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1. 南京工业大学 材料科学与工程学院,江苏 南京,210009
2. 南京工业大学 电光源材料科学研究所,江苏 南京,210015
收稿日期:2009-11-19,
修回日期:2010-03-11,
网络出版日期:2010-11-22,
纸质出版日期:2010-11-22
移动端阅览
谢晔, 王涛, 王海波. Y(PV)O<sub>4</sub>:Eu<sup>3+</sup>荧光粉表面包覆Y(OH)<sub>3</sub>的性能[J]. 发光学报, 2010,31(6): 821-825
XIE Ye, WANG Tao, WANG Hai-bo. Surface Coating of Y(PV)O<sub>4</sub>:Eu<sup>3+</sup> Phosphor with Y(OH)<sub>3</sub>[J]. Chinese Journal of Luminescence, 2010,31(6): 821-825
采用化学共沉淀法对Y(PV)O
4
:Eu
3+
荧光粉进行表面包膜处理
获得了表面均匀包覆Y(OH)
3
膜层的Y(PV)O
4
:Eu
3+
荧光粉。用SEM、XRD等手段对其表面形貌、晶格结构性能进行了表征。结果表明:在Y(PV)O
4
:Eu
3+
粉体表面均匀包覆Y(OH)
3
膜层后
Y(PV)O
4
:Eu
3+
的晶格结构、发光性能没有改变
亮度较未包覆的荧光粉有较大提高
且没有发生色坐标偏移现象。
In this work
Y(PV)O
4
:Eu
3+
phosphors were coated with Y(OH)
3
by the coprecipitation process. The surface morphology and the crystal structure were characterized by SEM and XRD
respectively. The results indicated that the surface of Y(PV)O
4
:Eu
3+
phosphors are evenly coated by Y(OH)
3
and the crystal structure of the coated Y(PV)O
4
:Eu
3+
phosphors remains the same with the uncoated samples
i.e.
after surface treatment
the luminance centre of Eu
3+
does not shift
the emission is still at about 620 nm. The color coordinates of Y(PV)O
4
:Eu
3+
are
x
=0.660
y
=0.340
so it can meet the requirement of PDP. The emitting spectra of Y(PV)O
4
:Eu
3+
phosphor particles coated with Y(OH)
3
and without coating were investigated under 308 nm excitation. The results demonstrated that the initial luminance of coated Y(PV)O
4
:Eu
3+
phosphors is higher than the uncoated samples. This method is simple
convenient and economical as compared with other methods.
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