BaAl12O19:Mn2+和YPO4:Tb3+共混对等离子绿色发光体发光性能的改善

任新光; 狄卫华

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BaAl₁₂O₁₉:Mn²⁺和YPO₄:Tb³⁺共混对等离子绿色发光体发光性能的改善

论文 | 更新时间：2020-08-12

- BaAl₁₂O₁₉:Mn²⁺和YPO₄:Tb³⁺共混对等离子绿色发光体发光性能的改善
- Improvement of Luminescence Performance on Green-emitting PDP Phosphor by Blending BaAl₁₂O₁₉:Mn²⁺ and YPO₄:Tb²⁺
- 发光学报 2010年31卷第6期页码：826-830
- 作者机构：
  
  中国科学院长春光学精密机械与物理研究所激发态物理重点实验室,吉林长春,130033
- 作者简介：
- 基金信息：
  
  国家自然科学基金(50502031)();吉林省科技厅自然科学基金(20060522)资助项目()
- DOI：
  中图分类号： O482.31;TN104.3
- 收稿日期：2009-12-19，
  
  修回日期：2010-03-12，
  
  网络出版日期：2010-11-22，
  
  纸质出版日期：2010-11-22
- 稿件说明：
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任新光, 狄卫华. BaAl12O19:Mn2+和YPO4:Tb3+共混对等离子绿色发光体发光性能的改善[J]. 发光学报, 2010,31(6): 826-830

REN Xin-guang, DI Wei-hua. Improvement of Luminescence Performance on Green-emitting PDP Phosphor by Blending BaAl12O19:Mn2+ and YPO4:Tb2+[J]. Chinese Journal of Luminescence, 2010,31(6): 826-830
任新光, 狄卫华. BaAl12O19:Mn2+和YPO4:Tb3+共混对等离子绿色发光体发光性能的改善[J]. 发光学报, 2010,31(6): 826-830 DOI：

REN Xin-guang, DI Wei-hua. Improvement of Luminescence Performance on Green-emitting PDP Phosphor by Blending BaAl12O19:Mn2+ and YPO4:Tb2+[J]. Chinese Journal of Luminescence, 2010,31(6): 826-830 DOI：

摘要

等离子体平板显示用绿色发光粉主要有硅酸盐(Zn

SiO

:Mn

)、铝酸盐(BaAl

:Mn

)、磷酸盐(YPO

:Tb

)和硼酸盐(YBO

:Tb

)4种体系。前两者具有量子效率高、色纯度好等优点

然而抗真空紫外辐照能力差

发光衰减时间长;Tb

激活的磷酸盐和硼酸盐体系具有适宜的发光寿命

抗真空紫外辐射能力强

然而Tb

的发射光是黄绿色

色纯度不够好

且发光亮度相对较弱。按一定的混合比率使BaAl

:Mn

和YPO

:Tb

均匀混合

组合这两种体系绿色发光粉各自的优点

优化了等离子体平板显示用绿色发光粉的整体性能。

Abstract

The research on Plasma display panel (PDP) phosphors has gained much attention. The green PDP phosphor is an important component due to its highest brightness in three-color-based phosphors. Existing and developing green-emitting phosphors include Mn-activated silicates and aluminates

and Tb-activated phosphates and borates systems. Mn-activated silicates and aluminates have high quantum efficiency and excellent color coordinate

but low stability to vacuum ultraviolet (VUV) radiation and long decay time. Tb-activated phosphates and borates have suitable decay time and high stability to VUV radiation

but low brightness and color purity. This work investigates the luminescent performance of single BaAl

:Mn

YPO

:Tb

and especially their blends. The result indicates that the blends of BaAl

:Mn

and YPO

:Tb

can effectively combine their respective advantages to improve the overall luminescent performance of green-emitting phosphors for PDP application.

关键词

Keywords

references

Shen Sikuan, Zhang Xiaoning, Huang Jinfu. New progress of key technologies in PDPs [J]. Chin. J. Liquid Crystal and Displays (液晶与显示), 2009, 24 (1):38-42 (in Chinese).[2] Jung K Y, Kim E J, Kang Y C, et al. Morphology control and optimization of luminescent property of YBO3 ∶ Tb phosphor particles prepared by spray pyrolysis [J]. J. Electrochem. Soc., 2004, 151 (3):H69-H73.[3] Di W H, Wang X J, Chen B J, et al. Preparation, characterization and VUV luminescence property of YPO4 ∶ Tb phosphor for a PDP [J]. Opt. Mater., 2005, 27 (8):1386-1390.[4] Hong G Y, Jeoung B W, Jeon B S, et al. Improvement of discharge characteristics of the Zn2SiO4 ∶ Mn2+ phosphor layer in plasma display panels [J]. J. Electrochem. Soc., 2004, 151 (10):H205-H209.[5] Sohn K S, Park E S, Kim C H, et al. Photoluminescence behavior of BaAl12O19 ∶ Mn phosphor prepared by pseudocombinational chemistry method [J]. J. Electrochem. Soc., 2000, 147 (11):4368-4373.[6] Ronda C R, Amrein T. Evidence for exchange-induced luminescence in Zn2SiO4 ∶ Mn [J]. J. Lumin., 1996, 69 (5-6):245-248.[7] Rao R P. Tb3+ activated green phosphors for plasma display panel applications [J]. J. Electrochem. Soc., 2003, 150 (8):H165-H171.

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