新型三元配合物Tb(DPAB)3IP的制备与发光性能

任晓明; 魏长平; 吕志军; 贾坤; 于敏娜

doi:null

您当前的位置：

首页 >

文章列表页 >

新型三元配合物Tb(DPAB)₃IP的制备与发光性能

论文 | 更新时间：2020-08-12

- 新型三元配合物Tb(DPAB)₃IP的制备与发光性能
- Synthesis and Photoluminescent Property of A Novel Tb(DPAB)₃IP Complex
- 发光学报 2010年31卷第6期页码：926-930
- 作者机构：
  
  长春理工大学材料科学与工程学院,吉林长春,130022
- 作者简介：
- 基金信息：
  
  吉林省教育厅科技项目(2006237)资助()
- DOI：
  中图分类号： O482.31
- 收稿日期：2009-11-19，
  
  修回日期：2010-01-05，
  
  网络出版日期：2010-11-22，
  
  纸质出版日期：2010-11-22
- 稿件说明：
移动端阅览
任晓明, 魏长平, 吕志军, 贾坤, 于敏娜. 新型三元配合物Tb(DPAB)3IP的制备与发光性能[J]. 发光学报, 2010,31(6): 926-930

REN Xiao-ming, WEI Chang-ping, LU Zhi-jun, JIA Kun, YU Min-na. Synthesis and Photoluminescent Property of A Novel Tb(DPAB)3IP Complex[J]. Chinese Journal of Luminescence, 2010,31(6): 926-930
任晓明, 魏长平, 吕志军, 贾坤, 于敏娜. 新型三元配合物Tb(DPAB)3IP的制备与发光性能[J]. 发光学报, 2010,31(6): 926-930 DOI：

REN Xiao-ming, WEI Chang-ping, LU Zhi-jun, JIA Kun, YU Min-na. Synthesis and Photoluminescent Property of A Novel Tb(DPAB)3IP Complex[J]. Chinese Journal of Luminescence, 2010,31(6): 926-930 DOI：

摘要

合成了邻菲罗啉的衍生物咪唑并邻菲罗啉(IP)

并以其为第二配体

二苯胺羰基邻苯甲酸(HDPAB)为第一配体

制备出新型稀土铽三元有机配合物Tb(DPAB)

IP。采用元素分析、红外光谱和紫外光谱对合成的配体及配合物进行了表征。通过荧光光谱研究了配合物的荧光性质

结果表明第二配体IP有较大的共轭体系

在紫外光激发下

配合物中的配体可将吸收的能量传递给稀土Tb

离子

表现出较强的Tb

离子的特征发射

且配体Tb(DPAB)

IP的荧光强度明显大于Tb(DPAB)

phen的荧光强度。这说明适宜的第二配体对配合物有很好的敏化发光作用

合成的Tb(DPAB)

IP是一种良好的绿光材料。

Abstract

In this paper

imidazo phenanthroline(IP) and 2-diphenylamine carbonyl benzoic (HDPAB) were synthesized. Then HDPAB was used as the first ligand and IP as the secondary ligand

a new ternary organic terbium complex Tb(DPAB)

IP was prepared. In the same condition

with the same first ligand

Tb(DPAB)

phen was prepared where phen as the second ligand. The structures and compositions of the ligands and ternary complexes were confirmed by elemental analysis

IR spectra and UV spectra

the fluorescence properties of the two terbium complexes were also studied. Elemental analysis demonstrated that the compositions of the ternary complexes were Tb(DPAB)

IP and Tb(DPAB)

phen. IR spectra indicated that rare earth Tb

ion coordinated with six oxygen atoms of three benzoic acid ligands and two nitrogen atoms of the second ligand. UV spectra showed that the main absorption was from HDPAB in the ternary complex.Fluorescence spectra demonstrated that two kinds of ternary organic terbium complexes could emit characteristic fluorescence of rare earth Tb

and the second ligand IP had stronger conjugation system. With the excitation of ultraviolet

the energy absorbed by the ligands in the complexes could be transfered to the rare earth Tb

ion

so they could emit characteristic fluorescence and the fluorescence intensity of Tb(DPAB)

IP was obviously higher than that of Tb(DPAB)

phen. Thus the appropriate secondary ligand of imidazo Phenanthroline (IP) obviously enhanced the fluorescent intensity of terbium complex. So

the new ternary organic terbium complex of Tb(DPAB)

IP is an excellent green-emitting material.

关键词

Keywords

references

Kido J, Nagai K, Okamoto Y. Organic electroluminescent devices using lanthanide complexes [J]. J. Alloys Compd., 1993, 192 (1-2):30-33.[2] Pope M, Kallmann H P, Magnante P. Electroluminescence in organic crystal [J]. J. Chem. Phys., 1963, 38 (8):2042-2043.[3] Li W L, Yu J Q. Organic electroluminescent devices using terbium chelates as the emitting layers [J]. Synth. Met., 1997, 91 (1-3):263-265.[4] Tian Wenjing, Wu Fang, Fan Yuguo, et al. Energy band structure of organic/polymer materials and its applications in electroluminescent devices [J]. Chin. J. Lumin. (发光学报), 2000, 21 (3):230-237 (in Chinese).[5] Ding Bangdong, Zhang Jimei, Zhu Wenqing, et al. Convenient electrochemical method to determine the energy level of organic electroluminescent materials [J]. Chin. J. Lumin. (发光学报), 2003, 24 (6):606-611 (in Chinese).[6] Yu G, Liu Y Q, Wu X, et al. Soluble europium complexes for light-emitting diodes [J]. Chem. Mater., 2000, 12 (9):2537-2541.[7] Gao Xin, Deng Zhenbo, Tao Dongliang, et al. Luminescence properties of a new kind of rare earth complexes [J]. J. Chin. Rare Earth Soc. (中国稀土学报), 2001, 19 (6):536-539 (in Chinese).[8] Fu Y J, Wong T K S, Yan Y K, et al. Synthesis, characterization and luminescent properties of a europium(Ⅲ) complex [J]. Thin Solid Films, 2002, 417 (1-2):78-84.[9] Li Wenxian, Zhang Raiping, Guo Lei, et al. Synthesis of phenylacetic acid rare earth complexes at low temperature solid state reaction and luminescence property of Eu3+ complexes [J]. Chin. J. Lumin. (发光学报), 2007, 28 (2):207-213(in Chinese).[10] Xu Lijuan, Wang Ruifen, Zhao Na, et al. Synthesis and properties of ternary terbium complexes with halogen-benzoic acid and 1, 10-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):781-787 (in Chinese).

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

卤代苯甲酸铽与1, 10-邻菲哕啉三元配合物的合成及性质

间甲基和邻氯苯甲酸稀土配合物发光性能的研究

铽－甲基吲哚乙酰丙酮三元配合物发光过程研究

静电纺丝技术制备Eu(BPA)₃phen/聚丙烯腈纤维及其性能

基于稀土配合物和离子液体的新型稀土发光材料研究进展