三维超分子化合物(C12N2H8)的合成、晶体结构与荧光性质

范瑞清; 孙存发; 王平; 周广鹏; 陈红

doi:null

您当前的位置：

首页 >

文章列表页 >

三维超分子化合物(C₁₂N₂H₈)的合成、晶体结构与荧光性质

论文 | 更新时间：2020-08-12

- 三维超分子化合物(C₁₂N₂H₈)的合成、晶体结构与荧光性质
- Synthesis, Crystal Structure and Luminescent Properties of 3-D Supramolecular Compound (C₁₂N₂H₈)
- 发光学报 2010年31卷第6期页码：931-935
- 作者机构：
  
  哈尔滨工业大学化学系,黑龙江哈尔滨,150001
- 作者简介：
- 基金信息：
  
  国家自然科学基金(21071035, 20771030,20671025,20971031)();高等学校博士学科点专项科研基金(20070213005)();哈尔滨市
- DOI：
  中图分类号： O482.31
- 收稿日期：2010-04-28，
  
  修回日期：2010-07-08，
  
  网络出版日期：2010-11-22，
  
  纸质出版日期：2010-11-22
- 稿件说明：
移动端阅览
范瑞清, 孙存发, 王平, 周广鹏, 陈红. 三维超分子化合物(C12N2H8)的合成、晶体结构与荧光性质[J]. 发光学报, 2010,31(6): 931-935

FAN Rui-qing, SUN Cun-fa, WANG Ping, ZHOU Guang-peng, CHEN Hong. Synthesis, Crystal Structure and Luminescent Properties of 3-D Supramolecular Compound (C12N2H8)[J]. Chinese Journal of Luminescence, 2010,31(6): 931-935
范瑞清, 孙存发, 王平, 周广鹏, 陈红. 三维超分子化合物(C12N2H8)的合成、晶体结构与荧光性质[J]. 发光学报, 2010,31(6): 931-935 DOI：

FAN Rui-qing, SUN Cun-fa, WANG Ping, ZHOU Guang-peng, CHEN Hong. Synthesis, Crystal Structure and Luminescent Properties of 3-D Supramolecular Compound (C12N2H8)[J]. Chinese Journal of Luminescence, 2010,31(6): 931-935 DOI：

摘要

合成了一个三维超分子化合物(C

)(C

)(命名为BP1)

通过元素分析、红外光谱、核磁共振氢谱和X射线单晶衍射对其结构进行了表征

结果表明分子之间通过氢键和-堆积弱的相互作用形成超分子化合物。对所有合成的超分子化合物进行了紫外光谱和荧光光谱的测试。在室温DMSO溶液中

当激发波长为342nm时

化合物在373nm处有一强发射峰

呈现紫色荧光

这可以归属于分子内的

跃迁。X射线单晶衍射分析结果表明

该超分子化合物属于三斜晶系

1空间群

晶胞参数

=1.0878(2)nm

=1.1252(2)nm

=1.1680(2)nm

=97.89(3)

=110.91(3)

=109.62(3)

=1.2032(4)nm

=0.0531

=0.1634

GOF值为1.034。

Abstract

Supramolecular system has received great attention in the fields of catalytic

magnetic

liquid crystal materials

and bio-organic chemistry in recent years. They are composed of monomeric units through non-covalent intermolecular interactions including intermolecular hydrogen bond and - stacking interaction. The result is that the energy of the molecular system is greatly reduced and the molecular structure becomes more stable

which leads to the emergence of new properties of the optics

electricity

magnetic

and biological activity. Till now

many supramolecular polymers with one-dimensional chain

two-dimensional layer or three-dimensional open framework structures have been reported. In this work

a 3-D supramolecular compound (C

)(C

) (BP1) was synthesized and characterized by elemental analysis

H NMR and single-crystal X-ray diffraction. In the crystal structure

multiform hydrogen bonds and - stacking interactions lead to a 3-D supramolecular compound. At room temperature in DMSO solution

the compound has purple fluorescent emission at 373 nm

when excited at excitation wavelength of 342 nm. Fluorescent emission of the compounds originates from

transitions in molecular. The crystal belongs to triclinic

space group

1 with

=1.087 8(2) nm

=1.125 2(2) nm

=1.168 0(2) nm

=97.89(3)

=110.91(3)

=109.62(3)

=1.203 2(4) nm

=0.053 1

=0.163 4

GOF is 1.034.

关键词

Keywords

references

Lehn J M. Supramolecular Chemistry-Scope and Perspectives [M]. Beijing: Peking University Press, 2002, 21-186 (in Chinese).[2] Bosman A W, Sijbesma R P, Meijer E W. Supramolecular polymers at work [J]. Materials Today, 2004, 7 (4):34-39.[3] Ni Yiping, Chen Jianding. The progress of supramolecular polymers [J]. China Synthetic Resin and Plastics (合成树脂及塑料), 2008, 25 (5):73-76 (in Chinese).[4] Lu Yafei. Supramolecular polymer science and engineering [J]. Polymer Materials Science and Engineering (高分子材料科学与工程), 2005, 25 (3):47-51 (in Chinese).[5] Roithova J, Milko P. Naphthol coupling monitored by infrared spectroscopy in the gas phase [J]. J. Am. Chem. Soc., 2010, 132 (1):281-288.[6] Zhang Jun, Dong Limin, Jiang Jianxin, et al. Synthesis and fluorescence properties of Eu3+-trimellitic acid-1,10-phenanthroline ternary complexes doped with La3+ ion [J]. Chin. J. Lumin. (发光学报), 2010, 31 (1):131-136 (in Chinese).[7] Caulder D L, Raymond K N. Supermolecules by design [J]. Acc. Chem. Rev., 1999, 32 (11):975-982.[8] Du Miao, Zhang Zhihui, Zhao Xiaojun. Cocrystallization of bent dipyridyl type compounds with aromatic dicarboxylic acids: effect of the geometries of building blocks on hydrogen-bonding supramolecular patterns [J]. Cryst. Growth Des., 2005, 5 (3):1199-1208.[9] Aaker C B, Scott B M, Smith M M, et al. Establishing amide:amide reliability and synthon transferability in the supramolecular assembly of metal-containing one-dimensional architectures [J]. Inorg. Chem., 2009, 48 (9):4052-4061.[10] Chen Jing, Nan Qiuli, Guo Lingxiang, et al. Preparation and characterization of novel optically active polyurethanes containing 1,10-binaphthol [J]. J. Appl. Polymer Science, 2010, 115 (4):2190-2196.[11] Ye Hongmei, Ren Ning, Zhang Jianjun, et al. Synthesis, crystal structures and thermal decomposition kinetics of four new lanthanide complexes with 3,4-dimethylbenzoic acid and 1,10-phenanthroline [J]. Struct. Chem., 2010, 21 :165-173.[12] Lin Pu. 1,1'-binaphthyl dimers, oligomers, and polymers: molecular recognition, asymmetric catalysis, and new materials [J]. Chem. Rev., 1998, 98 (7):2405-2494.[13] Shi X, Zhou G S, Fang Q R, et al. Novel supramolecular frameworks self-assembled from one-dimensional polymeric coordination chains [J]. Eur. J. Inorg. Chem., 2004, 2004 (1):185-191.[14] Fan Ruiqing, Zhang Yanjiao, Yin Yanbin, et al. Syntheses, structures,and luminescent properties of cadmium(II) complexes:3D supramolecular n and Cd(phen)2(NO3)(NO2) constructed by-stacking interactions [J]. Synthetic Metals, 2009, 159 (11):1106-1111.[15] Shelxtl N T. Crystal Structure Analysis Package, Version 5.10 [M]. Germany: University of Gottingen, 1997.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

两种新型芴衍生物的合成、晶体结构及光谱性能

2,7-二(3-(氰基)苯基)-9,9-二乙基芴的合成、晶体结构及光学性质

Li（Sc, M）Si₂O₆∶Cr³⁺（M = Ga³⁺/Lu³⁺/Y³⁺/Gd³⁺）的近红外发光性能

稀土离子的多格位占据及能量传递

Ce³⁺掺杂Y‐Si‐O‐N体系荧光材料晶体及能带/电子结构对其发光特性的影响