 (8):1068-1070 (in Chinese).[12] Nandi P, Jose G. Spectroscopic properties of Er3+ doped phospho-tellurite glasses [J]. Phys. B, 2006, 381 (1-2):66-67.

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