新型固态照明用发光材料 Ca3SiO4Br2∶ Eu2+的合成、结构与发光性能

夏志国; 孙家跃; 李国武; 熊明; 杜海燕

doi:null

您当前的位置：

首页 >

文章列表页 >

新型固态照明用发光材料 Ca₃SiO₄Br₂∶ Eu²⁺的合成、结构与发光性能

材料合成及性能研究 | 更新时间：2020-08-12

- 新型固态照明用发光材料 Ca₃SiO₄Br₂∶ Eu²⁺的合成、结构与发光性能
- Synthesis and Analysis of Novel Solid State Lighting Compound Ca₃SiO₄Br₂∶ Eu²⁺
- 发光学报 2011年32卷第10期页码：988-992
- 作者机构：
  
  1. 中国地质大学(北京) 材料科学与工程学院北京,100083
  2. 北京工商大学化学与环境工程学院北京,100048
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51002146)();教育部博士点新教师基金(20090022120002)();中央高校基本科研业务费专项基金(2010ZY35, 2011YXL
- DOI：
  中图分类号： O482.31
- 收稿日期：2011-06-08，
  
  修回日期：2011-08-30，
  
  网络出版日期：2011-10-22，
  
  纸质出版日期：2011-10-22
- 稿件说明：
移动端阅览
夏志国, 孙家跃, 李国武, 熊明, 杜海燕. 新型固态照明用发光材料 Ca3SiO4Br2∶ Eu2+的合成、结构与发光性能[J]. 发光学报, 2011,32(10): 988-992

XIA Zhi-guo, SUN Jia-yue, LI Guo-wu, XIONG Ming, DU Hai-yan. Synthesis and Analysis of Novel Solid State Lighting Compound Ca3SiO4Br2∶ Eu2+[J]. Chinese Journal of Luminescence, 2011,32(10): 988-992
夏志国, 孙家跃, 李国武, 熊明, 杜海燕. 新型固态照明用发光材料 Ca3SiO4Br2∶ Eu2+的合成、结构与发光性能[J]. 发光学报, 2011,32(10): 988-992 DOI：

XIA Zhi-guo, SUN Jia-yue, LI Guo-wu, XIONG Ming, DU Hai-yan. Synthesis and Analysis of Novel Solid State Lighting Compound Ca3SiO4Br2∶ Eu2+[J]. Chinese Journal of Luminescence, 2011,32(10): 988-992 DOI：

摘要

制备了一种Eu

掺杂的新型Ca

SiO

蓝色发光材料

详细研究了其晶体结构组成。采用助熔剂法生长出Ca

SiO

片状单晶

解析并证实该晶体为Ca

SiO

其结构基元中存在交替排列的Ca

SiO

和CaBr

层。荧光光谱测试表明:Ca

SiO

∶ Eu

材料可被近紫外光(300~430 nm)有效激发

产生较强的蓝光发射

发射主峰位于470 nm左右

样品的紫外-可见(UV-Vis)光谱进一步证实了其有效吸收近紫外光的特征。研究表明

卤硅酸盐基质的Ca

SiO

∶ Eu

材料是一种优良白光LED用蓝色荧光粉。

Abstract

Novel blue-emitting material

-doped Ca

SiO

was reported in this paper. Flaky crystals of Ca

SiO

were grown out of high-temperature Ca

SiO

/CaBr

melts. The crystal structure was determined as the chemical composition of Ca

SiO

and structural investigations have also shown that Ca

SiO

is composed of the layers of calcium chloride and dicalcium silicate. Based on the photoluminescence analysis

SiO

∶ Eu

phosphor exhibited a broad blue emission band of main peak at 470 nm under the near ultraviolet (n-UV) light (300~450 nm)

and efficient n-UV absorption property can be testified by UV-Vis diffuse reflectance spectra. It indicated that halosilicate materials Ca

SiO

∶ Eu

phosphor is an excellent phosphor in the application of the white LEDs.

关键词

Keywords

references

Liu Xingren. Phosphor for white LED solid state lighting [J]. Chin. J. Lumin. (发光学报), 2007, 28 (3):291-301 (in Chinese).[2] Hppe H A. Recent developments in the field of inorganic phosphors [J]. Angew Chem. Int. Ed., 2009, 48 :3572-3582.[3] Wu Hao, Pan Yuexiao, Guo Congfei, et al. Fabrication and p roperties of rare earth phosphors and their applications in white-light LEDs [J]. Chin. J. Lumin. (发光学报), 2006, 27 (2):201-205 (in Chinese).[4] Li Huijuan, Shao Qiyue, Dong Yan, et al. The thermal quenching of YAG∶Ce3+ phosphors for white LED application [J]. Chin. J. Lumin. (发光学报), 2008, 29 (6):984-985 (in Chinese).[5] Xia Z G, Sun J Y, Du H Y. Study on luminescence properties and crystal-lattice environmental of Eu2+ in Sr4-x-MgxSi3O8Cl4∶Eu2+ phosphor [J]. J. Rare Earths, 2004, 22 (3):370-374.[6] Xia Z G, Sun J Y, Du H Y, et al. Luminescence of Eu2+ in alkali earth chlorosilicate phosphor and their color-tunable properties [J]. Opt. Mater., 2006, 28 (5):524-529.[7] Shen C, Shao Q Y, Han X L, et al. Luminescent properties of Ca8Mg(SiO4)4Cl2∶Eu2+,Dy3+ phosphor for white LED [J]. Chin. J. Lumin. (发光学报), 2010, 31 (1):44-48 (in Chinese).[8] Xia Z G, Du H Y, Sun J Y, et al. A novel blue-emitting Ca2B5O9Br∶Eu2+ phosphor prepared by a microwave calcination route [J]. Mater. Chem. Phys., 2010, 119 (1):7-11.[9] Guo C F, Luan L F, Shi F G, et al. White-emitting Phosphor Ca2BO3Cl∶Ce3+,Eu2+ for UV light-emitting diodes [J]. J. Electrochem. Soc., 2009, 156 (1):J125-J128.[10] Song Y S, Jia G, Yang M, et al. Sr3Al2O5Cl2∶Ce3+,Eu2+: A potential tunable yellow-to-white-emitting phosphor for ultraviolet light emitting diodes [J]. Appl. Phys. Lett., 2009, 94 (9):091902-1-3.[11] Lee J J, Choi J C, Zhang X M, et al. Novel blue-emitting Sr3Ga2O5Cl2∶Eu2+ phosphor for UV-pumped white LEDs [J]. Mater. Lett., 2010, 64 (6):768-770.[12] Chiu Y C, Liu W R, Chang C K, et al. Ca2PO4Cl∶ Eu2+:An intense near-ultraviolet converting blue phosphor for white light-emitting diodes [J]. J. Mater. Chem., 2010, 20 (9):1755-1758.[13] Ye R L, Wang X R, Zhang Z Y. Crystal structure of the new compound calcium magnesium silicate chloride [J]. J. Chin. Ceram. Soc. (硅酸盐学报), 1987, 15 (4):309-314 (in Chinese).[14] Yang Y, Jin S Z, Shen C Y, et al. Spectral properties of alkaline earth composite silicate phosphors for white-LED [J]. Chin. J. Lumin. (发光学报), 2008, 29 (5):800-804 (in Chinese).[15] Yang C T, Chen Q Q, Meng J X, et al. Effect of Ca2+ doping on luminescence properties of BaMgSiO4∶Eu2+ phosphor [J]. Chin. J. Lumin. (发光学报), 2010, 31 (3):316-320 (in Chinese).[16] Ding W J, Wang J, Zhang M, et al. A novel orange phosphor of Eu2+-activated calcium chlorosilicate for white light-emitting diodes [J]. J. Solid State Chem., 2006, 179 (11):3582-3585.[17] Xia Z G, Li G W, Chen D M, et al. Synthesis and calcination temperature dependence photoluminescence properties of novel bromosilicate phosphors [J]. Mater. Lett., 2009, 63 (29):2600-2602.[18] Xia Z G, Li Q, Sun J Y. Greenish-yellow light-emitting, long-lasting phosphorescence in Eu2+-doped CaO-CaBr2-SiO2 phosphor system [J]. Chem. Lett., 2006, 35 (7):764-765.[19] Xia Z G, Liu J, Li Q, et al. Comparative investigation of photoluminescence and long-lasting phosphorescence properties in the (CaO-CaBr2-SiO2)∶Eu2+ phosphor system [J]. Electrochem. Solid-State Lett., 2007, 10 (1):J4-J8.[20] Xia Z G, Li Q, Li G W, et al. Crystal growth of Ca3SiO4Br2: New photoluminescence bromosilicate host [J]. J. Crys. Growth, 2011, 318 (1):958-961.[21] Bachmann V, Ronda C, Meijierink A. Temperature quenching of yellow Ce3+ luminescence in YAG∶Ce [J]. Chem. Mater., 2009, 21 (10):2077-2084.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

Li（Sc, M）Si₂O₆∶Cr³⁺（M = Ga³⁺/Lu³⁺/Y³⁺/Gd³⁺）的近红外发光性能

稀土离子的多格位占据及能量传递

稀土掺杂铅卤钙钛矿发光、光电材料与器件研究进展

Ce³⁺掺杂Y‐Si‐O‐N体系荧光材料晶体及能带/电子结构对其发光特性的影响

Ba²⁺调制SrGe_4-xO₉∶xMn⁴⁺晶体结构及其发光性质