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1. 中国科学院 长春光学精密机械与物理研究所,吉林 长春,中国,130033
2. 长春理工大学 理学院,吉林 长春,130021
收稿日期:2010-04-05,
修回日期:2010-08-30,
网络出版日期:2010-11-22,
纸质出版日期:2010-11-22
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王阳, 张继森, 吕少哲, 孙秀平, 夏楠. (ZnO)<sub>1<em>-x-y</em></sub>(P<sub>2</sub>O<sub>5</sub>)<em><sub>x</sub></em>(B<sub>2</sub>O<sub>3</sub>)<sub><em>y</em></sub>玻璃的环境稳定性和红外光致发光[J]. 发光学报, 2010,31(6): 796-799
WANG Yang, ZHANG Ji-sen, LU Shao-zhe, SUN Xiu-ping, XIA Nan. Durability and Near-infrared Photoluminescence of Er<sup>3+</sup>-doped (ZnO) <sub>1-<em>x-y</em></sub>(P<sub>2</sub>O<sub>5</sub> ) <sub><em>x</em></sub>(B<sub>2</sub>O<sub>3</sub> ) <sub><em>y</em></sub> Glass Systems[J]. Chinese Journal of Luminescence, 2010,31(6): 796-799
王阳, 张继森, 吕少哲, 孙秀平, 夏楠. (ZnO)<sub>1<em>-x-y</em></sub>(P<sub>2</sub>O<sub>5</sub>)<em><sub>x</sub></em>(B<sub>2</sub>O<sub>3</sub>)<sub><em>y</em></sub>玻璃的环境稳定性和红外光致发光[J]. 发光学报, 2010,31(6): 796-799 DOI:
WANG Yang, ZHANG Ji-sen, LU Shao-zhe, SUN Xiu-ping, XIA Nan. Durability and Near-infrared Photoluminescence of Er<sup>3+</sup>-doped (ZnO) <sub>1-<em>x-y</em></sub>(P<sub>2</sub>O<sub>5</sub> ) <sub><em>x</em></sub>(B<sub>2</sub>O<sub>3</sub> ) <sub><em>y</em></sub> Glass Systems[J]. Chinese Journal of Luminescence, 2010,31(6): 796-799 DOI:
Er
3+
掺杂的(ZnO)
1-
x-y
(P
2
O
5
)
x
(B
2
O
3
)
y
玻璃具有优良的光学性质。沸水煮沸实验结果表明
该类玻璃具有较高的环境稳定性。与(Er
2
O
3
)
z
(ZnO)
1-
x-z
(P
2
O
5
)
x-z
类玻璃相比
Er
3+
掺杂的该类玻璃在1.5m峰值位置的光谱半峰全宽超过110nm
而且具有较高的猝灭浓度。
Er
3+
-doped (B
2
O
3
)
y
(ZnO)
1-
x-y
(P
2
O
5
)
x
glass with excellent optical properties was prepared. The glass was proved to have the high stability by the investigation of the durability in boiling water. The spectral characters of the glass at about 1.5 m changed a lot with the doped contents of both Er
3+
and B
2
O
3
. Comparing with Er
3+
-doped zinc phosphate glass systems
the glass prepared in our laboratory exhibits a larger quenching concentration and a much broader emission band at 1.54 m.
Jiang S, Myers M J, Peyghambarian N. Er3+ doped phosphate glasses and lasers [J]. J. Non-cryst. Solids, 1998, 239 (1-3):143-148.[2] Yang Yanmin, Yang Zhiping, Zhang Cangsheng, et al. Spectroscopic properties of Er3+-doped borate glass containing more silve [J]. Chin. J. Lumin. (发光学报), 2009, 30 (1):40-46 (in Chinese).[3] Van Wazer J R. Phosphorous and Its Compounds [M]. New York: Inter-science, 1958.[4] Abe Y. Topics in Phosphorous Chemistry [M]. New York: Wiley, 1983.[5] Otaigbe J U, Beall G H. Inorganic phosphate glasses as polymers [J]. Tends Polym. Sci., 1997, 5 (11):369-379.[6] Allan B J, Hiremath B V (Eds.). Solid State Optical Materials in Ceramic Transitions [M]. Westerville: American Ceramic Society, 1992.[7] Quinn C J, Frayer P D, Beall G H in:Salamone J C (Eds.). Polymeric Material Encyclopedia [M]. Boca Raton: CRC, 1996, 2766.[8] Zarzycki J in: Cahn R W, Haasen P, Kramer E J (Eds.). Materials Science and Technology [M]. Weinheim: American Ceramic Society, 1991, 314.[9] Powell R. Physics of Solid-State Laser Materials [M]. Berlin: Springer, 1998.[10] Gan Fuxi. Optical and Spectroscopic Properties of Glass [M]. Berlin: Springer, 1992.[11] Quimby R, Miniscalco W J, Thompson B. Clustering in erbium-doped silica glass fibers analyzed using 980 nm excited-state absorption [J]. J. Appl. Phys., 1994, 76 (8):4472-4478.[12] De Barros M R X, Nykolak G, DiGiovanni D J, et al. Performance of a high concentration Er-doped alumino silicate fiber amplifier [J]. IEEE Photonics Technol. Lett., 1996, 8 (6):761-763.[13] Nishi T, Nakagawa K, Ohishi Y, et al. The amplification properties of a highly Er3+-doped phosphate fiber [J]. Jpn. J. Appl. Phys. B, 1992, 31 (2):L177-L179.[14] Wang Xiaojun, Huang Shihua, Srivastavu A M, et al. Photon cascade emission through energy transfer in Pr3+ and Er3+ codoped system [J]. Journal of Rare Earths, 2002, 20 (4):259-263.
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