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1. 中国科学院 激发态重点实验室 长春光学精密机械与物理研究所,吉林 长春,130033
2. 中国科学院 研究生院 北京,100039
收稿日期:2011-07-24,
修回日期:2011-09-21,
网络出版日期:2011-12-22,
纸质出版日期:2011-12-22
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王琪, 张金龙, 王立军, 刘云. 基于电感耦合等离子体的InP基半导体材料干法刻蚀的研究[J]. 发光学报, 2011,32(12): 1276-1280
WANG Qi, ZHANG Jin-long, WANG Li-jun, LIU Yun. Dry Etching of InP Material Based on Inductivity Coupled Plasma[J]. Chinese Journal of Luminescence, 2011,32(12): 1276-1280
研究了基于电感耦合等离子体(ICP)刻蚀系统的InP基半导体材料的干法刻蚀。采用Cl
2
/Ar/H
2
混合刻蚀气体
分别研究了氯气体积分数和ICP功率与刻蚀速率之间的关系
及镍、二氧化硅和二者结合型掩膜版的适用范围。获得有效的刻蚀速率为450~1200 nm/min
InP对金属镍的选择性刻蚀比值为175~190。掩膜版的选择与制备方法适用于基于ICP系统的任何半导体材料的干法刻蚀工艺。
Dry etching of InP material based on inductivity coupled plasma(ICP) was thoroughly studied
Cl
2
/Ar/H
2
gas mixture was adopted
and the etching depth could reach 10 m with a vertical and a smooth surface. The gas percentages of the total gas versus etching rate
and the applicable regions of Ni
SiO
2
and the combination of Ni and SiO
2
were studied
respectively. The regions of the effective etching rate and selectivity against Ni are 450~1200 nm/min and 175~190
respectively. The choosing and fabrication approaches adopted are highly suitable for any semiconductor material based on ICP system.
Zhao W, Bae J W, Adesida I, et al. Effect of mask thickness on the nanoscale sidewall roughness and optical scattering losses of deep-etched InP/InGaAsP high mesa waveguides [J]. J. Vac. Sci. Technol. B, 2005, 23 (5):2041-2045.[2] Sun C Z, Zhou Q W, Xiong B, et al. Vertical and smooth etching of InP by Cl2/Ar/CH4 inductively coupled plasma at room temperature [J]. Chin. Phys. Lett., 2003, 20 (8):1312-1314.[3] Park S, Kim S S, Wan L W, et al. InGaAsP-InP nanoscale waveguide-coupled microring lasers with submilliampere threshold current using Cl2/N2-based high-density plasma etching [J]. IEEE J. Quantm. Electron., 2005, 41 (3):351-356.[4] Adesida I, Nummila K, Andideh E, et al. Nanostructure fabrication in InP and related compounds [J]. J. Vac. Sci. Technol. B, 2002, 8 (6):1357-1360.[5] Hahn Y B, Hays D C, Cho H, et al. Effect of inert gas additive species on Cl2 high density plasma etching of compound semiconductors Part Ⅱ. InP, InSb, InGaP and InGaAs [J]. Appl. Surf. Sci., 1999, 144 (1-4):215-221.[6] MatsutanA I, Ohtsuki H, Koyama F, et al. Vertical and smooth etching of InP by Cl2/Xe inductively coupled plasma [J]. 1999, 38 (7A):4260-4261.[7] Rommel S L , Jang J H, Lu W, et al. Effect of H2 on the etch profile of InP/InGaAsP alloys in Cl2/Ar/H2 inductively coupled plasma reactive ion etching chemistries for photonic device fabrication [J]. J. Vac. Sci. Technol. B, 2002, 20 (4):1327-1330.[8] Jang J H, Zhao W, Bae J W , et al. Study of the evolution of nanoscale roughness from the line edge of exposed resist to the sidewall of deep-etched InP/InGaAsP heterostructures [J]. J. Vac. Sci. Technol. B, 2004, 22 (5):2538-2541.[9] Jang J H, Zhao W, Bae J W, et al., Direct measurement of nanoscale sidewall roughness of optical waveguides using an atomic force microscope [J]. Appl. Phys. Lett., 2003, 83 (20):4116-4118.[10] Lee C W, Nie D, Mei T, et al. Study and optimization of room temperature inductively coupled plasma etching of InP using Cl2/CH4/H2 and CH4/H2 [J]. J. Cry. Grow., 2006, 288 (1):213-216.[11] Gmachl C, Capasso F, Sivco D, et al. Recent progress in quantum cascade lasers and applications [J]. Rep. Prog. Phys., 2001, 64 (11):1553-1601.
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